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VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%",[340,343,346,349,352,355,358,361],{"key":341,"value":342},"个人防护装备","Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter",{"key":344,"value":345},"危害码 (欧洲)","Xn, Xi",{"key":347,"value":348},"风险声明 (欧洲)","22-42\u002F43-68-36\u002F37\u002F38",{"key":350,"value":351},"安全声明 (欧洲)","S26-S36\u002F37\u002F39-S24\u002F25-S22",{"key":353,"value":354},"危险品运输编码","NONH for all modes of transport",{"key":356,"value":357},"WGK德国","3",{"key":359,"value":360},"RTECS号","UU8815550",{"key":328,"value":329},"\u003Ctd>\n\n\u003Cp>\u003Cstrong>氧氟沙星毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp> 急性毒性LD50雄、雌小鼠，雄、雌大鼠(rng\u002Fkg)：5450，5290，3590，3750口服；208，233，273，276静脉注射；＞10000，＞10000，7070，9000皮下注射 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F82419-36-1_1084751.html#duXinDiv\">氧氟沙星毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>方法1：以2，3，4-三氟硝基苯为起始原料，经选择性碱水解、醚化、还原、与C2H5OCH=C(COOEt)2或(CH3)2NCH=C(COOEt)2缩合、环合、水解，与乙酸硼作用后，再引入N-甲基哌嗪而得产品。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>方法2：以邻苯二甲酰亚胺衍生物为原料，经氟化生成四氟邻苯二甲酰亚胺，水解、脱羧生成2，3，4，5-四氟苯甲酸，再氯化、酰化、脱羧生成2，3，4，5-四氟苯甲酰乙酸乙酯，接着先和原甲酸三乙酯、后和2-氨基丙醇反应，再环合生成吡啶并[1，2，3-de][1，4]苯并嘿嗪衍生物，最后和哌嗪反应生成氧氟沙星。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>方法3：上述得到的四氟苯甲酰乙酸乙酯，先和甲基哌嗪反应，引入哌嗪基后，再引入侧链后环合，然后水解得氧氟沙星。在氧氟沙星的制备中，哌嗪基的引入是一研究热点。越后引入，对其收率影响越大。该方法先把哌嗪引入，其引入收率可达88%。但在环合时，必须用强碱，如氢化钠，才能进行环合。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>4.以2,3,4-三氟硝基苯为原料，经选择性碱水解、醚化、还原、缩合、环合、水解，与乙酸硼作用后，再引入犖甲基哌嗪而得产品。或者以邻苯二甲酰亚胺衍生物为原料，经氟化生成四氟邻苯二甲酰亚胺，经水解、脱羧生成2,3,4,5,-四氟苯甲酸，再氯化、酰化、脱羧生成2,3,4,5,-四氟苯甲酰乙酸乙酯。然后和原甲酸三乙酯、再和2-氨基丙醇反应，最后和哌嗪反应生成氧氟沙星。也可以将上述得到的2,3,4,5,-四氟苯甲酰乙酸乙酯，先和甲基哌嗪反应，引入哌嗪基后，再引入侧链后环合，然后水解得氧氟沙星。\u003Cbr \u002F>\u003C\u002Fp>","\u003Ctd>\n\r\n                                        \r\n                                        氧氟沙星\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F> 产品名称：\n\u003Cb>Ofloxacin\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害未分类\n\u003Cbr \u002F> 　健康危害\n\u003Cbr \u002F> 急性毒性（经口）\n\u003Cb>第5级\u003C\u002Fb>\n\u003Cbr \u002F> 　环境危害未分类\n\u003Cbr \u002F>\n\u003Cb>GHS标签元素\u003C\u002Fb>\n\u003Cbr \u002F> 　图标或危害标志无\n\u003Cbr \u002F> 　信号词警告\n\u003Cbr \u002F> 　危险描述吞咽可能有害。\n\u003Cbr \u002F> 　防范说明\n\u003Cbr \u002F>\n\u003Cb>[急救措施]\u003C\u002Fb>\n\u003Cb>若感不适：呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>氧氟沙星\n\u003Cbr \u002F> 百分比：\n\u003Cb>>98.0%(LC)(T)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>82419-36-1\u003C\u002Fb>\n\u003Cbr \u002F> 俗名：\n\u003Cb>9-Fluoro-3,7-dihydro-3-methyl-10-(4-methyl-1-piperazinyl)-7-oxo-2H-\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>[1,4]oxazino[2,3,4-ij]quinoline-6-carboxylic Acid\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cb>C18H20FN3O4\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。若感不适立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>若皮肤刺激或发生皮疹：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续清洗。\n\u003Cbr \u002F>\n\u003Cb>如果眼睛刺激：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>若感不适，呼叫解毒中心\u002F医生。漱口。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F> 氧氟沙星\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，泡沫，雾状水，二氧化碳\n\u003Cbr \u002F> 特殊危险性：小心，燃烧或高温下可能分解产生毒烟。\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F> 周围一旦着火：如果安全，移去可移动容器。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用个人防护用品。远离溢出物\u002F泄露处并处在上风处。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F> 控制和清洗的方法和材料：清扫收集粉尘，封入密闭容器。注意切勿分散。附着物或收集物应该立即根据合适的\n\u003Cbr \u002F> 法律法规处置。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：在通风良好处进行处理。穿戴合适的防护用具。防止粉尘扩散。处理后彻底清洗双手\n\u003Cbr \u002F> 和脸。\n\u003Cbr \u002F> 注意事项：如果粉尘或浮质产生，使用局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免接触皮肤、眼睛和衣物。\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于凉爽、阴暗处。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F> 光敏\n\u003Cbr \u002F> 包装材料：依据法律。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统，操作人员切勿直接接触。同时安装淋浴器和洗\n\u003Cbr \u002F> 眼器。\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：防尘面具。依据当地和政府法规。\n\u003Cbr \u002F> 　手部防护：防护手套。\n\u003Cbr \u002F> 　眼睛防护：安全防护镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F> 固体\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>\n\u003Cbr \u002F> 外观：\n\u003Cb>晶体-粉末\u003C\u002Fb>\n\u003Cbr \u002F> 颜色：\n\u003Cb>白色-微浅黄色\u003C\u002Fb>\n\u003Cbr \u002F> 气味：无资料\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：\n\u003Cbr \u002F>\n\u003Cb>263°C\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>无资料\n\u003Cbr \u002F> 闪点：无资料\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 密度：无资料\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F> 氧氟沙星\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：未报道特殊反应性。\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳, 氮氧化物 (NOx), 氟化氢\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>orl-rat LD50:3590 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>ivn-rat LD50:273 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>scu-rat LD50:7070 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：无资料\n\u003Cbr \u002F> 对眼睛严重损害或刺激：无资料\n\u003Cbr \u002F> 生殖细胞变异原性：\n\u003Cb>mmo-sat 50 ng\u002Fplate (+S9)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>mmo-esc 15.63 ng\u002Fplate (-S9)\u003C\u002Fb>\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>UU8815500\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：无资料\n\u003Cbr \u002F> 甲壳类：无资料\n\u003Cbr \u002F> 藻类：无资料\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>无资料\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律无资料\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在可燃溶剂中溶解混合，在装有后燃和洗涤装置的化学焚烧炉中\n\u003Cbr \u002F> 焚烧。废弃处置时请遵守国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：与联合国分类标准不一致\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>未列明\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F> 氧氟沙星\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\u003Cbr \u002F>\u003Cbr \u002F>\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[368,374,380,386,392,398,404,410,416,422,428,434],{"slug":369,"cid":370,"name":371,"nameZh":372,"cas":373},"785872091479019520","J-1094974-3","Denatonium chloride","氯化地那铵","1674-99-3",{"slug":375,"cid":376,"name":377,"nameZh":378,"cas":379},"785883024532180992","J-1116316-9","Didecyldimethylammonium chloride","双癸基二甲基氯化铵","7173-51-5",{"slug":381,"cid":382,"name":383,"nameZh":384,"cas":385},"785891756762730496","J-31041-8","Hexamethonium bromide","六甲溴铵","55-97-0",{"slug":387,"cid":388,"name":389,"nameZh":390,"cas":391},"785891911704514560","J-1448095-6","1,6-Dibromopyrene","1,6-二溴芘","27973-29-1",{"slug":393,"cid":394,"name":395,"nameZh":396,"cas":397},"785884139197829120","J-1182658-7","Dichloro(1,10-phenanthroline)palladium(II)","二氯(1,10-菲咯啉)钯(II)","14783-10-9",{"slug":399,"cid":400,"name":401,"nameZh":402,"cas":403},"785873119507124224","J-1994051-3","Tetrabutylammonium iodide","四丁基碘化铵","311-28-4",{"slug":405,"cid":406,"name":407,"nameZh":408,"cas":409},"785893832100155392","J-36340-6","1H,1H,2H,2H-Perfluorohexyl iodide","全氟丁基乙基碘","2043-55-2",{"slug":411,"cid":412,"name":413,"nameZh":414,"cas":415},"785897009360932864","J-46069-5","Cetylpyridinium chloride","西吡氯铵","123-03-5",{"slug":417,"cid":418,"name":419,"nameZh":420,"cas":421},"785894241678135296","J-1501577-7","2,9-Dibromo-1,10-phenanthroline","2,9-二溴-1,10-菲罗啉","39069-02-8",{"slug":423,"cid":424,"name":425,"nameZh":426,"cas":427},"785876269278433280","J-1385088-9","6,12-Dibromochrysene","6,12-二溴屈","131222-99-6",{"slug":429,"cid":430,"name":431,"nameZh":432,"cas":433},"785892160594513920","J-1115521-8","decyldimethyloctylammonium chloride","辛基癸基二甲基氯化铵","32426-11-2",{"slug":435,"cid":436,"name":437,"nameZh":438,"cas":439},"785897948247494656","J-1524658-9","Di-μ-chloro-tetracarbonyldirhodium(I)","四羰基二氯化二铑","14523-22-9",1794251863391,"zh-CN",[]]