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4-Mercaptopyridine

Also known as: 4-Pyridinethiol, Pyridine-4-thiol, 4-thiopyridine, 4(1H)-Pyridinethione, 4-Pyridyl Mercaptan, Mercaptopyridine

4-Mercaptopyridine (CAS 4556-23-4) is a compound in the Pharma Intermediates category listed in the Jingsj chemical database. It has the molecular formula C5H5NS and a molecular weight of 111.165 g/mol. Key properties include a melting point of 182-189 °C, a boiling point of 194.0±13.0 °C at 760 mmHg, a density of 1.2±0.1 g/cm3 and a flash point of 71.1±19.8 °C. It is classified under GHS with signal word Warning and hazard statements H315 — Causes skin irritation, H319 — Causes serious eye irritation and H335 — May cause respiratory irritation. No supplier offers are currently listed; request a quote. Record last updated Aug 21, 2026.

CAS No.
4556-23-4
Jingsj CID
J-1088888-7
Molecular Formula
C5H5NS
Molecular Weight
111.165 g/mol
Category
Pharma Intermediates
Last updated
8/21/2026

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Physicochemical Properties

Melting Point182-189 °C
Boiling Point194.0±13.0 °C at 760 mmHg
Density1.2±0.1 g/cm3
Flash Point71.1±19.8 °C
Exact Mass111.014267
PSA51.69000
LogP1.03
Vapor Pressure0.6±0.4 mmHg at 25°C
Refractive Index1.598

GHS Safety & Compliance

IrritantSignal word: Warning
  • H315 — Causes skin irritation
  • H319 — Causes serious eye irritation
  • H335 — May cause respiratory irritation

Customs & Trade Information

HS Code2933399090
Summary2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Frequently Asked Questions

What is the CAS number of 4-Mercaptopyridine?

The CAS number of 4-Mercaptopyridine is 4556-23-4.

What are the molecular formula and molecular weight of 4-Mercaptopyridine?

4-Mercaptopyridine has molecular formula C5H5NS and molecular weight 111.165 g/mol.

Is 4-Mercaptopyridine hazardous?

4-Mercaptopyridine has GHS signal word Warning and hazard statements H315 — Causes skin irritation; H319 — Causes serious eye irritation; H335 — May cause respiratory irritation.

What are the upstream and downstream products of 4-Mercaptopyridine?

For 4-Mercaptopyridine, Upstream Products: 4-chloropyridine, 4-Hydroxypyridine, 4(1H)-Pyridinone; Downstream Products: 4,4'-Thiodipyridine, 4-chloropyridine, 4-Phenylpyridine.

Data compiled from public chemical databases such as PubChem and supplier catalogs; supplier offers are provided by suppliers.

Last updated:

How to cite: Jingsj. "4-Mercaptopyridine (CAS 4556-23-4)". Jingsj Chemical Database. https://www.jingsj.com/compound/J-1088888-7 (accessed 2026-11-09).

Data for reference only; verify product details with suppliers before purchase.