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25ºC(lit.)","density",{"label":194,"labelZh":195,"value":196},"Exact Mass","精确质量","108.93600",{"label":198,"labelZh":198,"value":199},"外观性状","绿色粉末",{"label":201,"labelZh":202,"value":203},"Storage Conditions","储存条件","储存注意事项储存于阴凉、通风的库房。包装密封。应与酸类分开存放，切忌混储。储区应备有合适的材料收容泄漏物。",{"label":205,"labelZh":205,"value":206},"稳定性","1.本品溶解性低，由铬引起的急性毒性较低。由于分解生成氟化氢等有毒气体，必须注意它的毒性，有腐蚀性。应使吸入蒸气的患者脱离污染区，安置休息并保暖。眼睛受刺激时用水冲洗15 min。皮肤接触时先用水冲洗，再用肥皂彻底洗涤。误服立即漱口，急送医院救治。\n2.稳定性 稳定\n3.禁配物 强酸\n4.避免接触的条件 受热\n5.聚合危害 不聚合\n6.分解产物 氟化氢",{"label":208,"labelZh":209,"value":210},"Molecular Structure","分子结构","1、摩尔折射率：无可用的\n2、摩尔体积（cm\n3\n\u002Fmol）：无可用的\n3、等张比容（90.2K）：无可用的\n4、表面张力（dyne\u002Fcm）：无可用的\n5、介电常数：无可用的\n6、极化率：无可用的\n7、单一同位素质量：108.935722 Da\n8、标称质量：109 Da\n9、平均质量：108.9913 Da",{"label":212,"labelZh":213,"value":214},"Computational Chemistry","计算化学","1.疏水参数计算参考值（XlogP）:无\n2.氢键供体数量:0\n3.氢键受体数量:3\n4.可旋转化学键数量:0\n5.互变异构体数量:无\n6.拓扑分子极性表面积0\n7.重原子数量:4\n8.表面电荷:0\n9.复杂度:0\n10.同位素原子数量:0\n11.确定原子立构中心数量:0\n12.不确定原子立构中心数量:0\n13.确定化学键立构中心数量:0\n14.不确定化学键立构中心数量:0\n15.共价键单元数量:4",{"label":216,"labelZh":216,"value":217},"更多","1.性状：绿色粉末或结晶\n2.熔点（℃）：1100\n3.沸点（℃）：1100~1200（升华）\n4.相对密度（水=1）：3.78\n5.溶解性：不溶于水，不溶于醇，微溶于酸，溶于氢氟酸。",{"pictogram":219,"signal":220,"hazards":221},"Corrosion \u002F Irritant","Danger",[],[],"\u003Ctd>\n\u003Cdiv class=\"\" id=\"MSDSTbl\">\n\u003Ctable class=\"_table_all\">\n\u003Ctbody>\n\u003Ctr class=\"_tr_1\">\n\u003Ctd class=\"_td_header_1\">\u003Cstrong> 国标编号: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_1\"> 83002 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_2\">\n\u003Ctd class=\"_td_header_2\">\u003Cstrong> ＣＡＳ: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_2\"> 7788-97-8 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_3\">\n\u003Ctd class=\"_td_header_3\">\u003Cstrong> 中文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_3\"> 氟化铬 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_4\">\n\u003Ctd class=\"_td_header_4\">\u003Cstrong> 英文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_4\"> chromium fluoride;chromic fluoride \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_5\">\n\u003Ctd class=\"_td_header_5\">\u003Cstrong> 别 名: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_5\"> 三氟化铬；氟化高铬 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_6\">\n\u003Ctd class=\"_td_header_6\">\u003Cstrong> 分子式: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_6\"> CrF\u003Csub>3\u003C\u002Fsub> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_7\">\n\u003Ctd class=\"_td_header_7\">\u003Cstrong> 分子量: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_7\"> 109.01 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_8\">\n\u003Ctd class=\"_td_header_8\">\u003Cstrong> 熔 点: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_8\"> >1000℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_9\">\n\u003Ctd class=\"_td_header_9\">\u003Cstrong> 密 度: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_9\"> 相对密度(水=1)3.78 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_10\">\n\u003Ctd class=\"_td_header_10\">\u003Cstrong> 蒸汽压: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_10\"> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_11\">\n\u003Ctd class=\"_td_header_11\">\u003Cstrong> 溶解性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_11\"> 不溶于水，不溶于醇，微溶于酸，溶于氢氟酸 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_12\">\n\u003Ctd class=\"_td_header_12\">\u003Cstrong> 稳定性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_12\"> 稳定 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_13\">\n\u003Ctd class=\"_td_header_13\">\u003Cstrong> 外观与性状: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_13\"> 绿色粉末或结晶 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_14\">\n\u003Ctd class=\"_td_header_14\">\u003Cstrong> 危险标记: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_14\"> 20(腐蚀品) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_15\">\n\u003Ctd class=\"_td_header_15\">\u003Cstrong> 用 途: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_15\"> 用于印染工业，用作毛织品防蛀剂、卤化催化剂、大理石硬化及着色剂 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Cbr\u002F>\n\u003Ch3>\u003C\u002Fh3>\n\u003Chr class=\"msds_hr\"\u002F>\n\u003Cb class=\"msds_title\">2.对环境的影响:\u003C\u002Fb>\n\u003Cp>一、健康危害\u003C\u002Fp>\n\u003Cp>侵入途径：吸入、食入。健康危害：具有腐蚀性。受高热分解生成氟化氢等有毒气体。\u003C\u002Fp>\n\u003Cp>二、毒理学资料及环境行为\u003C\u002Fp>\n\u003Cp>危险特性：受高热分解，放出刺激性烟气。 燃烧(分解)产物：氟化氢。\u003C\u002Fp>\n\u003Chr class=\"_hr_split_2\">\n\u003Cb class=\"_b_title_2\">3.现场应急监测方法:\u003C\u002Fb>\n\u003Cp>速测管法\u003C\u002Fp>\n\u003Chr class=\"_hr_split_3\"\u002F>\n\u003Cb class=\"_b_title_3\">4.实验室监测方法:\u003C\u002Fb>\n\u003Cp>离子选择性电极法(GB7484-87，水质)石灰滤纸-氟离子选择电极法(GB\u002FT15433-95，空气)滤膜氟离子选择电极法(GB\u002FT15434-95，空气)\u003C\u002Fp>\n\u003Chr class=\"_hr_split_4\"\u002F>\n\u003Cb class=\"_b_title_4\">5.环境标准:\u003C\u002Fb>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr class=\"_tr_16\">\n\u003Ctd class=\"_td_header_16\">中国(TJ36-79)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_16\">车间空气中有害物质的最高容许浓度\u003C\u002Ftd>\n\u003Ctd>1mg\u002Fm\u003Csup>3\u003C\u002Fsup>[F]\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_17\">\n\u003Ctd class=\"_td_header_17\">中国(TJ36-79)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_17\">居住区大气中有害物质的最高容许浓度(氟化物)\u003C\u002Ftd>\n\u003Ctd>0.02mg\u002Fm\u003Csup>3\u003C\u002Fsup>(一次值)；0.007mg\u002Fm\u003Csup>3\u003C\u002Fsup>(日均值)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_18\">\n\u003Ctd class=\"_td_header_18\">中国(GB16297-1996)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_18\">大气污染物综合排放标准(氟化物)\u003C\u002Ftd>\n\u003Ctd>①最高允许排放浓度：\u003Cbr\u002F>9-90mg\u002Fm\u003Csup>3\u003C\u002Fsup>(表2)；11-100mg\u002Fm\u003Csup>3\u003C\u002Fsup>3(表1)\u003Cbr\u002F>②最高允许排放速率(kg\u002Fh)：\u003Cbr\u002F>二级：0.10-4.2(表2)；0.12-4.9(表1)\u003Cbr\u002F>三级：0.15-6.3(表2)；0.18-7.5(表1)\u003Cbr\u002F>\u003Cdiv id=\"msdsControl\">③无组织排放监控浓度限值：\u003Cbr\u002F>0.02mg\u002Fm\u003Csup>3\u003C\u002Fsup>(表2)；0.02mg\u002Fm\u003Csup>3\u003C\u002Fsup>(表1)\u003C\u002Fdiv>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_19\">\n\u003Ctd class=\"_td_header_19\">中国(GB5048-92)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_19\">农田灌溉水质标准(氟化物)\u003C\u002Ftd>\n\u003Ctd>2.0～3.0mg\u002FL(水作，旱作，蔬菜)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_20\">\n\u003Ctd class=\"_td_header_20\">中国(GB11607-89)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_20\">渔业水质标准\u003C\u002Ftd>\n\u003Ctd>1mg\u002FL(氟化物)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_21\">\n\u003Ctd class=\"_td_header_21\">中国(GB5749-85)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_21\">生活饮用水卫生标准\u003C\u002Ftd>\n\u003Ctd>1.0mg\u002FL(氟化物)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_22\">\n\u003Ctd class=\"_td_header_22\">中国(GB\u002FT14848-93)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_22\">地下水质量标准(mg\u002FL)\u003C\u002Ftd>\n\u003Ctd>I类1.0；II类1.0；III类1.0；IV类2.0；V类2.0以上(氟化物)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_23\">\n\u003Ctd class=\"_td_header_23\">中国(GHZB1-1999)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_23\">地表水环境质量标准(mg\u002FL)\u003C\u002Ftd>\n\u003Ctd>I类1.0以下；II类1.0；III类1.0；IV类1.5；V类1.5(氟化物)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_24\">\n\u003Ctd class=\"_td_header_24\">中国(GB8978-1996)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_24\">污水综合排放标准(mg\u002FL)\u003C\u002Ftd>\n\u003Ctd>一级10；二级10～20；三级20～30(氟化物)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_25\">\n\u003Ctd class=\"_td_header_25\">中国(GB5058.3-1996)\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_25\">固体废弃物浸出毒性鉴别标准值\u003C\u002Ftd>\n\u003Ctd>50mg\u002FL(氟化物)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ch3>\u003Cbr\u002F>\u003C\u002Fh3>\n\u003Cp>6.应急处理处置方法: 一、泄漏应急处理\u003C\u002Fp>\n\u003Cp>隔离泄漏污染区，限制出入。建议应急处理人员戴自吸过滤式防尘口罩，穿防酸碱工作服。不要直接接触泄漏物。小量泄漏：避免扬尘，用洁清的铲子收集于干燥、净洁、有盖的容器中。大量泄漏：用塑料布、帆布覆盖，减少飞散。然后收集回收或运至废物处理场所处置。二、防护措施\u003C\u002Fp>\n\u003Cp>呼吸系统防护：空气中粉尘浓度超标时，建议佩戴自吸过滤式防尘口罩。 眼睛防护：戴安全防护眼镜。 防护服：穿防腐工作服。 手防护：戴防化学品手套。 其它：工作场所禁止吸烟、进食和饮水，饭前要洗手。保持良好的卫生习惯。实行就业前和定期的体检。\u003C\u002Fp>\n\u003Cp>三、急救措施\u003C\u002Fp>\n\u003Cp>皮肤接触：立即脱去被污染的衣着，用大量流动清水冲洗，至少15分钟。就医。 眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗，至少15分钟。就医。 吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。 食入：误服者用水漱口，给饮牛奶或蛋清。就医。\u003C\u002Fp>\n\u003Cp>灭火方法：灭火剂：水、二氧化碳、砂土。\u003C\u002Fp>\u003C\u002Fhr>\u003C\u002Fdiv>\n\u003C\u002Ftd>",[225,231,237,243,249,255],{"slug":226,"cid":227,"name":228,"nameZh":229,"cas":230},"785898843542654976","J-1365436-8","Lithium metagallate","偏镓酸锂","944251-30-3",{"slug":232,"cid":233,"name":234,"nameZh":235,"cas":236},"785876002248069120","J-11715-5","Lithium titanate","钛酸锂","12031-82-2",{"slug":238,"cid":239,"name":240,"nameZh":241,"cas":242},"785882279560876032","J-2854-9","Sodium tetrafluoroborate","氟硼酸钠","13755-29-8",{"slug":244,"cid":245,"name":246,"nameZh":247,"cas":248},"785943667683627008","J-1568449-7","Dilithium hydrogen phosphate","磷酸氢二锂","33943-39-4",{"slug":250,"cid":251,"name":252,"nameZh":253,"cas":254},"785889384611188736","J-27507-1","Magnesium metaborate","偏硼酸镁","13703-82-7",{"slug":256,"cid":257,"name":258,"nameZh":259,"cas":260},"785892670621880320","J-33359-3","silver","蛋白银","9015-51-4",1790105270164,"zh-CN",[]]