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六氯苯(ISO)及滴滴涕(ISO,INN)〔六氯苯别名过氯苯,滴滴涕别名[1,1,1-三氯-2,2-双（4-氯苯基）乙烷]〕。监管条件:89(禁止出口商品,禁止进口商品)。增值税率:17.0%。退税率:0.0%。最低关税:5.5%。普通关税:30.0%",{"key":329,"value":330},"申报要素","品名, 成分含量, 用途",{"key":332,"value":333},"监管条件","8.禁止出口商品 9.禁止进口商品",{"key":335,"value":336},"Summary","2903920000 perchlorobenzene。supervision conditions:89(articles on the list of prohibited export goods,articles on the list of prohibited import goods)。VAT:17.0%。tax rebate rate:0.0%。MFN tarrif:5.5%。general tariff:30.0%",[338,341,343,346,349,352,355,358,361,364,367,370,373,376,379],{"key":339,"value":340},"符号","GHS02, GHS07, GHS08, GHS09",{"key":342,"value":250},"信号词",{"key":344,"value":345},"危害声明","H225-H319-H336-H350-H411",{"key":347,"value":348},"补充危害声明","Repeated exposure may cause skin dryness or cracking.",{"key":350,"value":351},"警示性声明","P201-P210-P273-P280-P304 + P340 + P312-P308 + P313",{"key":353,"value":354},"个人防护装备","dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator 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大鼠孕后10~13d经口给予最低中毒剂量（TDLo）40mg\u002Fkg，致肌肉骨骼系统发育畸形。大鼠孕后1~22d经口给予最低中毒剂量（TDLo）6450mg\u002Fkg，致血液和淋巴系统（包括脾和骨髓）、免疫和网状内皮系统发育畸形。小鼠孕后7~16d经口给予最低中毒剂量（TDLo）1g\u002Fkg，颅面部（包括鼻、舌）、泌尿系统发育畸形。雌鼠交配前14d经口给予最低中毒剂量（TDLo）100mg\u002Fkg，致中枢神经系统发育畸形。\u003C\u002Fp>\n\u003Cp>6.致癌性 IARC致癌性评论：G2B，可疑人类致癌物。\u003C\u002Fp>\n\u003Cp>7.其他大鼠经口最低中毒剂量（TDLo）：40mg\u002Fkg（孕后10~13d用药），对胎鼠肌肉、骨骼系统有影响。小鼠经口最低中毒剂量（TDLo）：1g\u002Fkg，有胚胎毒性，对泌尿生殖系统有影响。\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>六氯苯生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1.生态毒性\u003C\u002Fp>\n\u003Cp>LC50：22mg\u002FL（96h）（黑头呆鱼，静态）；12mg\u002FL（96h）（蓝鳃太阳鱼，静态）\u003C\u002Fp>\n\u003Cp>2.生物降解性\u003C\u002Fp>\n\u003Cp>好氧生物降解（h）：23256~50136\u003C\u002Fp>\n\u003Cp>厌氧生物降解（h）：93024~200544\u003C\u002Fp>\n\u003Cp>3.非生物降解性\u003C\u002Fp>\n\u003Cp>光解最大光吸收波长范围（nm）：291~301\u003C\u002Fp>\n\u003Cp>空气中光氧化半衰期（h）：3753~37530\u003C\u002Fp>\n\u003Cp>4.生物富集性 BCF：11000~27000（鲤鱼，接触浓度0.5ppb，接触时间8周）；6000~30000（鲤鱼，接触浓度0.05ppb，接触时间8周）\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F118-74-1_951456.html#duXinDiv\">六氯苯毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>1.三氯苯氯法将三氯苯加热至110℃，保温干燥1h，能氯气氯化，反应时放出热量，起始温度100-120℃，最终温度为260-270℃，氯化10-14h，当温度开始下降时即表示氯化反应已达终点，停止通氯，将熔融的物料放入盛水的结晶箱，搅拌下六氯苯结晶成粒。用冷水洗涤，即得六氯苯。\u003C\u002Fp>\u003Cp>2.六六六无效体直接氯化法无效体经热风干燥至含水量在1%以下，加入熔融釜中，加热至150-170℃熔化，然后加入洗涤器和氯化塔。洗涤器温度保持在210-230℃，氯化塔通氯后，依照反应热慢慢升温，控制通氯速度，使反应温度每小时上升2-3℃。氯化塔的含氯尾气通入洗涤器吸收后送至副产盐酸系统。当氯化温度达260-270℃，并迅速放入盛水的结晶罐中骤冷结晶即得成品。\u003C\u002Fp>","\u003Ctd>\n\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 国标编号: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 61876 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> ＣＡＳ: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 118-74-1 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 中文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 六氯苯 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 英文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> Hexachlorobenzene；Hexachlorbenzd \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 别 名: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 灭黑穗药 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 分子式: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> C\u003Csub>6\u003C\u002Fsub>Cl\u003Csub>6\u003C\u002Fsub> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 分子量: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 284.78 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 熔 点: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 226℃ 沸点：323～326 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 密 度: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 相对密度(水=1)2.44； \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 蒸汽压: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 242℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 溶解性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 不溶于水，溶于乙醚、氯仿等多数有机溶剂 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 稳定性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 稳定 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 外观与性状: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 纯品为无色细针状或小片状晶体，工业品为淡黄色或淡棕色晶体 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 危险标记: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 14(有毒品) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 用 途: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 用作防治麦类黑穗病，种子和土壤消毒 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Cbr \u002F>\n\u003Cb> 2.对环境的影响: \u003C\u002Fb>\n\u003Cbr \u002F> 一、健康危害\n\u003Cbr \u002F>\n\u003Cbr \u002F>侵入途径：吸入、食入。\n\u003Cbr \u002F>健康危害：中毒时能影响肝脏、中枢神经系统和心血管系统。用本品拌种时引起眼刺激、烧灼感、口鼻发干、疲乏、头痛、恶心等。可致皮肤溃疡。接触者尿和粪中有大量紫质排出。 \n\u003Cbr \u002F> 二、毒理学资料及环境行为\n\u003Cbr \u002F>\n\u003Cbr \u002F>急性毒性：LD\n\u003Csub>50\u003C\u002Fsub>3500mg\u002Fkg(大鼠经口)；4000mg\u002Fkg(小鼠经口)\n\u003Cbr \u002F>亚急性和慢性毒性：动物亚急性和慢性毒性反应有神经毒性症状，肝、肾重量增加，尿中粪卟啉排泄增加等。\n\u003Cbr \u002F>致突变性：DNA损伤：鼠伤寒沙门氏菌20umol\u002FL。微粒体致突变：制酒酵母菌100ppm。\n\u003Cbr \u002F>生殖毒性：大鼠经口最低中毒剂量(TDL\n\u003Csub>0\u003C\u002Fsub>)：40mg\u002Fkg(孕后10～13天用药)，对胎鼠肌肉、骨骼系统有影响。小鼠经口最低中毒剂量(TDL\n\u003Csub>0\u003C\u002Fsub>)：1g\u002Fkg，有胚胎毒性，对泌尿生殖系统有影响。\n\u003Cbr \u002F>致癌性：IARC致癌性评论：人为可疑性反应，动物为阳性反应。 \n\u003Cbr \u002F>  危险特性：不易燃烧。受高热分解产生有毒腐蚀性烟气。\n\u003Cbr \u002F> 燃烧(分解)产物：一氧化碳、二氧化碳、氯化氢。 \n\u003Ch3>3.现场应急监测方法:\u003C\u002Fh3>\n\n\u003Cbr \u002F> 　 \n\u003Cbr \u002F>\n\u003Ch3>4.实验室监测方法:\u003C\u002Fh3>\n\u003Cbr \u002F> 气相色谱法《水和废水监测分析方法》(第三版)国家环保局编\n\u003Cbr \u002F>气相色谱法《固体废弃物试验分析评价手册》中国环境监测总站等译 \n\u003Ch3>5.环境标准:\u003C\u002Fh3>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>前苏联\u003C\u002Ftd>\n\u003Ctd>车间空气中有害物质的最高容许浓度\u003C\u002Ftd>\n\u003Ctd>0.9mg\u002Fm\u003Csup>3\u003C\u002Fsup>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>前苏联(1977) \u003C\u002Ftd>\n\u003Ctd>居民区大气中有害物最大允许浓度\u003C\u002Ftd>\n\u003Ctd>0.03mg\u002Fm\u003Csup>3\u003C\u002Fsup>(最大值，昼夜均值)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(待颁布)\u003C\u002Ftd>\n\u003Ctd>饮用水源中有害物质的最高容许浓度\u003C\u002Ftd>\n\u003Ctd>0.05mg\u002FL\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(GHZB1-1999)\u003C\u002Ftd>\n\u003Ctd>地表水环境质量标准(I、II、III类水域)\u003C\u002Ftd>\n\u003Ctd>0.05mg\u002FL\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\n\n\u003Ch3>\u003Cbr \u002F>6.应急处理处置方法:\u003Cbr \u002F>\u003C\u002Fh3>\n\u003Cbr \u002F> 一、泄漏应急处理\n\u003Cbr \u002F>\n\u003Cbr \u002F>隔离泄漏污染区，周围设警告标志，切断火源。应急处理人员戴好防毒面具，穿一般消防防护服。用洁净的铲子收集于干燥洁净有盖的容器中，用水泥、沥青或适当的热塑性材料固化处理再废弃。如大量泄漏，收集回收或无害处理后废弃。\n\u003Cbr \u002F>废弃物处置方法：目前处置方法包括焚烧法、深井灌注法和填埋法。最有效的方法是焚烧法。 \n\u003Cbr \u002F> 二、防护措施\n\u003Cbr \u002F>\n\u003Cbr \u002F>呼吸系统防护：可能接触其粉尘时，应该佩戴防毒口罩。紧急事态抢救或撤离时，建议佩戴自给式呼吸器。\n\u003Cbr \u002F>眼睛防护：必要时戴化学安全防护眼镜。\n\u003Cbr \u002F>防护服：穿工作服。\n\u003Cbr \u002F>手防护：戴防化学品手套。\n\u003Cbr \u002F>其它：工作现场禁止吸烟、进食和饮水。工作后，彻底清洗。及时换洗工作服。注意个人清洁卫生。 \n\u003Cbr \u002F> 三、急救措施\n\u003Cbr \u002F>\n\u003Cbr \u002F>皮肤接触：脱去污染的衣着，用大量清水彻底冲洗。\n\u003Cbr \u002F>眼睛接触：立即翻开上下眼睑，用流动清水或生理盐水冲洗。就医。\n\u003Cbr \u002F>吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。呼吸困难时给输氧。呼吸停止时，立即进行人工呼吸。就医。\n\u003Cbr \u002F>食入：给饮足量温水，催吐。就医。\n\u003Cbr \u002F>\n\u003Cbr \u002F>灭火方法：雾状水、泡沫、二氧化碳、干粉、砂土。\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[386,392,398,404,410,416,422,428,434,440,446,452],{"slug":387,"cid":388,"name":389,"nameZh":390,"cas":391},"785892438634926080","J-1348958-2","Benzalkonium 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