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Chlorotrimethylsilane

Also known as: Trimethylchlorosilane, Trimethylsilyl chloride, CSI, TMCS, chloro(trimethyl)silane, Trimethylchlorosilane (TMCS)

Chlorotrimethylsilane (CAS 75-77-4) is a compound in the Aliphatic Hydrocarbons category listed in the Jingsj chemical database. It has the molecular formula C3H9ClSi and a molecular weight of 108.642 g/mol. Key properties include a melting point of −40 °C(lit.), a boiling point of 58.7±9.0 °C at 760 mmHg, a density of 0.9±0.1 g/cm3 and a flash point of -27.8±0.0 °C. It is classified under GHS with signal word Danger and hazard statements H225 — Highly flammable liquid and vapour, H301 — Toxic if swallowed and H331 — Toxic if inhaled. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
75-77-4
Jingsj CID
J-920909-9
Molecular Formula
C3H9ClSi
Molecular Weight
108.642 g/mol
Category
Aliphatic Hydrocarbons
Last updated
8/21/2026

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Physicochemical Properties

Melting Point−40 °C(lit.)
Boiling Point58.7±9.0 °C at 760 mmHg
Density0.9±0.1 g/cm3
Flash Point-27.8±0.0 °C
Exact Mass108.016205
LogP2.17
Additional Property3.7 (vs air)
Vapor Pressure219.8±0.1 mmHg at 25°C
Refractive Index1.388
Additional PropertyREACTS

GHS Safety & Compliance

Flammable / Corrosion / Acute ToxicitySignal word: Danger
  • H225 — Highly flammable liquid and vapour
  • H301 — Toxic if swallowed
  • H331 — Toxic if inhaled
  • H312 — Harmful in contact with skin
  • H314 — Causes severe skin burns and eye damage

Customs & Trade Information

HS Code29310095

Frequently Asked Questions

What is the CAS number of Chlorotrimethylsilane?

The CAS number of Chlorotrimethylsilane is 75-77-4.

What are the molecular formula and molecular weight of Chlorotrimethylsilane?

Chlorotrimethylsilane has molecular formula C3H9ClSi and molecular weight 108.642 g/mol.

Is Chlorotrimethylsilane hazardous?

Chlorotrimethylsilane has GHS signal word Danger and hazard statements H225 — Highly flammable liquid and vapour; H301 — Toxic if swallowed; H331 — Toxic if inhaled.

What are the upstream and downstream products of Chlorotrimethylsilane?

For Chlorotrimethylsilane, Upstream Products: Ethoxytrimethylsilane, Methoxytrimethylsilane, Bis(trimethylsilyl) sulfate.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "Chlorotrimethylsilane (CAS 75-77-4)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-920909-9 (accessed 2026-11-07).

Data for reference only; verify product details with suppliers before purchase.