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SEVERITY，强烈反应；\u003C\u002Fp>\n\u003Cp>2、急性毒性：\u003C\u002Fp>\n\u003Cp>大鼠经口LD50：3250μL\u002Fkg；\u003C\u002Fp>\n\u003Cp>大鼠吸入LCL0：5600mg\u002Fm3\u002F4H；\u003C\u002Fp>\n\u003Cp>小鼠腹膜腔LD50：78mg\u002Fkg；\u003C\u002Fp>\n\u003Cp>兔子皮肤接触LD50：2520μL\u002Fkg；\u003C\u002Fp>\n\u003Cp>哺乳动物经口LD50：1500mg\u002Fkg；\u003C\u002Fp>\n\u003Cp>哺乳动物皮肤接触LD50：1580mg\u002Fkg；\u003C\u002Fp>\n\u003Cp>3、慢性毒性\u002F致癌性：仓鼠经口TDLo：252mg\u002Fkg\u002F20W-C\u003C\u002Fp>\n\u003Cp>4.急性毒性\u003C\u002Fp>\n\u003Cp>LD50：3250mg\u002Fkg（大鼠经口）；2520mg\u002Fkg（兔经皮）\u003C\u002Fp>\n\u003Cp>5.刺激性\u003C\u002Fp>\n\u003Cp>家兔经皮：500mg（4h），轻度刺激。\u003C\u002Fp>\n\u003Cp>家兔经眼：10mg，重度刺激。\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>对叔丁基苯酚生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1.生态毒性\u003C\u002Fp>\n\u003Cp>LC50：5.1mg\u002FL（96h）（黑头呆鱼）\u003C\u002Fp>\n\u003Cp>EC50：4.2mg\u002FL（24h）（水蚤）；0.21mg\u002FL（5min）（发光菌，Microtox毒性测试）\u003C\u002Fp>\n\u003Cp>2.生物降解性 暂无资料\u003C\u002Fp>\n\u003Cp>3.非生物降解性 暂无资料\u003C\u002Fp>\n\u003Cp>4.生物富集性 BCF：34（小球藻）\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F98-54-4_120.html#duXinDiv\">对叔丁基苯酚毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>1.由苯酚与异丁烯为原料以阳离子交换树脂作催化剂制得。\u003C\u002Fp>\u003Cp>2.由苯酚与二异丁烯反应制得。反应过程除得到叔丁基酚以外，还同时联产对辛基苯酚4-(tert-Octyl)phenol，[140-66-9]。\u003C\u002Fp>\u003Cp>3.由苯酚与叔丁醇反应，经水洗、结晶、离心分离、干燥得成品。\u003C\u002Fp>\u003Cp>4.对叔丁基酚有3种工艺路线。\u003Cbr \u002F>(1)由苯酚与异丁烯为原料制得。\u003Cbr \u002F>以阳离子交换树脂作催化剂，在流化床内于80～140℃进行催化烷基化，反应含量为60%～70%，所得混合叔丁基酚经固定床催化转位成对叔丁基酚，然后减压精馏，分离出过量苯酚再循环使用，并得产品对叔丁基酚，以异丁烯计收率为90%以上。\u003Cbr \u002F>(2)由苯酸与2,4,4-三甲基-2-戊烯(二聚异丁烯)反应而得。\u003Cbr \u002F>反应过程除得到对叔丁基酚以外，还同时联产对辛基苯酚。\u003Cbr \u002F>(3)由苯酚与叔丁醇反应而得。\u003Cbr \u002F>将无水三氯化铝与石油醚混合，搅拌下慢慢加入苯酚，用冰水冷却，再慢慢加入叔丁醇，加完后搅拌15min，再分批加入无水三氯化铝，最后搅拌4～5h，慢慢加到1∶1盐酸中，静置，分出石油层，水层用石油醚提取，合并石油醚溶液用水洗涤，分净水后回收石油醚，减压蒸馏得成品。采用此工艺进行工业生产时，合成反应在145～150℃下进行。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>采用杂多酸催化合成　将苯酚、杂多酸催化剂H4SiW12O40·狓H2O一起加入反应器中，在不断搅拌下加热到110℃，匀速通入一定量的异丁烯气体，反应4～5h，倒出反应液进行水洗、重结晶、过滤、干燥即得成品。较佳的反应条件是：反应温度110℃，苯酚与异丁烯的摩尔比为1∶2，反应时间为4.5h，催化剂用量占苯酚质量的３％，在该条件下，产品的收率可达85%，与硫酸催化合成对叔丁基苯酚相比，提高收率20%左右。\u003C\u002Fp>","\u003Ctd>\n\n\u003Ca href=\"\u002Fen\u002Fcas\u002F98-54-4_120.html#MSDSDiv\">对叔丁基苯酚MSDS英文版\u003C\u002Fa>\n\n\u003C\u002Ftd>","2026-08-21T06:59:45.532503Z",false,[399,405,411,417,423,429],{"slug":400,"cid":401,"name":402,"nameZh":403,"cas":404},"785896112765538304","J-43614-8","2,2,3,3,3-Pentafluoro-1-propanol","2,2,3,3,3-五氟-1-丙醇","422-05-9",{"slug":406,"cid":407,"name":408,"nameZh":409,"cas":410},"785893704765280256","J-36008-7","Acetaminophen","对乙酰氨基酚","103-90-2",{"slug":412,"cid":413,"name":414,"nameZh":415,"cas":416},"785882480539340800","J-4316-4","Piperonyl alcohol","胡椒醇","495-76-1",{"slug":418,"cid":419,"name":420,"nameZh":421,"cas":422},"785884071552094208","J-22803-5","Ribitol","核糖醇","488-81-3",{"slug":424,"cid":425,"name":426,"nameZh":427,"cas":428},"785891798026293248","J-1438801-5","4-Propoxyphenol","4-丙氧基苯酚","18979-50-5",{"slug":430,"cid":431,"name":432,"nameZh":433,"cas":434},"785892967020761088","J-1368507-0","4-Propylresorcinol","4-丙基间苯二酚","18979-60-7",1792611607556,"zh-CN",[]]