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摩尔体积（cm\n3\n\u002Fmol）：152.8\n3、 等张比容（90.2K）：397.8\n4、 表面张力（dyne\u002Fcm）：45.8\n5、 极化率（10\n-24\ncm\n3\n）：19.53",{"label":239,"labelZh":240,"value":241},"Computational Chemistry","计算化学","1、 疏水参数计算参考值（XlogP）：3.9\n2、 氢键供体数量：0\n3、 氢键受体数量：4\n4、 可旋转化学键数量：2\n5、 拓扑分子极性表面积（TPSA）：58.9\n6、 重原子数：13\n7、 表面电荷：0\n8、 复杂度：265\n9、 同位素原子数量：0\n10、 确定原子立构中心数量：0\n11、 不确定原子立构中心数量：0\n12、 确定化学键立构中心数量：0\n13、 不确定化学键立构中心数量：0\n14、 共价键单元数量：1",{"label":243,"labelZh":243,"value":244},"更多","1. 性状：无色至淡黄色液体，有强烈刺激气味。\n2. 密度（g\u002FmL,25\u002F4℃）：未确定\n3. 相对蒸汽密度（g\u002FmL,空气=1）：未确定\n4. 熔点（ºC）：未确定\n5. 沸点（ºC）：251\n6. 沸点（ºC，2000Pa）：125\n7. 折射率：未确定\n8. 闪点（ºC）：未确定\n9. 比旋光度（º）：未确定\n10. 自燃点或引燃温度（ºC）：未确定\n11. 蒸气压（kPa,25ºC）：未确定\n12. 饱和蒸气压（kPa,60ºC）：未确定\n13. 燃烧热（KJ\u002Fmol）：未确定\n14. 临界温度（ºC）：未确定\n15. 临界压力（KPa）：未确定\n16. 油水（辛醇\u002F水）分配系数的对数值：未确定\n17. 爆炸上限（%,V\u002FV）：未确定\n18. 爆炸下限（%,V\u002FV）：未确定\n19. 溶解性：溶于乙醚、丙酮和其他有机溶剂。",null,[],"\u003Ctd>\n\u003Cdiv class=\"\" id=\"MSDSTbl\">\n\u003Ctable class=\"_table_all\">\n\u003Ctbody>\n\u003Ctr class=\"_tr_1\">\n\u003Ctd class=\"_td_header_1\">\u003Cstrong> 国标编号: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_1\"> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_2\">\n\u003Ctd class=\"_td_header_2\">\u003Cstrong> ＣＡＳ: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_2\"> 26471-62-5 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_3\">\n\u003Ctd class=\"_td_header_3\">\u003Cstrong> 中文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_3\"> 甲苯二异氰酸酯 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_4\">\n\u003Ctd class=\"_td_header_4\">\u003Cstrong> 英文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_4\"> Toluene diisocyanate \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_5\">\n\u003Ctd class=\"_td_header_5\">\u003Cstrong> 别 名: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_5\"> 二异氰酸甲苯酯;Diisocyanatotoluene;TDI; \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_6\">\n\u003Ctd class=\"_td_header_6\">\u003Cstrong> 分子式: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_6\"> C\u003Csub>9\u003C\u002Fsub>H\u003Csub>6\u003C\u002Fsub>N\u003Csub>2\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_7\">\n\u003Ctd class=\"_td_header_7\">\u003Cstrong> 分子量: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_7\"> 174.16 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_8\">\n\u003Ctd class=\"_td_header_8\">\u003Cstrong> 熔 点: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_8\"> 3.5～5.5 ℃(TDI-65); \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_9\">\n\u003Ctd class=\"_td_header_9\">\u003Cstrong> 密 度: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_9\"> 1.22±0.01(25℃) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_10\">\n\u003Ctd class=\"_td_header_10\">\u003Cstrong> 蒸汽压: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_10\"> 132℃(闭杯) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_11\">\n\u003Ctd class=\"_td_header_11\">\u003Cstrong> 溶解性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_11\"> 不溶于水; 溶于丙酮、乙酸乙酯和甲苯等 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_12\">\n\u003Ctd class=\"_td_header_12\">\u003Cstrong> 稳定性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_12\"> 能与强氧化剂发生反应。遇热、明火、火花会着火 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_13\">\n\u003Ctd class=\"_td_header_13\">\u003Cstrong> 外观与性状: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_13\"> 无色透明至淡黄色液体,有刺激性气味 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_14\">\n\u003Ctd class=\"_td_header_14\">\u003Cstrong> 危险标记: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_14\"> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr class=\"_tr_15\">\n\u003Ctd class=\"_td_header_15\">\u003Cstrong> 用 途: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd class=\"_td_header_content_15\"> 用于制造聚氨酯树脂及其泡沫塑料 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Cbr\u002F> 理化性质 \n\u003Cbr\u002F>\n\u003Cbr\u002F>甲苯二异氰酸酯为无色透明至淡黄色液体,有刺激性气味; 遇光颜色变深。分子式C9-H6-N2-O2。分子量174.16。相对密度1.22±0.01(25℃)。凝固点3.5～5.5 ℃(TDI-65); 11.5～13.5℃(TDI-80); 19.5～21.5℃。沸点251℃。闪点132℃(闭杯)。蒸气密度6.0。蒸气压0.13kPa(0.01mmHg20℃)。蒸气与空气混合物可燃限0.9～9.5% 。不溶于水; 溶于丙酮、乙酸乙酯和甲苯等。容易与包含有活泼氢原子的化合物:胺、水、醇、酸、碱发生反应,特别是与氢氧化钠和叔胺发生难以控制反应,并放出大量热。与水反应生成二氧化碳是聚氨酯泡沫塑料制造过程中的关键反应之一; 应避免受潮。在常温下聚合反应速度很慢,但加热至45℃以上或催化剂存在下能自聚生成二聚物。能与强氧化剂发生反应。遇热、明火、火花会着火。加热分解放出氰化物和氮氧化物。 \n\u003Cbr>\n\u003Cbr>消防措施 \n\u003Cbr>\u003Cdiv id=\"msdsControl\">\n\u003Cbr\u002F>用干粉、二氧化碳灭火，大火用水施救。消防人员须穿戴防毒面具与防护服。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>储运须知 \n\u003Cbr\u002F>\n\u003Cbr\u002F>包装标志：毒害品。包装方法：（II）类。铁桶装内充氮气。储运条件：储存于阴凉、干燥、通风良好的不燃材料结构的库房中，防止容器受损和受潮。储存温度控制在20-35℃。远离热源和火源、与胺类、醇、碱类和含水物品隔离储运。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>泄漏处理 \n\u003Cbr\u002F>\n\u003Cbr\u002F>戴好防毒面具与手套。用四倍量消灰中和后扫起，倒至空旷地方掩埋或焚烧掉。对污染的地面用肥皂或洗涤剂刷洗，经稀释的污水放入废水系统。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>接触机会 \n\u003Cbr\u002F>\n\u003Cbr\u002F>主要用于制造聚氨酯树脂及其泡沫塑料。生产和使用TDI者均可接触。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>侵入途径 \n\u003Cbr\u002F>\n\u003Cbr\u002F>主要经呼吸道吸入,不能经无损皮肤吸收。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>毒理学简介 \n\u003Cbr\u002F>\n\u003Cbr\u002F>大鼠经口LD50: 4130 mg\u002Fkg; 吸入LCLo: 600 ppm\u002F6H。小鼠经口LD50: 1950 mg\u002Fkg; 吸入LC50: 9700 ppb\u002F4H。兔经皮LD50: >10 mL\u002Fkg。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>本品急性吸入毒性较高,经口毒性较低。主要有明显刺激和致敏作用。对眼、呼吸道粘膜和皮肤有刺激作用,并引起支气管哮喘。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>人的嗅觉阈为0.35～0.92mg\u002Fm^3,另有报道为3mg\u002Fm^3。3～3.6mg\u002Fm^3时,对粘膜有刺激; 27.8mg\u002Fm^3时眼和呼吸道严重刺激。16mg\u002Fm^3,工作3～4周后,不少人出现急性上呼吸道炎; 0.5mg\u002Fm^3,工作一周,出现剧烈的咳嗽和呼吸困难。 \n\u003Cbr\u002F>TDI引起支气管哮喘,可能系异氰基团与体内的蛋白质的氨基结合后,生成异性蛋白,成为抗原诱发的变态反应; 也可同时有药理机制和刺激作用。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>2,6-TDI的刺激作用比2,4-TDI为大。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>临床表现 \n\u003Cbr\u002F>\n\u003Cbr\u002F>TDI主要影响呼吸系统。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>接触较高浓度TDI时,可产生眼和上呼吸道刺激症状。眼部有发痒、辛辣痛感、流泪、视物模糊和结膜充血等症状,可发生角膜炎或角结膜炎; 并有咽喉干燥、剧烈咳嗽、胸闷、呼吸困难,可有喘息性支气管炎等症状。严重者可出现肺水肿。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>部分工人经上述发作一次或数次之后,产生过敏。以后,即使极微量接触,亦能诱发支气管哮喘。哮喘发作前,有一定潜伏期。尤以夜间发作多见。一般脱离接触后可恢复,有时恢复较慢。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>实验室检查如变应原皮肤试验、血清抗原特异性IgE测定、变应原支气管激发试验和肺功能测定等有助诊断。参见<职业性哮喘诊断标准及处理原则>。皮肤直接接触TDI,可产生刺激性接触性皮炎,也可引起变应性接触性皮炎。 \n\u003Cbr\u002F>\n\u003Cbr\u002F>处理 \n\u003Cbr\u002F>\n\u003Cbr\u002F>过量接触者应脱离现场。对症处理。哮喘性支气管炎和支气管哮喘发作时,可给予支气管解痉剂,如氨茶碱、喘定、异丙基肾上腺素等,并可给予抗过敏、祛痰、镇咳、抗炎等药物。严重者可应用糖皮质激素。接触性皮炎的治疗可参见 \n\u003Cbr\u002F><化学物致刺激性接触性皮炎的治疗>。有明显的特应性体质者,如接触TDI后,反复发生过敏性哮喘或变应性接触性皮炎者应调离原工作。 标准 \n\u003Cbr\u002F>\n\u003Cbr\u002F>车间空气卫生标准: \n\u003Cbr\u002F>中国MAC 0.2mg\u002Fm^3; \n\u003Cbr\u002F>美国ACGIH TLV-TWA 0.036mg\u002Fm^3, STEL 0.14mg\u002Fm^3 \n\u003Cbr\u002F>OEL-FRANCE: VME 0.01 ppm (0.08 mg\u002Fm3), VLE 0.02 ppm (0.16 mg\u002Fm3), JAN1999; \n\u003Cbr\u002F>OEL-SWEDEN: TWA 0.005 ppm, CEILING 0.01 ppm, JAN1999; \n\u003Cbr\u002F>OEL-UNITED KINGDOM: TWA 0.02 mg(NCO)\u002Fm3, STEL 0.07 mg(NCO)\u002Fm3, SEP2000 \n\u003Cbr\u002F>\n\u003Cbr\u002F>危规:2,4-甲苯二异氰酸酯 GB6.1 类61111。原铁规:有机有毒品,84052。UN NO.2078。IMDG CODE 6093-1页,6.1 类。 \n\u003Cbr\u002F>\u003C\u002Fdiv>\n\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fbr>\u003C\u002Fdiv>\n\u003C\u002Ftd>",[249,255,261,267,273,279],{"slug":250,"cid":251,"name":252,"nameZh":253,"cas":254},"785912954162778112","J-277028-6","(R)-2-Amino-2-phenylethan-1-ol hydrochloride","(R)-2-氨基-2-苯基乙醇盐酸盐","85711-12-2",{"slug":256,"cid":257,"name":258,"nameZh":259,"cas":260},"851506987899293696","J-1134966-0","2-(4-aminophenyl)ethanol,hydrochloride","2-(4-氨基苯基)乙醇盐酸盐","92814-31-8",{"slug":262,"cid":263,"name":264,"nameZh":265,"cas":266},"851508040438910976","J-1134968-2","2-anilinoethanol,hydrochloride","2-苯胺基乙醇盐酸盐","41210-94-0",{"slug":268,"cid":269,"name":270,"nameZh":271,"cas":272},"851517633953009664","J-1134984-0","(S)-2-Amino-2-phenylethan-1-ol hydrochloride","(S)-2-氨基-2-苯基乙醇盐酸盐","88026-82-8",{"slug":274,"cid":275,"name":276,"nameZh":277,"cas":278},"785884388796665856","J-23317-6","Ethyl 1-piperazineacetate","1-哌嗪乙酸乙酯","40004-08-8",{"slug":280,"cid":281,"name":282,"nameZh":283,"cas":284},"785894920266190848","J-903262-2","4-Chloro-o-toluidine hydrochloride","4-氯-邻甲苯胺盐酸盐","3165-93-3",1790100180853,"zh-CN",[]]