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4-(Chloromethyl)benzoic acid

Also known as: alpha-Chloro-p-toluic acid, p-Carboxybenzyl chloride, 4-(Chloromethyl)benzoic acid, 4-Carboxybenzyl chloride, α-Chloro-p-toluic acid, p-Carboxbenzyl chloride, 4-Chloro-p-toluic acid

4-(Chloromethyl)benzoic acid (CAS 1642-81-5) is a compound in the Organic Acids category listed in the Jingsj chemical database. It has the molecular formula C8H7ClO2 and a molecular weight of 170.593 g/mol. Key properties include a melting point of 201-202 °C(lit.), a boiling point of 317.7±25.0 °C at 760 mmHg, a density of 1.3±0.1 g/cm3 and a flash point of 145.9±23.2 °C. It is classified under GHS with signal word Danger and hazard statements H314 — Causes severe skin burns and eye damage and H334 — May cause allergy or asthma symptoms if inhaled. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
1642-81-5
Jingsj CID
J-44223-9
Molecular Formula
C8H7ClO2
Molecular Weight
170.593 g/mol
Category
Organic Acids
Last updated
8/21/2026

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Physicochemical Properties

Melting Point201-202 °C(lit.)
Boiling Point317.7±25.0 °C at 760 mmHg
Density1.3±0.1 g/cm3
Flash Point145.9±23.2 °C
Exact Mass170.013458
PSA37.30000
LogP2.16
Vapor Pressure0.0±0.7 mmHg at 25°C
Refractive Index1.577

GHS Safety & Compliance

Corrosion / Health HazardSignal word: Danger
  • H314 — Causes severe skin burns and eye damage
  • H334 — May cause allergy or asthma symptoms if inhaled

Customs & Trade Information

HS Code2916399090
Summary2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 4-(Chloromethyl)benzoic acid?

The CAS number of 4-(Chloromethyl)benzoic acid is 1642-81-5.

What are the molecular formula and molecular weight of 4-(Chloromethyl)benzoic acid?

4-(Chloromethyl)benzoic acid has molecular formula C8H7ClO2 and molecular weight 170.593 g/mol.

Is 4-(Chloromethyl)benzoic acid hazardous?

4-(Chloromethyl)benzoic acid has GHS signal word Danger and hazard statements H314 — Causes severe skin burns and eye damage; H334 — May cause allergy or asthma symptoms if inhaled.

What are the upstream and downstream products of 4-(Chloromethyl)benzoic acid?

For 4-(Chloromethyl)benzoic acid, Upstream Products: 4-Methylbenzoic acid, 4-Carboxyphenylacetic acid, 4-(Chloromethyl)benzonitrile; Downstream Products: 4-((diethylamino)methyl)benzoic acid hydrochloride, Methyl 4-(chloromethyl)benzoate, Methyl 4-(methoxymethyl)benzoate.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "4-(Chloromethyl)benzoic acid (CAS 1642-81-5)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-44223-9 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.