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4-Hydroxybenzoic acid

Also known as: p-Hydroxybenzoic acid, 4-Carboxyphenol, p-Salicylic acid, p-carboxyphenol, para-Hydroxybenzoic acid, Benzoic acid, 4-hydroxy-, ACETYLSALICYLIC ACID IMPURITY A (ASPIRIN IMPURITY A), PROPYL PARAHYDROXYBENZOATE IMP. A (EP): 4-HYDROXYBENZOIC ACID

4-Hydroxybenzoic acid (CAS 99-96-7) is a compound in the Organic Acids category listed in the Jingsj chemical database. It has the molecular formula C7H6O3 and a molecular weight of 138.121 g/mol. Key properties include a melting point of 213-217 °C(lit.), a boiling point of 336.2±25.0 °C at 760 mmHg, a density of 1.4±0.1 g/cm3 and a flash point of 171.3±19.7 °C. It is classified under GHS with signal word Warning and hazard statements H315 — Causes skin irritation, H319 — Causes serious eye irritation and H335 — May cause respiratory irritation. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
99-96-7
Jingsj CID
J-8741-2
Molecular Formula
C7H6O3
Molecular Weight
138.121 g/mol
Category
Organic Acids
Last updated
8/21/2026

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Physicochemical Properties

Melting Point213-217 °C(lit.)
Boiling Point336.2±25.0 °C at 760 mmHg
Density1.4±0.1 g/cm3
Flash Point171.3±19.7 °C
Exact Mass138.031693
PSA57.53000
LogP1.42
Vapor Pressure0.0±0.8 mmHg at 25°C
Refractive Index1.616
Additional Property5 g/L (20 ºC)

GHS Safety & Compliance

IrritantSignal word: Warning
  • H315 — Causes skin irritation
  • H319 — Causes serious eye irritation
  • H335 — May cause respiratory irritation

Activity & Biological Data

TargetHuman Endogenous Metabolite Bacteria:160 μg/mL (IC50)
Additional Information[1]. Cho JY, Antimicrobial activity of 4-hydroxybenzoic acid and trans 4-hydroxycinnamic acid isolated and identified from rice hull. Biosci Biotechnol Biochem. 1998 Nov;62(11):2273-6.

Customs & Trade Information

HS Code2918290000
SummaryHS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 4-Hydroxybenzoic acid?

The CAS number of 4-Hydroxybenzoic acid is 99-96-7.

What are the molecular formula and molecular weight of 4-Hydroxybenzoic acid?

4-Hydroxybenzoic acid has molecular formula C7H6O3 and molecular weight 138.121 g/mol.

Is 4-Hydroxybenzoic acid hazardous?

4-Hydroxybenzoic acid has GHS signal word Warning and hazard statements H315 — Causes skin irritation; H319 — Causes serious eye irritation; H335 — May cause respiratory irritation.

What are the upstream and downstream products of 4-Hydroxybenzoic acid?

For 4-Hydroxybenzoic acid, Upstream Products: 4-Hydroxybenzyl alcohol, 4-Bromobenzoic acid, 4-Iodobenzoic acid; Downstream Products: Methyl 4-(pyridin-4-yl)benzoate, 4-Chlorobenzotrichloride, 4-Methylanisole.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "4-Hydroxybenzoic acid (CAS 99-96-7)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-8741-2 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.