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4-methylmorpholine

Also known as: N-Methylmorpholine, NMM, 4-Methyl-1-oxa-4-azacyclohexane, 4-Methylmorfolin, Methylmorpholine, 1-Methylmorpholine, N-Me-morpholine

4-methylmorpholine (CAS 109-02-4) is a compound in the Pharma Intermediates category listed in the Jingsj chemical database. It has the molecular formula C5H11NO and a molecular weight of 101.147 g/mol. Key properties include a melting point of −66 °C(lit.), a boiling point of 114.1±15.0 °C at 760 mmHg, a density of 0.9±0.1 g/cm3 and a flash point of 23.9±0.0 °C. It is classified under GHS with signal word Danger and hazard statements H225 — Highly flammable liquid and vapour, H302 — Harmful if swallowed and H314 — Causes severe skin burns and eye damage. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
109-02-4
Jingsj CID
J-1364602-2
Molecular Formula
C5H11NO
Molecular Weight
101.147 g/mol
Category
Pharma Intermediates
Last updated
8/21/2026

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Physicochemical Properties

Melting Point−66 °C(lit.)
Boiling Point114.1±15.0 °C at 760 mmHg
Density0.9±0.1 g/cm3
Flash Point23.9±0.0 °C
Exact Mass101.084061
PSA12.47000
LogP-0.33
Additional Property>1 (vs air)
Vapor Pressure20.2±0.2 mmHg at 25°C
Refractive Index1.435
Additional Property>500 g/L (20 ºC)

GHS Safety & Compliance

Flammable / Corrosion / IrritantSignal word: Danger
  • H225 — Highly flammable liquid and vapour
  • H302 — Harmful if swallowed
  • H314 — Causes severe skin burns and eye damage

Customs & Trade Information

HS Code2934999090
Summary2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Frequently Asked Questions

What is the CAS number of 4-methylmorpholine?

The CAS number of 4-methylmorpholine is 109-02-4.

What are the molecular formula and molecular weight of 4-methylmorpholine?

4-methylmorpholine has molecular formula C5H11NO and molecular weight 101.147 g/mol.

Is 4-methylmorpholine hazardous?

4-methylmorpholine has GHS signal word Danger and hazard statements H225 — Highly flammable liquid and vapour; H302 — Harmful if swallowed; H314 — Causes severe skin burns and eye damage.

What are the upstream and downstream products of 4-methylmorpholine?

For 4-methylmorpholine, Upstream Products: 4-Methylmorpholine 4-oxide, Methanol, 2-(2-Aminoethoxy)ethanol; Downstream Products: 4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride, Methyl pivalate, Boc-3-(1-naphthyl)-L-alanine.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "4-methylmorpholine (CAS 109-02-4)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-1364602-2 (accessed 2026-11-06).

Data for reference only; verify product details with suppliers before purchase.