Skip to main content

Tetramethyl orthosilicate

Also known as: TMOS, Methyl silicate, Tetramethoxysilane, Methyl orthosilicate, Silicon tetramethoxide, Tetramethyl silicate, Orthosilicic acid tetramethyl ester, Dynasil M, EINECS 211-656-4, MFCD00008341

Tetramethyl orthosilicate (CAS 681-84-5) is a compound in the Organic Acids category listed in the Jingsj chemical database. It has the molecular formula C4H12O4Si and a molecular weight of 152.221 g/mol. Key properties include a melting point of −4 °C(lit.), a boiling point of 121.2±8.0 °C at 760 mmHg, a density of 1.0±0.1 g/cm3 and a flash point of 28.9±0.0 °C. It is classified under GHS with signal word Danger and hazard statements H226 — Flammable liquid and vapour, H315 — Causes skin irritation and H318 — Causes serious eye damage. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
681-84-5
Jingsj CID
J-47492-0
Molecular Formula
C4H12O4Si
Molecular Weight
152.221 g/mol
Category
Organic Acids
Last updated
8/21/2026

No offers for this compound yet.

Request a quote

Physicochemical Properties

Melting Point−4 °C(lit.)
Boiling Point121.2±8.0 °C at 760 mmHg
Density1.0±0.1 g/cm3
Flash Point28.9±0.0 °C
Exact Mass152.050491
PSA36.92000
LogP2.97
Additional Property5.25 (vs air)
Vapor Pressure17.7±0.2 mmHg at 25°C
Refractive Index1.382
Additional Propertyhydrolysis

GHS Safety & Compliance

Flammable / Corrosion / Acute ToxicitySignal word: Danger
  • H226 — Flammable liquid and vapour
  • H315 — Causes skin irritation
  • H318 — Causes serious eye damage
  • H330 — Fatal if inhaled

Customs & Trade Information

HS Code2920909090
Summary2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Frequently Asked Questions

What is the CAS number of Tetramethyl orthosilicate?

The CAS number of Tetramethyl orthosilicate is 681-84-5.

What are the molecular formula and molecular weight of Tetramethyl orthosilicate?

Tetramethyl orthosilicate has molecular formula C4H12O4Si and molecular weight 152.221 g/mol.

Is Tetramethyl orthosilicate hazardous?

Tetramethyl orthosilicate has GHS signal word Danger and hazard statements H226 — Flammable liquid and vapour; H315 — Causes skin irritation; H318 — Causes serious eye damage.

What are the upstream and downstream products of Tetramethyl orthosilicate?

For Tetramethyl orthosilicate, Upstream Products: Methanol, Tetrachlorosilane, Silicon; Downstream Products: 2,4-Dimethoxy-1-nitrobenzene, Tetrabutyl orthosilicate, Trimethoxy(3,3,3-trifluoropropyl)silane.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "Tetramethyl orthosilicate (CAS 681-84-5)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-47492-0 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.