Skip to main content

2-Chloroacetophenone

Also known as: Phenacyl chloride, 2-Chloro-1-phenylethanone, α-Chloroacetophenone, ω-Chloroacetophenone, Phenyl chloromethyl ketone, (Chloroacetyl)benzene, 1-Phenyl-2-chloro-1-ethanone, 2-Chloro-1-phenylethan-1-one, alpha-Chloroacetophenone, omega-Chloroacetophenone, MACE, α-Phenacyl chloride

2-Chloroacetophenone (CAS 532-27-4) is a compound in the Ketones category listed in the Jingsj chemical database. It has the molecular formula C8H7ClO and a molecular weight of 154.594 g/mol. Key properties include a melting point of 54-56 °C(lit.), a boiling point of 244.5±0.0 °C at 760 mmHg, a density of 1.2±0.1 g/cm3 and a flash point of 104.8±11.0 °C. It is classified under GHS with signal word Danger and hazard statements H300, H311 — Toxic in contact with skin and H331 — Toxic if inhaled. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
532-27-4
Jingsj CID
J-33630-5
Molecular Formula
C8H7ClO
Molecular Weight
154.594 g/mol
Category
Ketones
Last updated
8/21/2026

No offers for this compound yet.

Request a quote

Physicochemical Properties

Melting Point54-56 °C(lit.)
Boiling Point244.5±0.0 °C at 760 mmHg
Density1.2±0.1 g/cm3
Flash Point104.8±11.0 °C
Exact Mass154.018539
PSA17.07000
LogP1.85
Vapor Pressure0.0±0.4 mmHg at 25°C
Refractive Index1.534
Additional Propertyinsoluble.

GHS Safety & Compliance

Corrosion / Acute Toxicity / Health HazardSignal word: Danger
  • H300
  • H311 — Toxic in contact with skin
  • H331 — Toxic if inhaled
  • H315 — Causes skin irritation
  • H318 — Causes serious eye damage
  • H334 — May cause allergy or asthma symptoms if inhaled
  • H335 — May cause respiratory irritation

Customs & Trade Information

HS Code2914700090
SummaryHS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 2-Chloroacetophenone?

The CAS number of 2-Chloroacetophenone is 532-27-4.

What are the molecular formula and molecular weight of 2-Chloroacetophenone?

2-Chloroacetophenone has molecular formula C8H7ClO and molecular weight 154.594 g/mol.

Is 2-Chloroacetophenone hazardous?

2-Chloroacetophenone has GHS signal word Danger and hazard statements H300; H311 — Toxic in contact with skin; H331 — Toxic if inhaled.

What are the upstream and downstream products of 2-Chloroacetophenone?

For 2-Chloroacetophenone, Upstream Products: Acetophenone, 2,2,2-Trichloro-1-phenylethanol, N-Methyl-N-nitrosotoluene-4-sulphonamide; Downstream Products: (Dimethylaminomethylene)dimethylammonium chloride, 2-(4-Fluorophenyl)-1-phenylethanone, 2-(p-toluenesulfonyl)acetophenone.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "2-Chloroacetophenone (CAS 532-27-4)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-33630-5 (accessed 2026-11-06).

Data for reference only; verify product details with suppliers before purchase.