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\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F764-42-1_750959.html#duXinDiv\">反丁烯二腈毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>由反丁烯二酸制得，反丁烯二酸的化学性质与顺丁烯二酸相似，反丁烯二酸加热至250-300℃转变顺丁烯二酸酐，反丁烯二酸也能生成一元及二元酯或酰胺，但不能生成一元酰氯而可生成二元酰氯。反丁烯二酸酯化生成反丁烯二酸二乙酯，再经酰胺化，脱水即得反丁烯二腈。1.酰胺化将反丁烯二酸二乙酯冷至0℃，搅拌下慢慢加入氨水，加完后再搅拌4h，过滤，用少量水洗一次，晾干，得反丁烯酰胺[627-64-5]。2.脱水将上述反丁烯酰胺与五氧化二磷混匀后，加热，减压蒸馏至无馏出物为止，得反丁烯二腈粗品。将粗品溶于苯中，摇动下倒入石油醚中，过滤，凉干即得成品。  \u003C\u002Fp>","\u003Ctd>\n\r\n                                        \r\n                                        反丁烯二腈\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F> 产品名称：\n\u003Cb>Fumaronitrile\u003C\u002Fb>\n\u003Cbr \u002F> 修改号码：\n\u003Cb>5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害未分类\n\u003Cbr \u002F> 　健康危害\n\u003Cbr \u002F> 急性毒性（经口）\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F> 急性毒性（经皮）\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F> 急性毒性（吸入）\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>皮肤腐蚀\u002F刺激\u003C\u002Fb>\n\u003Cb>第2级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>严重损伤\u002F刺激眼睛\u003C\u002Fb>\n\u003Cb>2A类\u003C\u002Fb>\n\u003Cbr \u002F> 　环境危害未分类\n\u003Cbr \u002F>\n\u003Cb>GHS标签元素\u003C\u002Fb>\n\u003Cbr \u002F> 　图标或危害标志\n\u003Cbr \u002F> 　信号词危险\n\u003Cbr \u002F> 　危险描述吸入或皮肤接触或吞咽会中毒。\n\u003Cbr \u002F> 造成皮肤刺激\n\u003Cbr \u002F> 造成严重眼刺激\n\u003Cbr \u002F> 　防范说明\n\u003Cbr \u002F>\n\u003Cb>[预防]\u003C\u002Fb>避免吸入。\n\u003Cbr \u002F> 只能在室外或通风良好的环境下使用。\n\u003Cbr \u002F> 使用本产品时切勿吃东西，喝水或吸烟。\n\u003Cbr \u002F> 处理后要彻底清洗双手。\n\u003Cbr \u002F>\n\u003Cb>穿戴防护手套\u002F护目镜\u002F防护面具。\u003C\u002Fb>\n\u003Cbr \u002F> 反丁烯二腈\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>[急救措施]\u003C\u002Fb>\n\u003Cb>吸入：将受害者移到新鲜空气处，在呼吸舒适的地方保持休息。呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>食入：立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续冲洗。\n\u003Cbr \u002F>\n\u003Cb>眼睛接触：求医\u002F就诊\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：用大量肥皂和水轻轻洗。\n\u003Cbr \u002F>\n\u003Cb>若皮肤刺激：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。\u003C\u002Fb>\n\u003Cbr \u002F> 被污染的衣物清洗后方可重新使用。\n\u003Cbr \u002F>\n\u003Cb>若感不适：呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>[储存]\u003C\u002Fb>存放于通风良好处。保持容器密闭。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F>\n\u003Cb>[废弃处置]\u003C\u002Fb>\n\u003Cb>根据当地政府规定把物品\u002F容器交与工业废弃处理机构。\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>反丁烯二腈\n\u003Cbr \u002F> 百分比：\n\u003Cb>>98.0%(GC)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>764-42-1\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cb>C4H2N2\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续清洗。\n\u003Cbr \u002F>\n\u003Cb>如果眼睛刺激：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>立即呼叫解毒中心\u002F医生。漱口。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，泡沫，雾状水，二氧化碳\n\u003Cbr \u002F> 特殊危险性：小心，燃烧或高温下可能分解产生毒烟。\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F> 周围一旦着火：如果安全，移去可移动容器。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用特殊的个人防护用品（针对有毒颗粒的P3过滤式空气呼吸器）。远离溢出物\u002F泄露\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：处并处在上风处。\n\u003Cbr \u002F> 泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F> 控制和清洗的方法和材料：清扫收集粉尘，封入密闭容器。注意切勿分散。附着物或收集物应该立即根据合适的\n\u003Cbr \u002F> 法律法规处置。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：在通风良好处进行处理。穿戴合适的防护用具。防止粉尘扩散。处理后彻底清洗双手\n\u003Cbr \u002F> 和脸。\n\u003Cbr \u002F> 反丁烯二腈\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 注意事项：如果可能，使用封闭系统。如果粉尘或浮质产生，使用局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免接触皮肤、眼睛和衣物。\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于凉爽、阴暗、通风良好处。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F> 包装材料：依据法律。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统。同时安装淋浴器和洗眼器。\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：\n\u003Cb>防尘面具，自携式呼吸器（SCBA），供气呼吸器等。使用通过政府标准的呼吸器。依\u003C\u002Fb>\n\u003Cbr \u002F> 据当地和政府法规。\n\u003Cbr \u002F> 　手部防护：防渗手套。\n\u003Cbr \u002F> 　眼睛防护：护目镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防渗防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F> 固体\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>\n\u003Cbr \u002F> 外观：\n\u003Cb>晶体-粉末\u003C\u002Fb>\n\u003Cbr \u002F> 颜色：\n\u003Cb>白色-微浅黄色\u003C\u002Fb>\n\u003Cbr \u002F> 气味：无资料\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：\n\u003Cb>97°C\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>\n\u003Cb>186 °C\u003C\u002Fb>\n\u003Cbr \u002F> 闪点：无资料\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 密度：无资料\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>溶于\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>\n\u003Cbr \u002F> 溶于：\n\u003Cb>醚, 苯, 丙酮, 乙醇\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：未报道特殊反应性。\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳, 氮氧化物 (NOx), 氰化物\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>ivn-mus LD50:56 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>orl-rat LD50:132 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>ipr-mus LD50:38 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：无资料\n\u003Cbr \u002F> 对眼睛严重损害或刺激：无资料\n\u003Cbr \u002F> 生殖细胞变异原性：\n\u003Cb>sln-smc 17 mg\u002FL\u003C\u002Fb>\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F> 反丁烯二腈\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>LT2300000\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：无资料\n\u003Cbr \u002F> 甲壳类：无资料\n\u003Cbr \u002F> 藻类：无资料\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>无资料\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律无资料\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在可燃溶剂中溶解混合，在装有后燃和洗涤装置的化学焚烧炉中\n\u003Cbr \u002F> 焚烧。废弃处置时请遵守国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：\n\u003Cb>第1项 毒害品。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>\n\u003Cb>3439\u003C\u002Fb>\n\u003Cbr \u002F> 正式运输名称：\n\u003Cb>腈类, 固体, 有毒的, 不另作详细说明\u003C\u002Fb>\n\u003Cbr \u002F> 包装等级：\n\u003Cb>III\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[386,392,398,404,410,416,422,428,434,440,446,452],{"slug":387,"cid":388,"name":389,"nameZh":390,"cas":391},"785894875575881728","J-39466-1","1,3-difluoropropane","1,3-二氟丙烷","462-39-5",{"slug":393,"cid":394,"name":395,"nameZh":396,"cas":397},"785883357849325568","J-7986-7","Polydimethylsiloxane","聚二甲基硅氧烷","9016-00-6",{"slug":399,"cid":400,"name":401,"nameZh":402,"cas":403},"785888712742408192","J-922352-3","2-Methylpyrrolidine","2-甲基吡咯烷","765-38-8",{"slug":405,"cid":406,"name":407,"nameZh":408,"cas":409},"785883885836701696","J-41075-3","3-Aminopentane","3-氨基戊烷","616-24-0",{"slug":411,"cid":412,"name":413,"nameZh":414,"cas":415},"785896576466817024","J-44491-7","Polyvinyl chloride","聚氯乙烯","9002-86-2",{"slug":417,"cid":418,"name":419,"nameZh":420,"cas":421},"785889783778906112","J-28696-4","Polyvinylidene fluoride","聚偏氟乙烯","24937-79-9",{"slug":423,"cid":424,"name":425,"nameZh":426,"cas":427},"785882042352013312","J-21977-2","Cycloheptane","环庚烷","291-64-5",{"slug":429,"cid":430,"name":431,"nameZh":432,"cas":433},"785883203456995328","J-1154283-9","3,3-Dimethylpyrrolidine","3,3-二甲基吡咯烷","3437-30-7",{"slug":435,"cid":436,"name":437,"nameZh":438,"cas":439},"785872993652838400","J-1993580-9","Oxepane","氧杂环庚烷","592-90-5",{"slug":441,"cid":442,"name":443,"nameZh":444,"cas":445},"785892634022383616","J-33208-1","Allylthiourea","烯丙基硫脲","109-57-9",{"slug":447,"cid":448,"name":449,"nameZh":450,"cas":451},"785884697602297856","J-23915-6","Chlorotrifluoroethylene","三氟氯乙烯","79-38-9",{"slug":453,"cid":454,"name":455,"nameZh":456,"cas":457},"785889302788706304","J-27201-5","3-chlorocyclohexene","3-氯环己烯","2441-97-6",1794252767015,"zh-CN",[]]