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(欧洲)","S23-S25-S36\u002F37-S61",{"key":387,"value":388},"危险品运输编码","UN 1711 6.1\u002FPG 2",{"key":390,"value":391},"WGK德国","2",{"key":393,"value":394},"RTECS号","ZE9275000",{"key":396,"value":397},"包装等级","II",{"key":399,"value":400},"危险类别","6.1",{"key":351,"value":402},"29214910","\u003Ctd>\n\n\u003Cp>\u003Cstrong>2,6-二甲基苯胺毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1、急性毒性\u003C\u002Fp>\n\u003Cp>大鼠口径LD50：8400mg\u002Fkg；小鼠口径LD50：707mg\u002Fkg；\u003C\u002Fp>\n\u003Cp>2、致畸性\u003C\u002Fp>\n\u003Cp>沙门氏菌：50umol \u002Fplate；大肠杆菌：39ug\u002Fwell；仓鼠卵巢：1mg\u002FL；\u003C\u002Fp>\n\u003Cp>3、其他多剂量毒性数据\u003C\u002Fp>\n\u003Cp>大鼠口径TDL0：3150 mg\u002Fkg\u002F20D-C；\u003C\u002Fp>\n\u003Cp>大鼠口径TDL0：6200 mg\u002Fkg\u002F2W-I；大鼠口径TDL0：13300 mg\u002Fkg\u002F4W-I；\u003C\u002Fp>\n\u003Cp>大鼠口径TDL0：20150 mg\u002Fkg\u002F13W-I；\u003C\u002Fp>\n\u003Cp>4、慢性毒性\u002F致癌性：\u003C\u002Fp>\n\u003Cp>大鼠口径TDL0：107mg\u002Fkg\u002F2Y-C；\u003C\u002Fp>\n\u003Cp>5.急性毒性 LD50：840mg\u002Fkg（大鼠经口）\u003C\u002Fp>\n\u003Cp>6.刺激性 暂无资料\u003C\u002Fp>\n\u003Cp>7.致突变性 微生物致突变：鼠伤寒沙门菌50μmol\u002F皿。细胞遗传学分析：仓鼠卵巢1g\u002FL。姐妹染色单体交换：仓鼠卵巢301mg\u002FL\u003C\u002Fp>\n\u003Cp>8.致癌性 IARC致癌性评论：组2B，对人类是可能致癌物。\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>2,6-二甲基苯胺生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1.生态毒性 EC50：330mg\u002FL（48h）（梨形四膜虫）；26.5mg\u002FL（30min）（发光菌，Microtox测试）\u003C\u002Fp>\n\u003Cp>2.生物降解性\u003C\u002Fp>\n\u003Cp>好氧生物降解（h）：672~4320\u003C\u002Fp>\n\u003Cp>厌氧生物降解（h）：2688~17280\u003C\u002Fp>\n\u003Cp>3.非生物降解性 \u003C\u002Fp>\n\u003Cp>水中光氧化半衰期（h）：62.4~3480\u003C\u002Fp>\n\u003Cp>空气中光氧化半衰期（h）：0.33~3.3\u003C\u002Fp>\n\u003Cp>4.其他有害作用 该物质对环境有危害，应特别注意对水体的污染。\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F87-62-7_951017.html#duXinDiv\">2,6-二甲基苯胺毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>1.该产品的合成路线主要有2,6-二甲基苯酚氨解法、邻甲基苯胺烷基化法、苯胺甲基化法、间二甲苯双磺化硝化法和间二甲苯硝化还原法等。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>","\u003Ctd>\n\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 国标编号: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 61753 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> ＣＡＳ: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 87-62-7 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 中文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 2，6-二甲(基)苯胺 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 英文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 2,6-dimethylaniline；2,6-Xylidine \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 别 名: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 1-氨基-2，6-二甲基苯 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 分子式: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> C\u003Csub>8\u003C\u002Fsub>H\u003Csub>11\u003C\u002Fsub>N；(CH\u003Csub>3\u003Csub>)\u003Csub>2\u003C\u002Fsub>C\u003Csub>6\u003C\u002Fsub>H\u003Csub>3\u003C\u002Fsub>NH\u003Csub>2\u003C\u002Fsub> \u003C\u002Fsub>\u003C\u002Fsub>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 分子量: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 121.18 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 熔 点: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 11.2℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 密 度: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 相对密度(水=1)0.98； \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 蒸汽压: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 91℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 溶解性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 不溶于水，溶于乙醇、乙醚 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 稳定性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 稳定 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 外观与性状: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 无色液体 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 危险标记: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 14(毒害品) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 用 途: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 用于有机合成 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Cbr \u002F>\n\u003Cb> 2.对环境的影响: \u003C\u002Fb>\n\u003Cbr \u002F>一、健康危害 \n\u003Cbr \u002F>\n\u003Cbr \u002F>侵入途径：吸入、食入、经皮吸收。 \n\u003Cbr \u002F>健康危害：毒性与苯胺相似，形成高铁血红蛋白，造成组织缺氧，引起中枢神经系统，心血管系统和其它脏器损害。其中对中枢神经系统及肝脏损害较强，对血液作用较弱，也可引起皮炎。 \n\u003Cbr \u002F>急性中毒：病人出现恶心、呕吐、手指麻木、精神恍惚，唇、指端、耳廓发绀；重谨毒时皮肤、粘膜严重青紫，出现心悸、呼吸困难、抽搐等，甚至昏迷、休克。重笃者可出现溶血性黄疸、中毒性肝炎和中毒性肾损伤。 \n\u003Cbr \u002F>慢性中毒：患者有神经衰弱综合征表现，伴有轻度发绀、贫血和肝、脾肿大。 \n\u003Cbr \u002F>\n\u003Cbr \u002F>二、毒理学资料及环境行为 \n\u003Cbr \u002F>\n\u003Cbr \u002F>毒性：属中等毒类。 \n\u003Cbr \u002F>急性毒性：LD50840mg\u002Fkg(大鼠经口)；707mg\u002Fkg(小鼠经口) \n\u003Cbr \u002F>危险特性：遇明火、高热或与氧化剂接触，有引起燃烧的危险。受热分解放出有毒的氧化氮烟气。 \n\u003Cbr \u002F>燃烧(分解)产物：一氧化碳、二氧化碳、氧化氮。 \n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cb>3.现场应急监测方法: \u003C\u002Fb>\n\u003Cbr \u002F>　 \n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cb>4.实验室监测方法: \u003C\u002Fb>\n\u003Cbr \u002F>气相色谱法《空气中有害物质的测定方法》(第二版)，杭士平主编 \n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cb>5.环境标准: \u003C\u002Fb>\n\u003Cbr \u002F>中国(TJ36-79)车间空气中有害物质的最高容许浓度 5mg\u002Fm3[皮] \n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cb>6.应急处理处置方法: \u003C\u002Fb>\n\u003Cbr \u002F>一、泄漏应急处理 \n\u003Cbr \u002F>\n\u003Cbr \u002F>疏散泄漏污染区人员至安全区，禁止无关人员进入污染区，建议应急处理人员戴自给式呼吸器，穿化学防护服。不要直接接触泄漏物，在确保安全情况下堵漏。喷雾状水，减速少蒸发。用沙土或其它不燃性吸附剂混合吸收，然后收集运至废物处理场所处置。也可以用不燃性分散剂制成的乳液刷洗，经稀释的洗水放入废水系统。如大量泄漏，建围堤收容，然后收集、转移、回收或无害处理后废弃。 \n\u003Cbr \u002F>\n\u003Cbr \u002F>二、防护措施 \n\u003Cbr \u002F>\n\u003Cbr \u002F>呼吸系统防护：可能接触其蒸气时，佩带防毒面具。紧急事态抢救或逃生时，佩带正压自给式呼吸器。 \n\u003Cbr \u002F>眼睛防护：戴安全防护眼镜。 \n\u003Cbr \u002F>防护服：穿紧袖工作服，长统胶鞋。 \n\u003Cbr \u002F>手防护：戴橡皮手套。 \n\u003Cbr \u002F>其它：工作现场禁止吸烟、进食和饮水。及时换洗工作服。工作前后不饮酒，用温水洗澡。监测毒物。进行就业前和定期的体检。 \n\u003Cbr \u002F>\n\u003Cbr \u002F>三、急救措施 \n\u003Cbr \u002F>\n\u003Cbr \u002F>皮肤接触：立即脱去污染的衣着，用肥皂水及清水彻底冲洗。注意手、足和指甲等部位。 \n\u003Cbr \u002F>眼睛接触：立即提起眼睑，用大量流动清水或生理盐水冲洗。 \n\u003Cbr \u002F>吸入：迅速脱离现场至空气新鲜处。呼吸困难时给输氧。呼吸停止时，立即时进行人工呼吸。就医。 \n\u003Cbr \u002F>食入：误服者给漱口，饮水，洗胃后口服活性炭，再给以导泻。就医。 \n\u003Cbr \u002F>\n\u003Cbr \u002F>灭火方法：雾状水、泡沫、二氧化碳、干粉、砂土。 \n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\u003Cbr 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