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Methyl 3-chloro-3-oxopropanoate

Also known as: Methyl malonyl chloride, 3-Chloro-3-oxopropionic Acid Methyl Ester, (Chloroformyl)acetic Acid Methyl Ester, 3-methoxy-3-oxopropanoyl chloride, Methyl chloroformylacetate, methoxycarbonylacetyl chloride, methyl chlorocarbonyl acetate, methyl-3-chlorooxopropionate, Propanoic acid, 3-chloro-3-oxo-, methyl ester, EINECS 253-540-6, MFCD00013657

Methyl 3-chloro-3-oxopropanoate (CAS 37517-81-0) is a compound in the Organohalogen Compounds category listed in the Jingsj chemical database. It has the molecular formula C4H5ClO3 and a molecular weight of 136.534 g/mol. Key properties include a boiling point of 167.5±0.0 °C at 760 mmHg, a density of 1.3±0.1 g/cm3 and a flash point of 80.0±0.0 °C. It is classified under GHS with signal word Danger and hazard statements H314 — Causes severe skin burns and eye damage and H335 — May cause respiratory irritation. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
37517-81-0
Jingsj CID
J-1510232-6
Molecular Formula
C4H5ClO3
Molecular Weight
136.534 g/mol
Category
Organohalogen Compounds
Last updated
8/21/2026

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Physicochemical Properties

Boiling Point167.5±0.0 °C at 760 mmHg
Density1.3±0.1 g/cm3
Flash Point80.0±0.0 °C
Exact Mass135.992722
PSA43.37000
LogP0.56
Vapor Pressure1.7±0.3 mmHg at 25°C
Refractive Index1.425

GHS Safety & Compliance

Corrosion / IrritantSignal word: Danger
  • H314 — Causes severe skin burns and eye damage
  • H335 — May cause respiratory irritation

Customs & Trade Information

HS Code2918300090
Summary2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Frequently Asked Questions

What is the CAS number of Methyl 3-chloro-3-oxopropanoate?

The CAS number of Methyl 3-chloro-3-oxopropanoate is 37517-81-0.

What are the molecular formula and molecular weight of Methyl 3-chloro-3-oxopropanoate?

Methyl 3-chloro-3-oxopropanoate has molecular formula C4H5ClO3 and molecular weight 136.534 g/mol.

Is Methyl 3-chloro-3-oxopropanoate hazardous?

Methyl 3-chloro-3-oxopropanoate has GHS signal word Danger and hazard statements H314 — Causes severe skin burns and eye damage; H335 — May cause respiratory irritation.

What are the upstream and downstream products of Methyl 3-chloro-3-oxopropanoate?

For Methyl 3-chloro-3-oxopropanoate, Upstream Products: Potassium 3-methoxy-3-oxopropanoate, Monomethyl malonate; Downstream Products: Phenyl isothiocyanate, Methyl 3-oxovalerate, methyl 3-(methylamino)-3-oxopropanoate.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "Methyl 3-chloro-3-oxopropanoate (CAS 37517-81-0)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-1510232-6 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.