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Order",{"unitPrice":132,"pack":133,"currency":27,"origin":28,"originFlag":29,"moq":21,"stock":30},120,"10g",{"slug":135,"cid":136,"imgSvg":137,"name":138,"nameZh":139,"cas":140,"formula":141,"iupac":138,"category":52,"categoryName":53,"categoryEnName":54,"industry":21,"tags":142,"offersCount":56,"supplierCount":5,"bestOffer":143},"785871842647740416","J-1333345-2","\u002Fimages\u002Fchem_structures_svg\u002F479\u002F26490-63-1.svg","COBALT TETRAFLUOROBORATE HEXAHYDRATE","四氟化硼钴水合物","26490-63-1","B2CoF8H12O6",[23],{"unitPrice":144,"pack":145,"currency":27,"origin":28,"originFlag":29,"moq":21,"stock":30},12,"100g",{"slug":147,"cid":148,"imgSvg":149,"name":150,"nameZh":151,"cas":152,"formula":153,"iupac":150,"category":52,"categoryName":53,"categoryEnName":54,"industry":21,"tags":154,"offersCount":56,"supplierCount":57,"bestOffer":155},"785871842698072064","J-814953-0","\u002Fimages\u002Fchem_structures_svg\u002F432\u002F72259-10-0.svg","Copper(II) tetrafluoroborate 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mmHg","boilingPoint",{"label":196,"labelZh":196,"value":197,"prop":198},"Density","1.3±0.1 g\u002Fcm3","density",{"label":200,"labelZh":200,"value":201,"prop":202},"Flash Point","99.8±22.6 °C","flashPoint",{"label":204,"labelZh":205,"value":206},"Exact Mass","精确质量","91.993202",{"label":208,"labelZh":208,"value":209},"PSA","76.10000",{"label":211,"labelZh":211,"value":212},"LogP","0.09",{"label":214,"labelZh":214,"value":215},"外观性状","透明液体",{"label":217,"labelZh":217,"value":218},"蒸汽密度","3.2 (vs air)",{"label":220,"labelZh":221,"value":222},"Vapor Pressure","蒸汽压","0.0±0.9 mmHg at 25°C",{"label":224,"labelZh":225,"value":226},"Refractive Index","折射率","1.503",{"label":228,"labelZh":229,"value":230},"Storage Conditions","储存条件","储存注意事项 储存于阴凉、通风的库房。远离火种、热源。保持容器密封。应与氧化剂分开存放，切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。",{"label":232,"labelZh":232,"value":233},"稳定性","1. 在空气中迅速氧化，少量铜、铁、锰离子的存在能加速氧化过程。浓度小于70%（重量）的巯基乙酸水溶液,在室温下贮存是稳定的。在高浓度时，则会生成一定量的各种自酯化物。遇明火、高热能燃烧并放出有剧毒的硫化氢气体。\n2.稳定性 稳定\n3.禁配物 强氧化剂\n4.避免接触的条件 受热\n5.聚合危害 不聚合\n6.分解产物 硫化物",{"label":235,"labelZh":235,"value":236},"水溶解性","soluble",{"label":238,"labelZh":239,"value":240},"Molecular Structure","分子结构","1、摩尔折射率：20.77\n2、摩尔体积（cm\n3\n\u002Fmol）：70.2\n3、等张比容（90.2K）：185.3\n4、表面张力（dyne\u002Fcm）：48.5\n5、介电常数：无可用的\n6、极化率（10\n-24\ncm\n3\n）：8.23\n7、单一同位素质量：91.993199 Da\n8、标称质量：92 Da\n9、平均质量：92.117 Da",{"label":242,"labelZh":243,"value":244},"Computational 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class=\"_tr_1\">\n\u003Ctd class=\"_td_header_1\">\u003Cstrong> 国标编号: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_1\"> 81611 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_2\">\n\u003Ctd class=\"_td_header_2\">\u003Cstrong> ＣＡＳ: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_2\"> 68-11-1 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_3\">\n\u003Ctd class=\"_td_header_3\">\u003Cstrong> 中文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_3\"> 巯基乙酸 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_4\">\n\u003Ctd class=\"_td_header_4\">\u003Cstrong> 英文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_4\"> thioglycolic acid;mercaptoacetic acid \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_5\">\n\u003Ctd class=\"_td_header_5\">\u003Cstrong> 别 名: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_5\"> 硫氢基乙酸；硫代乙醇酸 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_6\">\n\u003Ctd class=\"_td_header_6\">\u003Cstrong> 分子式: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_6\"> C\u003Csub>2\u003C\u002Fsub>H\u003Csub>4\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub>S；HSCH\u003Csub>2\u003C\u002Fsub>COOH \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_7\">\n\u003Ctd class=\"_td_header_7\">\u003Cstrong> 分子量: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_7\"> 92.12 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_8\">\n\u003Ctd class=\"_td_header_8\">\u003Cstrong> 熔 点: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_8\"> -16.5℃ 沸点：123℃\u002F \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_9\">\n\u003Ctd class=\"_td_header_9\">\u003Cstrong> 密 度: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_9\"> 相对密度(水=1)1.33 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_10\">\n\u003Ctd class=\"_td_header_10\">\u003Cstrong> 蒸汽压: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_10\"> >110℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_11\">\n\u003Ctd class=\"_td_header_11\">\u003Cstrong> 溶解性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_11\"> 与水混溶，可混溶于乙醇、乙醚，溶于普通溶剂 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_12\">\n\u003Ctd class=\"_td_header_12\">\u003Cstrong> 稳定性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_12\"> 稳定 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_13\">\n\u003Ctd class=\"_td_header_13\">\u003Cstrong> 外观与性状: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_13\"> 无色透明液体，有强烈令人不愉快的气味 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_14\">\n\u003Ctd class=\"_td_header_14\">\u003Cstrong> 危险标记: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_14\"> 20(酸性腐蚀品) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_15\">\n\u003Ctd class=\"_td_header_15\">\u003Cstrong> 用 途: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_15\"> 用作测定铁的试剂及稳定剂，用于药水、烫发水制造等 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Cbr\u002F>\n\u003Cb class=\"msds_title\"> 2.对环境的影响: \u003C\u002Fb>\n\u003Cbr\u002F>一、健康危害 \n\u003Cbr\u002F>\n\u003Cbr\u002F>侵入途径：吸入、食入、经皮吸收。 \n\u003Cbr\u002F>健康危害：本品的毒作用，可能是其与某些酶的巯基的特殊作用有关，本品有强烈的刺激性。眼接触可致严重损害，导致永久性失明。可致皮肤灼伤；对皮肤有致敏性，引起过敏性皮炎。能经皮肤吸收引起中毒，动物皮肤贴敷本品10%溶液<5mL\u002Fkg即引起死亡。 \n\u003Cbr\u002F>\u003Cdiv id=\"msdsControl\">\n\u003Cbr>二、毒理学资料及环境行为 \n\u003Cbr>\n\u003Cbr>毒性：属高毒类。其毒作用可能是与某些酶的巯基特殊作用有关。 \n\u003Cbr>急性毒性：LD50<50mg\u002Fkg(大鼠经口)；250mg\u002Fkg(小鼠经口) \n\u003Cbr>\n\u003Cbr>危险特性：遇明火、高热或与氧化剂接触，有引起燃烧爆炸的危险。受热分解产生有毒的硫化物烟气。具有较强的腐蚀性。 \n\u003Cbr\u002F>燃烧(分解)产物：一氧化碳、二氧化碳、硫化物。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>\n\u003Chr class=\"msds_hr\"\u002F>\n\u003Cb class=\"_b_title_2\">3.现场应急监测方法: \u003C\u002Fb>\n\u003Cbr\u002F>　 \n\u003Cbr\u002F>\n\u003Cbr\u002F>\n\u003Chr class=\"_hr_split_2\">\n\u003Cb class=\"_b_title_3\">4.实验室监测方法: \u003C\u002Fb>\n\u003Cbr\u002F>用碘-聚乙烯吡咯烷酮容量测定有机化合物：I直接测定[刊，西班牙]\u002FHernandez Mendez J.；Gonzalez Perez C.，Espada Saenz-Torre M.\u002F\u002FStud.Chem.Univ.Salamanca.-1984，(9).-57～64 《分析化学文摘》1987.8 \n\u003Cbr\u002F>\n\u003Cbr\u002F>\n\u003Chr class=\"_hr_split_3\"\u002F>\n\u003Cb class=\"_b_title_4\">5.环境标准: \u003C\u002Fb>\n\u003Cbr\u002F>前苏联 车间空气中有害物质的最高容许浓度 0.1mg\u002Fm3[皮] \n\u003Cbr\u002F>\n\u003Cbr\u002F>\n\u003Chr class=\"_hr_split_4\"\u002F>\n\u003Cb class=\"_b_title_5\">6.应急处理处置方法: \u003C\u002Fb>\n\u003Cbr\u002F>一、泄漏应急处理 \n\u003Cbr\u002F>\n\u003Cbr\u002F>迅速撤离泄漏污染区人员至安全区，并进行隔离，严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿防酸碱工作服。不要直接接触泄漏物，尽可能切断泄漏源，防止进入下水道、排洪沟等限制性空间。小量泄漏：用砂土或其它不燃材料吸附或吸收。也可以用大量水冲洗，洗水稀释后放入废水系统。大量泄漏：构筑围堤或挖坑收容；用泡沫覆盖，降低蒸气灾害。用泵转移至槽车或专用收集器内，回收或运至废物处理场所处置。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>二、防护措施 \n\u003Cbr\u002F>\n\u003Cbr\u002F>呼吸系统防护：可能接触其蒸气时，应该佩戴自吸过滤式防毒面具(半面罩)。紧急事态抢救或撤离时，建议佩戴自给式呼吸器。 \n\u003Cbr\u002F>眼睛防护：戴化学安全防护眼镜。 \n\u003Cbr\u002F>防护服：穿防酸碱工作服。 \n\u003Cbr\u002F>手防护：戴橡胶耐酸碱手套。 \n\u003Cbr\u002F>其它：工作场所禁止吸烟、进食和饮水，饭前要洗手。工作毕，淋浴更衣。单独存放被毒物污染的衣服，洗后备用。保持良好的卫生习惯。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>三、急救措施 \n\u003Cbr\u002F>\n\u003Cbr\u002F>皮肤接触：脱去被污染的衣着，用大量流动清水冲洗，至少15分钟。就医。 \n\u003Cbr\u002F>眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15分钟。就医。 \n\u003Cbr\u002F>吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。 \n\u003Cbr\u002F>食入：误服者用水漱口，洗胃。给饮牛奶或蛋清。就医。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>灭火方法：灭火剂：雾状水、泡沫、砂土。 \n\u003Cbr\u002F>\u003C\u002Fhr>\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fdiv>\n\u003C\u002Fdiv>\n\u003C\u002Ftd>",[259,265,271,277,283,289],{"slug":260,"cid":261,"name":262,"nameZh":263,"cas":264},"785873164981768192","J-1014076-9","lithium pyruvate","丙酮酸锂","2922-61-4",{"slug":266,"cid":267,"name":268,"nameZh":269,"cas":270},"785875684076556288","J-1971914-2","Oxetan-3-ylmethanol","氧杂环丁烷-3-甲醇","6246-06-6",{"slug":272,"cid":273,"name":274,"nameZh":275,"cas":276},"785889753466671104","J-1015079-3","Ethanolamine hydrochloride","乙醇胺盐酸盐","2002-24-6",{"slug":278,"cid":279,"name":280,"nameZh":281,"cas":282},"785883181285904384","J-7379-6","1,1-Dimethoxypropane","丙醛缩二甲醇","4744-10-9",{"slug":284,"cid":285,"name":286,"nameZh":287,"cas":288},"785876836004401152","J-14853-1","Lithium acetylacetonate","乙酰丙酮锂","18115-70-3",{"slug":290,"cid":291,"name":286,"nameZh":287,"cas":292},"785898548444008448","J-1314521-7","19185-99-0",1790106819982,"zh-CN",[]]