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Methyl 2-chloroacetoacetate

Also known as: Methyl 2-chloro-3-oxobutanoate, 2-Chloroacetoacetic Acid Methyl Ester, 2-Acetyl-2-chloroacetic acid methyl ester, 2-chloro-3-oxo-butyric acid methyl ester, Butanoic acid, 2-chloro-3-oxo-, methyl ester, Chloroacetoacetic acid methyl ester, MFCD00008757

Methyl 2-chloroacetoacetate (CAS 4755-81-1) is a compound in the Organic Acids category listed in the Jingsj chemical database. It has the molecular formula C5H7ClO3 and a molecular weight of 150.56000 g/mol. Key properties include a melting point of −33-−32.7 °C(lit.), a boiling point of 137 °C(lit.), a density of 1.236 g/mL at 25 °C(lit.) and a flash point of 71.7 °C. It is classified under GHS with signal word Warning and hazard statements H302 — Harmful if swallowed, H312 — Harmful in contact with skin and H332 — Harmful if inhaled. No supplier offers are currently listed; request a quote. Record last updated Nov 2, 2026.

CAS No.
4755-81-1
Jingsj CID
J-43100-5
Molecular Formula
C5H7ClO3
Molecular Weight
150.56000 g/mol
Category
Organic Acids
Last updated
11/2/2026

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Physicochemical Properties

Melting Point−33-−32.7 °C(lit.)
Boiling Point137 °C(lit.)
Density1.236 g/mL at 25 °C(lit.)
Flash Point71.7 °C
Exact Mass150.00800
PSA43.37000
LogP0.35580
Refractive Indexn20/D 1.446(lit.)
Additional Property50 g/L (20 ºC)

GHS Safety & Compliance

IrritantSignal word: Warning
  • H302 — Harmful if swallowed
  • H312 — Harmful in contact with skin
  • H332 — Harmful if inhaled
  • H315 — Causes skin irritation
  • H319 — Causes serious eye irritation
  • H335 — May cause respiratory irritation

Customs & Trade Information

HS Code2918300090
Summary2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Frequently Asked Questions

What is the CAS number of Methyl 2-chloroacetoacetate?

The CAS number of Methyl 2-chloroacetoacetate is 4755-81-1.

What are the molecular formula and molecular weight of Methyl 2-chloroacetoacetate?

Methyl 2-chloroacetoacetate has molecular formula C5H7ClO3 and molecular weight 150.56000 g/mol.

Is Methyl 2-chloroacetoacetate hazardous?

Methyl 2-chloroacetoacetate has GHS signal word Warning and hazard statements H302 — Harmful if swallowed; H312 — Harmful in contact with skin; H332 — Harmful if inhaled.

What are the upstream and downstream products of Methyl 2-chloroacetoacetate?

For Methyl 2-chloroacetoacetate, Upstream Products: Methyl acetoacetate, Ethyl acetoacetate; Downstream Products: Methyl 2-amino-4-methylthiazole-5-carboxylate, Methyl 2-(4-chlorophenyl)-4-methyl-1,3-thiazole-5-carboxylate, methyl 3-methylbenzo[b]thiophene-2-carboxylate.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "Methyl 2-chloroacetoacetate (CAS 4755-81-1)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-43100-5 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.