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2,2,2-Trifluoroethyl formate

Also known as: Formic acid 2,2,2-trifluoroethyl ester, Trifluoroethyl formate, HCOOCH2CF3, TFEF, Zayia's reagent

2,2,2-Trifluoroethyl formate (CAS 32042-38-9) is a compound in the Organic Acids category listed in the Jingsj chemical database. It has the molecular formula C3H3F3O2 and a molecular weight of 128.050 g/mol. Key properties include a boiling point of 33.7±40.0 °C at 760 mmHg, a density of 1.3±0.1 g/cm3 and a flash point of -17.7±19.6 °C. It is classified under GHS with signal word Danger and hazard statements H225 — Highly flammable liquid and vapour, H302 — Harmful if swallowed and H319 — Causes serious eye irritation. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
32042-38-9
Jingsj CID
J-21125-6
Molecular Formula
C3H3F3O2
Molecular Weight
128.050 g/mol
Category
Organic Acids
Last updated
8/21/2026

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Physicochemical Properties

Boiling Point33.7±40.0 °C at 760 mmHg
Density1.3±0.1 g/cm3
Flash Point-17.7±19.6 °C
Exact Mass128.008514
PSA26.30000
LogP1.07
Vapor Pressure547.2±0.1 mmHg at 25°C
Refractive Index1.300

GHS Safety & Compliance

Flammable / IrritantSignal word: Danger
  • H225 — Highly flammable liquid and vapour
  • H302 — Harmful if swallowed
  • H319 — Causes serious eye irritation

Customs & Trade Information

HS Code2915120000
Summary2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Frequently Asked Questions

What is the CAS number of 2,2,2-Trifluoroethyl formate?

The CAS number of 2,2,2-Trifluoroethyl formate is 32042-38-9.

What are the molecular formula and molecular weight of 2,2,2-Trifluoroethyl formate?

2,2,2-Trifluoroethyl formate has molecular formula C3H3F3O2 and molecular weight 128.050 g/mol.

Is 2,2,2-Trifluoroethyl formate hazardous?

2,2,2-Trifluoroethyl formate has GHS signal word Danger and hazard statements H225 — Highly flammable liquid and vapour; H302 — Harmful if swallowed; H319 — Causes serious eye irritation.

What are the upstream and downstream products of 2,2,2-Trifluoroethyl formate?

For 2,2,2-Trifluoroethyl formate, Upstream Products: Formic Acid, 2,2,2-Trifluoroethanol, Bis(2,2,2-trifluoroethyl) ether; Downstream Products: N-(4-Methoxyphenyl)formamide, Formic Acid, 2,2,2-Trifluoroethanol.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "2,2,2-Trifluoroethyl formate (CAS 32042-38-9)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-21125-6 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.