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Ethyl oxalyl monochloride

Also known as: Ethyl chlorooxoacetate, Ethyl chloroglyoxylate, Ethyl oxalyl chloride, Monoethyl oxalyl chloride, Ethyl chloroglyoxalate, Ethyl chloro(oxo)acetate, Ethoxy oxalylchloride, ETCOX, Chloroglyoxylic Acid Ethyl Ester, Oxalic Acid Monoethyl Ester Chloride, ethyl 2-chloro-2-oxoacetate, Acetic acid, 2-chloro-2-oxo-, ethyl ester, Acetic acid, chlorooxo-, ethyl ester, Glyoxylic acid, chloro-, ethyl ester, Ethoxalyl chloride

Ethyl oxalyl monochloride (CAS 4755-77-5) is a compound in the Esters category listed in the Jingsj chemical database. It has the molecular formula C4H5ClO3 and a molecular weight of 136.534 g/mol. Key properties include a melting point of 135ºC, a boiling point of 137.0±9.0 °C at 760 mmHg, a density of 1.3±0.1 g/cm3 and a flash point of 41.7±0.0 °C. It is classified under GHS with signal word Danger and hazard statements H226 — Flammable liquid and vapour and H314 — Causes severe skin burns and eye damage. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
4755-77-5
Jingsj CID
J-48482-6
Molecular Formula
C4H5ClO3
Molecular Weight
136.534 g/mol
Category
Esters
Last updated
8/21/2026

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Physicochemical Properties

Melting Point135ºC
Boiling Point137.0±9.0 °C at 760 mmHg
Density1.3±0.1 g/cm3
Flash Point41.7±0.0 °C
Exact Mass135.992722
PSA43.37000
LogP1.06
Vapor Pressure7.2±0.3 mmHg at 25°C
Refractive Index1.425

GHS Safety & Compliance

Flammable / CorrosionSignal word: Danger
  • H226 — Flammable liquid and vapour
  • H314 — Causes severe skin burns and eye damage

Customs & Trade Information

HS Code2918300090
Summary2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Frequently Asked Questions

What is the CAS number of Ethyl oxalyl monochloride?

The CAS number of Ethyl oxalyl monochloride is 4755-77-5.

What are the molecular formula and molecular weight of Ethyl oxalyl monochloride?

Ethyl oxalyl monochloride has molecular formula C4H5ClO3 and molecular weight 136.534 g/mol.

Is Ethyl oxalyl monochloride hazardous?

Ethyl oxalyl monochloride has GHS signal word Danger and hazard statements H226 — Flammable liquid and vapour; H314 — Causes severe skin burns and eye damage.

What are the upstream and downstream products of Ethyl oxalyl monochloride?

For Ethyl oxalyl monochloride, Upstream Products: Diethyl oxalate, Oxalyl chloride, Ethanol; Downstream Products: ethyl 2-(4-methoxyphenyl)-2-oxoacetate, Ethyl 3-methyl-1,2,4-oxadiazole-5-carboxylate, ethyl 2-(4-isopropylphenyl)-2-oxoacetate.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "Ethyl oxalyl monochloride (CAS 4755-77-5)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-48482-6 (accessed 2026-11-07).

Data for reference only; verify product details with suppliers before purchase.