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2-Bromo-2'-chloroacetophenone

Also known as: 2-Bromo-1-(2-chlorophenyl)ethan-1-one, 2-Bromo-1-(2-chlorophenyl)ethanone, 2-Chlorophenacyl bromide, o-Chlorophenacyl bromide, 2-Bromo-2'-chloroacetophenone, 2'-Chloro-2-bromoacetophenone, α-Bromo-2-chloroacetophenone, MFCD00832993

2-Bromo-2'-chloroacetophenone (CAS 5000-66-8) is a compound in the Ketones category listed in the Jingsj chemical database. It has the molecular formula C8H6BrClO and a molecular weight of 233.490 g/mol. Key properties include a melting point of 162-166ºC (20 MMHG), a boiling point of 248.9±15.0 °C at 760 mmHg, a density of 1.6±0.1 g/cm3 and a flash point of 104.3±20.4 °C. It is classified under GHS with signal word Danger and hazard statements H314 — Causes severe skin burns and eye damage. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
5000-66-8
Jingsj CID
J-30497-2
Molecular Formula
C8H6BrClO
Molecular Weight
233.490 g/mol
Category
Ketones
Last updated
8/21/2026

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Physicochemical Properties

Melting Point162-166ºC (20 MMHG)
Boiling Point248.9±15.0 °C at 760 mmHg
Density1.6±0.1 g/cm3
Flash Point104.3±20.4 °C
Exact Mass231.929047
PSA17.07000
LogP2.62
Vapor Pressure0.0±0.5 mmHg at 25°C
Refractive Index1.584

GHS Safety & Compliance

CorrosionSignal word: Danger
  • H314 — Causes severe skin burns and eye damage

Customs & Trade Information

HS Code2914700090
SummaryHS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 2-Bromo-2'-chloroacetophenone?

The CAS number of 2-Bromo-2'-chloroacetophenone is 5000-66-8.

What are the molecular formula and molecular weight of 2-Bromo-2'-chloroacetophenone?

2-Bromo-2'-chloroacetophenone has molecular formula C8H6BrClO and molecular weight 233.490 g/mol.

Is 2-Bromo-2'-chloroacetophenone hazardous?

2-Bromo-2'-chloroacetophenone has GHS signal word Danger and hazard statements H314 — Causes severe skin burns and eye damage.

What are the upstream and downstream products of 2-Bromo-2'-chloroacetophenone?

For 2-Bromo-2'-chloroacetophenone, Upstream Products: 2'-Chloroacetophenone, Diazomethane, 2-Chlorobenzoyl chloride; Downstream Products: ethyl 4-(2-chlorophenyl)thiazole-2-carboxylate, 2-Chlorobenzoylacetonitrile, 2-Amino-2'-chloroacetophenone.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "2-Bromo-2'-chloroacetophenone (CAS 5000-66-8)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-30497-2 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.