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4-Fluoro-2-methylbenzoic acid

Also known as: 2-Carboxy-5-fluorotoluene, 4-Fluoro-o-toluic acid, 2-methyl-4-fluorobenzoic acid, Benzoic acid, 4-fluoro-2-methyl-, RARECHEM AL BE 0506, MFCD04115880

4-Fluoro-2-methylbenzoic acid (CAS 321-21-1) is a compound in the Organic Acids category listed in the Jingsj chemical database. It has the molecular formula C8H7FO2 and a molecular weight of 154.138 g/mol. Key properties include a melting point of 168-172 °C(lit.), a boiling point of 265.6±20.0 °C at 760 mmHg, a density of 1.3±0.1 g/cm3 and a flash point of 114.5±21.8 °C. It is classified under GHS with signal word Danger and hazard statements H302 — Harmful if swallowed and H318 — Causes serious eye damage. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
321-21-1
Jingsj CID
J-45181-0
Molecular Formula
C8H7FO2
Molecular Weight
154.138 g/mol
Category
Organic Acids
Last updated
8/21/2026

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Physicochemical Properties

Melting Point168-172 °C(lit.)
Boiling Point265.6±20.0 °C at 760 mmHg
Density1.3±0.1 g/cm3
Flash Point114.5±21.8 °C
Exact Mass154.043015
PSA37.30000
LogP2.53
Vapor Pressure0.0±0.6 mmHg at 25°C
Refractive Index1.533

GHS Safety & Compliance

Corrosion / IrritantSignal word: Danger
  • H302 — Harmful if swallowed
  • H318 — Causes serious eye damage

Customs & Trade Information

HS Code2916399090
Summary2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 4-Fluoro-2-methylbenzoic acid?

The CAS number of 4-Fluoro-2-methylbenzoic acid is 321-21-1.

What are the molecular formula and molecular weight of 4-Fluoro-2-methylbenzoic acid?

4-Fluoro-2-methylbenzoic acid has molecular formula C8H7FO2 and molecular weight 154.138 g/mol.

Is 4-Fluoro-2-methylbenzoic acid hazardous?

4-Fluoro-2-methylbenzoic acid has GHS signal word Danger and hazard statements H302 — Harmful if swallowed; H318 — Causes serious eye damage.

What are the upstream and downstream products of 4-Fluoro-2-methylbenzoic acid?

For 4-Fluoro-2-methylbenzoic acid, Upstream Products: 2-Bromo-5-fluorotoluene, Carbon dioxide, 4-Fluoro-2-methylbenzonitrile; Downstream Products: Methyl 4-fluoro-2-methylbenzoate, 4-Fluoro-2-methylbenzoyl chloride, Methyl 2-(bromomethyl)-4-fluorobenzoate.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "4-Fluoro-2-methylbenzoic acid (CAS 321-21-1)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-45181-0 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.