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4-Chlorobenzyl chloride

Also known as: 4-Chlorobenzyl chloride, 1-Chloro-4-(chloromethyl)benzene, α,4-Dichlorotoluene, p-Chlorobenzyl chloride, PCBC, Benzene, 1-chloro-4-(chloromethyl)-, (4-chlorophenyl)methyl chloride, 4,α-Dichlorotoluene, p-α-Dichlorotoluene, MFCD00000914, EINECS 203-242-7

4-Chlorobenzyl chloride (CAS 104-83-6) is a compound in the Organohalogen Compounds category listed in the Jingsj chemical database. It has the molecular formula C7H6Cl2 and a molecular weight of 161.029 g/mol. Key properties include a melting point of 27-29 °C(lit.), a boiling point of 223.0±0.0 °C at 760 mmHg, a density of 1.2±0.1 g/cm3 and a flash point of 97.8±0.0 °C. It is classified under GHS with signal word Warning and hazard statements H302 — Harmful if swallowed, H312 — Harmful in contact with skin and H332 — Harmful if inhaled. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
104-83-6
Jingsj CID
J-30586-2
Molecular Formula
C7H6Cl2
Molecular Weight
161.029 g/mol
Category
Organohalogen Compounds
Last updated
8/21/2026

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Physicochemical Properties

Melting Point27-29 °C(lit.)
Boiling Point223.0±0.0 °C at 760 mmHg
Density1.2±0.1 g/cm3
Flash Point97.8±0.0 °C
Exact Mass159.984650
LogP3.08
Vapor Pressure0.1±0.4 mmHg at 25°C
Refractive Index1.547
Additional Propertyinsoluble

GHS Safety & Compliance

Irritant / Environmental HazardSignal word: Warning
  • H302 — Harmful if swallowed
  • H312 — Harmful in contact with skin
  • H332 — Harmful if inhaled
  • H317 — May cause an allergic skin reaction
  • H411 — Toxic to aquatic life with long lasting effects

Customs & Trade Information

HS Code2903999090
Summary2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 4-Chlorobenzyl chloride?

The CAS number of 4-Chlorobenzyl chloride is 104-83-6.

What are the molecular formula and molecular weight of 4-Chlorobenzyl chloride?

4-Chlorobenzyl chloride has molecular formula C7H6Cl2 and molecular weight 161.029 g/mol.

Is 4-Chlorobenzyl chloride hazardous?

4-Chlorobenzyl chloride has GHS signal word Warning and hazard statements H302 — Harmful if swallowed; H312 — Harmful in contact with skin; H332 — Harmful if inhaled.

What are the upstream and downstream products of 4-Chlorobenzyl chloride?

For 4-Chlorobenzyl chloride, Upstream Products: 4-Chlorobenzyl alcohol, 4-Chlorobenzaldehyde, 4-Chlorobenzaldehyde dimethyl acetal; Downstream Products: S-(4-Chlorobenzyl)isothiouronium chloride, 4-(4-Chlorophenyl)-2-butanone, DL-4-Chlorophenylalanine ethyl ester hydrochloride.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "4-Chlorobenzyl chloride (CAS 104-83-6)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-30586-2 (accessed 2026-11-06).

Data for reference only; verify product details with suppliers before purchase.