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General tariff:20.0%",[339,342,345,348,351,354,357,360,363],{"key":340,"value":341},"个人防护装备","dust mask type N95 (US);Eyeshields;Gloves",{"key":343,"value":344},"危害码 (欧洲)","Xi: Irritant;Xn: Harmful;",{"key":346,"value":347},"风险声明 (欧洲)","R36\u002F37\u002F38",{"key":349,"value":350},"安全声明 (欧洲)","S9-S24\u002F25-S37\u002F39-S26-S36-S23",{"key":352,"value":353},"危险品运输编码","UN 2348 3\u002FPG 3",{"key":355,"value":356},"WGK德国","3",{"key":358,"value":359},"RTECS号","UD3150000",{"key":361,"value":362},"包装等级","I; II; III",{"key":327,"value":328},"\u003Ctd>\n\n\u003Cp>\u003Cstrong>6-苄氨基嘌呤毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>1、急性毒性：大鼠口经LD50：2125mg\u002Fkg：感觉器官敏感，精神萎靡    小鼠口经LD50：1300mg\u002Fkg：感觉器官敏感，精神萎靡    小鼠涂在皮肤LD50：>5gm\u002Fkg\r\n                                        \u003C\u002Fp>\n\u003Cp>\u003Cstrong>6-苄氨基嘌呤生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp> 对水是稍微有危害的不要让未稀释或大量的产品接触地下水、水道或者污水系统，若无政府许可，勿将材料排入周围环境 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F1214-39-7_1026751.html#duXinDiv\">6-苄氨基嘌呤毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>制备方法一\u003Cbr \u002F>以工业中生产病毒唑副产物（Ⅰ）为原料合成。生产过程通过水解、缩合、苄胺化三步化学反应。\u003Cbr \u002F>水解（次黄嘌呤的制备）。将1400mL3%盐酸和105g（Ⅰ）回流反应8h，加500mL10%氢氧化钠溶液，使pH值5～6。冷却、抽滤得灰黄色固体，用水重结晶，活性炭处理得白色粉末状固体（Ⅱ），干重83g。\u003C\u002Fp>\u003Cp>缩合（吡啶盐中间体的制备）。将6g（Ⅱ）溶于125mL吡啶溶液，滴加８犿犔三氯氧磷，反应置冰浴中冷却。滴毕继续于室温反应0.5h，即抽滤，干燥后得（Ⅲ）7.85g。\u003C\u002Fp>\u003Cp>苄胺化（6-BA的合成）。将中间体盐（Ⅲ）置于反应瓶中，滴加30mL苄胺，滴毕水浴升温至60～70℃，反应3h，蒸除苄胺得粗品（Ⅳ）2.1g。重结晶时用1mol\u002FL氢氧化钠溶解粗产物，活性炭煮沸脱色，热过滤，冷后调节pH值4～5，有白色固体析出。上述各步反应过程如下。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>制备方法二\u003Cbr \u002F>通过次黄嘌呤氯代，然后苄胺解制得苄基腺嘌呤。\u003Cbr \u002F>\u003C\u002Fp>\u003Cp>制备方法三\u003Cbr \u002F>\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>制备方法四\u003Cbr \u002F>由腺嘌呤与氯苄直接反应制得，但产品中9-位取代物难以分离和纯化。\u003Cbr \u002F>\u003C\u002Fp>","\u003Ctd>\n\n\u003Cb>N6-苄基腺嘌呤\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>N6-Benzyladenine\u003C\u002Fb>\n\u003Cbr \u002F> 产品名称：\n\u003Cbr \u002F> 修改号码：\n\u003Cb>5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害未分类\n\u003Cbr \u002F> 　健康危害\n\u003Cbr \u002F> 急性毒性（经口）\n\u003Cb>第4级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>皮肤腐蚀\u002F刺激\u003C\u002Fb>\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>严重损伤\u002F刺激眼睛\u003C\u002Fb>\n\u003Cb>2B类\u003C\u002Fb>\n\u003Cbr \u002F> 生殖毒性\n\u003Cb>第2级\u003C\u002Fb>\n\u003Cbr \u002F> 特异性靶器官毒性呼吸道刺激\n\u003Cbr \u002F>\n\u003Cb>- 单一接触 [第3级]\u003C\u002Fb>\n\u003Cbr \u002F> 　环境危害\n\u003Cbr \u002F> 急性水生毒性\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F> 慢性水生毒性\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>GHS标签元素\u003C\u002Fb>\n\u003Cbr \u002F> 　图标或危害标志\n\u003Cbr \u002F> 　信号词警告\n\u003Cbr \u002F> 　危险描述吞咽有害。\n\u003Cbr \u002F> 造成轻微皮肤刺激\n\u003Cbr \u002F> 造成眼刺激\n\u003Cbr \u002F> 怀疑会损害生育能力或胎儿\n\u003Cbr \u002F> 可能造成呼吸刺激\n\u003Cbr \u002F> 对水生生物有害\n\u003Cbr \u002F> 长期影响对水生生物有害\n\u003Cbr \u002F> 　防范说明\n\u003Cbr \u002F>\n\u003Cb>N6-苄基腺嘌呤\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>[预防]\u003C\u002Fb>使用前获取特定手册。\n\u003Cbr \u002F> 处理前必须阅读并理解所有安全措施。\n\u003Cbr \u002F> 避免吸入。\n\u003Cbr \u002F> 只能在室外或通风良好的环境下使用。\n\u003Cbr \u002F> 避免释放到环境中。\n\u003Cbr \u002F> 使用本产品时切勿吃东西，喝水或吸烟。\n\u003Cbr \u002F> 处理后要彻底清洗双手。\n\u003Cbr \u002F> 使用个人所需的防护用具。\n\u003Cbr \u002F>\n\u003Cb>[急救措施]\u003C\u002Fb>吸入：将受害者移到新鲜空气处，在呼吸舒适的地方保持休息。\n\u003Cbr \u002F>\n\u003Cb>食入：若感不适，呼叫解毒中心\u002F医生。漱口。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续冲洗。\n\u003Cbr \u002F>\n\u003Cb>眼睛接触：求医\u002F就诊\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>若皮肤刺激：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>如接触到或相关接触：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>[储存]\u003C\u002Fb>存放于通风良好处。保持容器密闭。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F>\n\u003Cb>[废弃处置]\u003C\u002Fb>\n\u003Cb>根据当地政府规定把物品\u002F容器交与工业废弃处理机构。\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>\n\u003Cb>N6-苄基腺嘌呤\u003C\u002Fb>\n\u003Cbr \u002F> 百分比：\n\u003Cb>>99.0%(LC)(T)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>1214-39-7\u003C\u002Fb>\n\u003Cbr \u002F> 俗名：\n\u003Cb>6-Benzylaminopurine\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cb>C12H11N5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。\n\u003Cbr \u002F>\n\u003Cb>求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>求医\u002F就诊。漱口。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，泡沫，雾状水，二氧化碳\n\u003Cbr \u002F> 特殊危险性：小心，燃烧或高温下可能分解产生毒烟。\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F> 周围一旦着火：如果安全，移去可移动容器。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用特殊的个人防护用品（针对有毒颗粒的P3过滤式空气呼吸器）。远离溢出物\u002F泄露\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：处并处在上风处。\n\u003Cbr \u002F> 泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F>\n\u003Cb>N6-苄基腺嘌呤\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 控制和清洗的方法和材料：清扫收集粉尘，封入密闭容器。注意切勿分散。附着物或收集物应该立即根据合适的\n\u003Cbr \u002F> 法律法规处置。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：在通风良好处进行处理。穿戴合适的防护用具。防止粉尘扩散。处理后彻底清洗双手\n\u003Cbr \u002F> 和脸。\n\u003Cbr \u002F> 注意事项：如果可能，使用封闭系统。如果粉尘或浮质产生，使用局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免所有部位的接触！\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于凉爽、阴暗、通风良好处。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F> 包装材料：依据法律。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统。同时安装淋浴器和洗眼器。\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：\n\u003Cb>防尘面具，自携式呼吸器（SCBA），供气呼吸器等。使用通过政府标准的呼吸器。依\u003C\u002Fb>\n\u003Cbr \u002F> 据当地和政府法规。\n\u003Cbr \u002F> 　手部防护：防渗手套。\n\u003Cbr \u002F> 　眼睛防护：护目镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防渗防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F> 固体\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>\n\u003Cbr \u002F> 外观：\n\u003Cb>晶体-粉末\u003C\u002Fb>\n\u003Cbr \u002F> 颜色：白色类白色\n\u003Cbr \u002F> 气味：无味\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：\n\u003Cbr \u002F>\n\u003Cb>234°C\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>无资料\n\u003Cbr \u002F> 闪点：无资料\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 密度：无资料\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>log水分配系数 =\u003C\u002Fb>\n\u003Cb>1.57\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：未报道特殊反应性。\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳, 氮氧化物 (NOx)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>N6-苄基腺嘌呤\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>orl-rat LD50:1.3 g\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>skn-rbt LD50:>5000 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>ihl-rat LC50:5.2 g\u002Fm3\u002F4H\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：无资料\n\u003Cbr \u002F> 对眼睛严重损害或刺激：无资料\n\u003Cbr \u002F> 生殖细胞变异原性：\n\u003Cb>oms-hmn-leu 100 nmol\u002FL\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>mmo-sat0.062mg\u002Fplate\u002F2D(+\u002F-S9)\u003C\u002Fb>\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>AU6252200\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：\n\u003Cb>96h LC50:21.4 mg\u002FL (Oncorhynchus mykiss)\u003C\u002Fb>\n\u003Cbr \u002F> 甲壳类：\n\u003Cb>48h EC50:20.5 mg\u002FL (Daphnia magna)\u003C\u002Fb>\n\u003Cbr \u002F> 藻类：\n\u003Cb>48h LC50:56 mg\u002FL (Chlamydomonas globosa)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>无资料\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>\n\u003Cb>1.57\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律\n\u003Cb>9.03 x 10-4\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在可燃溶剂中溶解混合，在装有后燃和洗涤装置的化学焚烧炉中\n\u003Cbr \u002F> 焚烧。废弃处置时请遵守国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：与联合国分类标准不一致\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>未列明\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F>\n\u003Cb>N6-苄基腺嘌呤\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\u003Cbr \u002F>\u003Cbr \u002F>\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[370,376,382,388,394,400,406,412,418,424,430,436],{"slug":371,"cid":372,"name":373,"nameZh":374,"cas":375},"855022104469311488","J-1994369-2","5-Bromo-2-Methoxypyridine hydrochloride","5-溴-2-甲氧基吡啶盐酸盐","13472-67-8",{"slug":377,"cid":378,"name":379,"nameZh":380,"cas":381},"785882713688117248","J-5474-0","L-Carnosine","L-肌肽","305-84-0",{"slug":383,"cid":384,"name":385,"nameZh":386,"cas":387},"785884025494441984","J-1179621-7","lithium 2-(morpholin-4-ylmethyl)benzoate","2-(吗啉甲基)苯甲酸锂","904696-60-2",{"slug":389,"cid":390,"name":391,"nameZh":392,"cas":393},"785898947561394176","J-1530331-8","2-Methylimidazole zinc salt","2-甲基咪唑锌盐","59061-53-9",{"slug":395,"cid":396,"name":397,"nameZh":398,"cas":399},"785895196641464320","J-1411212-0","Ethyl (2S)-2-indolinecarboxylate hydrochloride","(S)-吲哚啉-2-羧酸乙酯盐酸盐","79854-42-5",{"slug":401,"cid":402,"name":403,"nameZh":404,"cas":405},"854321256382599168","J-1994314-7","Ethyl indoline-3-carboxylate hydrochloride","吲哚-3-羧酸乙酯盐酸盐","1158918-79-6",{"slug":407,"cid":408,"name":409,"nameZh":410,"cas":411},"785889509320429568","J-1361950-6","Ethyl 2-(2-amino-1,3-thiazol-4-yl)acetate hydrochloride","2-氨基-1,3-噻唑-4-乙酸乙酯盐酸盐","76629-17-9",{"slug":413,"cid":414,"name":415,"nameZh":416,"cas":417},"785891847871401984","J-1442198-8","Dibenzothiophene-2-boronic acid","二苯并噻吩-2-硼酸","668983-97-9",{"slug":419,"cid":420,"name":421,"nameZh":422,"cas":423},"785897768873889792","J-1112013-1","4,4'-Bipyridine dihydrochloride","4,4'-联吡啶二盐酸盐","27926-72-3",{"slug":425,"cid":426,"name":427,"nameZh":428,"cas":429},"785883654130765824","J-1618524-3","2,3-dimethyl-1-oxido-4-(2,2,2-trifluoroethoxy)pyridin-1-ium","2,3-二甲基-4-(2,2,2-三氟乙氧基)吡啶-N-氧化物","103577-61-3",{"slug":431,"cid":432,"name":433,"nameZh":434,"cas":435},"854772462439632896","J-1994334-1","5,6,7,8-Tetrahydroquinolin-8-amine dihydrochloride","5,6,7,8-四氢-8-氨基喹啉二盐酸盐","1187929-87-8",{"slug":437,"cid":438,"name":439,"nameZh":440,"cas":441},"855018849429360640","J-1994362-5","(S)-5,6,7,8-Tetrahydroquinolin-8-amine dihydrochloride","(S)-5,6,7,8-四氢喹啉-8-胺二盐酸盐","865303-57-7",1794262274322,"zh-CN",[]]