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极化率（10-24cm3）：15.74",{"label":234,"labelZh":235,"value":236},"Computational Chemistry","计算化学","1.疏水参数计算参考值（XlogP）:无\n2.氢键供体数量:2\n3.氢键受体数量:6\n4.可旋转化学键数量:5\n5.互变异构体数量:4\n6.拓扑分子极性表面积134\n7.重原子数量:15\n8.表面电荷:0\n9.复杂度:282\n10.同位素原子数量:0\n11.确定原子立构中心数量:0\n12.不确定原子立构中心数量:1\n13.确定化学键立构中心数量:0\n14.不确定化学键立构中心数量:0\n15.共价键单元数量:1",{"label":238,"labelZh":238,"value":239},"更多","1.熔点（ºC）：从乙醇中得白色结晶，熔点106~108",{"pictogram":241,"signal":242,"hazards":243},"Irritant","Warning",[244],"H302 — Harmful if swallowed \u002F 吞咽有害",[],[247,250,253,256,259,262,265,268],{"key":248,"value":249},"描述","Erdosteine 抑制脂多糖 (LPS) 诱导的 NF-κB 激活。",{"key":251,"value":252},"相关类别","研究领域\n>>\n代谢疾病",{"key":254,"value":255},"靶点","NF-κB",{"key":257,"value":258},"体外研究","厄多司坦是一种口服粘液溶解剂,用作各种慢性呼吸道疾病的祛痰剂。厄多司坦通过抑制LPS刺激的小鼠巨噬细胞中的NF-κB活化而发挥抗炎作用。然而,厄多司坦不抑制LPS诱导的Akt和MAPK途径的磷酸化。为了评估厄多司坦对巨噬细胞的毒性作用,分析了细胞活力。用1,10或100μg\u002F mL厄多司坦治疗不会产生可检测的细胞毒性。用LPS(1μg\u002F mL)处理诱导RAW 264.7细胞中的IκBα降解,并且在10分钟后观察到最大降解。用指定浓度的厄多司坦预处理RAW 264.7细胞6小时,然后用LPS(1μg\u002F mL)刺激10分钟。用厄多司坦预处理对IκBα的基线量没有任何影响。单独使用DMSO以与用于厄多司汀递送的体积相同的体积处理对IκBα的基线量没有任何影响。用LPS处理10分钟后IκBα的量减少,并且用指定浓度和时间的Erdosteine预处理有效抑制IκBα降解[1]。",{"key":260,"value":261},"体内研究","将26只雄性小鼠分成如下四组：第1组,对照;第2组,厄多司坦治疗;第3组,甲氨蝶呤(MTX)治疗;和第4组,甲氨蝶呤+厄多司坦治疗。在实验的第一天,向第3组和第4组腹膜内施用单剂量的甲氨蝶呤,尽管每日单剂量的厄多司汀口服给予第2组和第4组7天。在实验结束时,移除动物的睾丸并称重。甲氨蝶呤组的总抗氧化能力和总氧化应激水平以及髓过氧化物酶活性均高于对照组(p \u003C0.05)。与对照组相比,甲氨蝶呤组的脂质过氧化水平没有变化。总之,厄多司坦可有效保护甲氨蝶呤诱导的睾丸毒性。使用甲氨蝶呤的厄多司坦可改善睾丸损伤,如曲细精管中精子发生的表现所示[2]。",{"key":263,"value":264},"细胞实验","将鼠巨噬细胞\u002F单核细胞系RAW264.7在含有10％胎牛血清，60U \u002F mL青霉素和100μg\u002F mL链霉素的Dulbecco改良Eagle培养基（DMEM）中在37.8℃，5％CO 2下维持为单层。使用比色四唑化合物MTS测定法定量细胞活力。简言之，将用不同浓度的厄多司坦（1,10或100μg\u002F mL）孵育24小时的1×10 4个细胞用10μLMTS溶液（5mg \u002F mL）处理45分钟。然后用异丙醇裂解细胞，并在540nm的波长下读取吸光度[1]。",{"key":266,"value":267},"动物实验","小鼠[2]将26只雄性C57BL \u002F 6小鼠（8周，20-30g）随机分成4组。对照组（n = 6）;对小鼠腹膜内（ip）处理0.5mL盐水作为安慰剂。在厄多司坦组（n = 6）中，小鼠用口服厄多司坦（强饲法; 10mg \u002F kg）治疗7天。在该研究中，使用低剂量MTX，因为高剂量（20-40mg \u002F kg）MTX具有抗炎和免疫抑制活性。 MTX组（n = 7）中的小鼠注射单剂量的ip MTX（10mg \u002F kg）。在MTX + Erdosteine组（n = 7），第一天给小鼠注射单剂量的ip MTX（10 mg \u002F kg），第一天开始给动物口服（10 mg \u002F kg）给予厄多司坦7天。在最后一次给药后，所有大鼠禁食约12小时，但可自由饮水。然后，在实验结束时通过颈椎脱位处死动物。处死后，迅速从小鼠体内取出睾丸。将右侧睾丸标本固定在10％中性缓冲甲醛溶液中进行组织学评估[2]。",{"key":269,"value":270},"参考文献","[1].\nPark JS, et al. Anti-inflammatory Effect of Erdosteine in Lipopolysaccharide-Stimulated RAW 264.7 Cells. Inflammation. 2016 Aug;39(4):1573-81.\n[2].\nOktar S, et al. Beneficial effect of erdosteine on methotrexate-induced testicular toxicity in mice. 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General tariff:20.0%",[299,302,304,307,310,313,316,319,322],{"key":300,"value":301},"符号","GHS07",{"key":303,"value":242},"信号词",{"key":305,"value":306},"危害声明","H302",{"key":308,"value":309},"警示性声明","P301 + P312 + P330",{"key":311,"value":312},"风险声明 (欧洲)","R36\u002F37\u002F38:Irritating to eyes, respiratory system and skin .",{"key":314,"value":315},"安全声明 (欧洲)","S26-S36\u002F37\u002F39",{"key":317,"value":318},"危险品运输编码","NONH for all modes of transport",{"key":320,"value":321},"WGK德国","3",{"key":287,"value":288},"\u003Ctd>\n\n\u003Cp>\u003Cstrong>厄多司坦毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp> 小鼠、大鼠LD50(g\u002Fkg)：>10经口；>3.5静脉注射;静注>10 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F84611-23-4_325187.html#duXinDiv\">厄多司坦毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>氯乙酸乙酯和硫化钠反应后,在盐酸作用下进行酸性水解,然后在乙酰氯作用下环合得到3-硫代戊二酸酐.将高半胱氨酸巯内酯盐酸盐溶于四氢呋喃中,以氢氧化钠水溶液中和后,再和3-硫代戊二酸酐反应,并以氧化钠水溶液调pH至7～8,即得厄多司坦.\u003C\u002Fp>\u003Cp>1. 3-硫代戊二酸的制备\u003C\u002Fp>\u003Cp>在反应瓶中加入硫化钠九水合物240g(0.1mol)和乙酸乙酯200ml,搅拌混合#降温至15ºC,滴入氯乙酸乙酯290g(2.4mol),滴毕,室温搅拌4h.过滤,滤渣用乙酸乙酯洗,水层以乙酸乙酯(100ml×2)提取,合并有机层,常压蒸除bp145ºC以下馏分,冷却,加入10%盐酸720ml ,搅拌回流3h.浓缩至干,加入水100ml,冷至-5ºC,放置4h.过滤,抽干,干燥,得白色固体3-硫代戊二酸100g,收率66%,mp128~131ºC.\u003C\u002Fp>\u003Cp>2. 3-硫代戊二酸酐的制备\u003C\u002Fp>\u003Cp>在反应瓶中加入3-硫代戊二酸75g(0.5mol)和乙酰氯118g(1.5mol),搅拌混合回流3h.常压蒸馏回收乙酰氯,剩余物冷至-5ºC放置4h析晶,过滤,滤饼用无水乙醚50ml洗,干燥,得3-硫代戊二酸酐白色针状结晶53g,收率80%,mp98~101ºC.\u003C\u002Fp>\u003Cp>3. 厄多司坦的合成\u003C\u002Fp>\u003Cp>在反应瓶中加入高半胱氨酸巯内酯盐酸盐31g(0.2mol)和THF100ml,搅拌溶解,降温至低于10ºC,滴入12mol\u002FLNaOH水溶液5ml,滴毕,搅拌10min.再滴加3-硫代戊二酸酐29g(0.22mol)的THF100ml溶液,用12mol\u002FLNaOH水溶液调至Ph7~8,滴毕,升温至室温搅拌4H.分出有机层,浓缩至体积50ml左右,用5%的NaOH水溶液(50ml×3)洗,合并水相,用6mol\u002FL盐酸调至pH3.2,过滤,滤饼50 ºC干燥,无水乙醇重结晶,得厄多司坦白色固体26g,收率52.8%,mp158~161ºC.\u003C\u002Fp>\u003Cp>\u003C\u002Fp>","\u003Ctd>\n\r\n                                        \r\n                                        厄多司坦\n\u003Cb>修改号码：5.3\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F> 产品名称：\n\u003Cb>Erdosteine\u003C\u002Fb>\n\u003Cbr \u002F> 修改号码：\n\u003Cb>5.3\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害未分类\n\u003Cbr \u002F> 　健康危害未分类\n\u003Cbr \u002F> 　环境危害未分类\n\u003Cbr \u002F>\n\u003Cb>GHS标签元素\u003C\u002Fb>\n\u003Cbr \u002F> 　图标或危害标志无\n\u003Cbr \u002F> 　信号词无信号词\n\u003Cbr \u002F> 　危险描述无\n\u003Cbr \u002F> 　防范说明无\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>厄多司坦\n\u003Cbr \u002F> 百分比：\n\u003Cb>>98.0%(GC)(T)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>84611-23-4\u003C\u002Fb>\n\u003Cbr \u002F> 俗名：\n\u003Cb>N-(Tetrahydro-2-oxo-3-thienyl)-3-thiapentanedioic Acid Monoamide\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cb>C8H11NO4S2\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。若感不适请求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用水清洗皮肤\u002F淋浴。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>若皮肤刺激或发生皮疹：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续清洗。\n\u003Cbr \u002F>\n\u003Cb>如果眼睛刺激：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>若感不适，求医\u002F就诊。漱口。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，泡沫，雾状水，二氧化碳\n\u003Cbr \u002F> 特殊危险性：小心，燃烧或高温下可能分解产生毒烟。\n\u003Cbr \u002F> 厄多司坦\n\u003Cb>修改号码：5.3\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F> 周围一旦着火：如果安全，移去可移动容器。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用个人防护用品。远离溢出物\u002F泄露处并处在上风处。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F> 控制和清洗的方法和材料：清扫收集粉尘，封入密闭容器。注意切勿分散。附着物或收集物应该立即根据合适的\n\u003Cbr \u002F> 法律法规处置。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：在通风良好处进行处理。穿戴合适的防护用具。防止粉尘扩散。处理后彻底清洗双手\n\u003Cbr \u002F> 和脸。\n\u003Cbr \u002F> 注意事项：如果粉尘或浮质产生，使用局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免接触皮肤、眼睛和衣物。\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于凉爽、阴暗处。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F> 包装材料：依据法律。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统，操作人员切勿直接接触。同时安装淋浴器和洗\n\u003Cbr \u002F> 眼器。\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：防尘面具。依据当地和政府法规。\n\u003Cbr \u002F> 　手部防护：防护手套。\n\u003Cbr \u002F> 　眼睛防护：安全防护镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F> 固体\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>\n\u003Cbr \u002F> 外观：\n\u003Cb>晶体-粉末\u003C\u002Fb>\n\u003Cbr \u002F> 颜色：白色类白色\n\u003Cbr \u002F> 气味：无资料\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：\n\u003Cbr \u002F>\n\u003Cb>162°C\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>无资料\n\u003Cbr \u002F> 闪点：无资料\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 密度：无资料\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>\n\u003Cbr \u002F> 微溶于：热乙腈\n\u003Cbr \u002F> 厄多司坦\n\u003Cb>修改号码：5.3\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：未报道特殊反应性。\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳, 氮氧化物 (NOx), 硫氧化物\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>orl-rat LD50:>10 g\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>ivn-rat LD50:>3500 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：无资料\n\u003Cbr \u002F> 对眼睛严重损害或刺激：无资料\n\u003Cbr \u002F> 生殖细胞变异原性：无资料\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>AJ1476200\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：无资料\n\u003Cbr \u002F> 甲壳类：无资料\n\u003Cbr \u002F> 藻类：无资料\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>无资料\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律无资料\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在可燃溶剂中溶解混合，在装有后燃和洗涤装置的化学焚烧炉中\n\u003Cbr \u002F> 焚烧。废弃处置时请遵守国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：与联合国分类标准不一致\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>未列明\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F> 厄多司坦\n\u003Cb>修改号码：5.3\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\u003Cbr \u002F>\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[329,335,341,347,353,359],{"slug":330,"cid":331,"name":332,"nameZh":333,"cas":334},"785897799613943808","J-47958-3","Sudan I","苏丹Ⅰ","842-07-9",{"slug":336,"cid":337,"name":338,"nameZh":339,"cas":340},"785897851497484288","J-1029313-9","Lead cyanamide","氨基氰铅(2+)盐(1:1)","20837-86-9",{"slug":342,"cid":343,"name":344,"nameZh":345,"cas":346},"785884196030648320","J-23062-3","Amobam","代森铵","3566-10-7",{"slug":348,"cid":349,"name":350,"nameZh":351,"cas":352},"785876833009668096","J-14831-7","Aluminum n-butoxide","正-丁氧基铝","3085-30-1",{"slug":354,"cid":355,"name":356,"nameZh":357,"cas":358},"785875461283516416","J-1030078-9","1,1,7,7-Tetramethyl-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-8-ol","1,1,7,7-四甲基-8-羟基久洛尼定","115704-83-1",{"slug":360,"cid":361,"name":362,"nameZh":363,"cas":364},"785883686766645248","J-8750-0","D-Biotin","D-生物素","58-85-5",1792638426163,"zh-CN",[]]