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(US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter",{"key":368,"value":369},"危害码 (欧洲)","T:Toxic;",{"key":371,"value":372},"风险声明 (欧洲)","R23;R34",{"key":374,"value":375},"安全声明 (欧洲)","S26-S36\u002F37\u002F39-S45",{"key":377,"value":378},"危险品运输编码","3277",{"key":380,"value":381},"RTECS号","LQ5950000",{"key":383,"value":384},"包装等级","II",{"key":386,"value":387},"危险类别","6.1(a)",{"key":335,"value":336},"\u003Ctd>\n\n\u003Cp>\u003Cstrong>氯甲酸氯乙酯毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1、急性毒性：小鼠（吸入）LCLo：200mg\u002Fm3\u002F10M\u003C\u002Fp>\n\u003Cp>由于食盐的LD50是3,000 mg\u002Fkg，BPA的急性毒性程度与食盐同。 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>氯甲酸氯乙酯生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>通常对水是不危害的，若无政府许可，勿将材料排入周围环境。 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F627-11-2_415209.html#duXinDiv\">氯甲酸氯乙酯毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>其制备方法是在通光气釜内加入氯乙醇，启动搅拌，然后通过光气流量计通入光气。通光气温度为40～50℃，继续通光气20～24h，接近终点时取样分析，达标后停止通光气，然后通氮气赶走光气和氯化氢，光气进行破坏分解，赶气至pH=5～6，取样分析为产品。\u003Cbr \u002F>ClCH2CH2OH+COCl2→ClCOOCH2CH2Cl+HCl↑+CO2↑ \u003C\u002Fp>","\u003Ctd>\n\n\u003Cb>氯甲酸-2-氯乙酯\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F> 产品名称：\n\u003Cb>2-Chloroethyl Chloroformate\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害\n\u003Cbr \u002F> 易燃液体\n\u003Cb>第3级\u003C\u002Fb>\n\u003Cbr \u002F> 　健康危害\n\u003Cbr \u002F> 急性毒性（吸入）\n\u003Cb>第2级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>皮肤腐蚀\u002F刺激\u003C\u002Fb>\n\u003Cb>1B类\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>严重损伤\u002F刺激眼睛\u003C\u002Fb>\n\u003Cb>第1级\u003C\u002Fb>\n\u003Cbr \u002F> 　环境危害未分类\n\u003Cbr \u002F>\n\u003Cb>GHS标签元素\u003C\u002Fb>\n\u003Cbr \u002F> 　图标或危害标志\n\u003Cbr \u002F> 　信号词危险\n\u003Cbr \u002F> 　危险描述易燃液体和蒸气\n\u003Cbr \u002F> 吸入致命\n\u003Cbr \u002F> 造成严重的皮肤灼伤和眼损伤\n\u003Cbr \u002F> 　防范说明\n\u003Cbr \u002F>\n\u003Cb>[预防]\u003C\u002Fb>\n\u003Cb>远离热源\u002F火花\u002F明火\u002F热表面。禁烟。\u003C\u002Fb>\n\u003Cbr \u002F> 保持容器密闭。\n\u003Cbr \u002F>\n\u003Cb>使用防爆的电气\u002F通风\u002F照明设备。采取预防措施以防静电和火花引起的着火。\u003C\u002Fb>\n\u003Cbr \u002F> 切勿吸入。\n\u003Cbr \u002F> 只能在室外或通风良好的环境下使用。\n\u003Cbr \u002F> 处理后要彻底清洗双手。\n\u003Cbr \u002F> 佩戴防护面具。\n\u003Cbr \u002F>\n\u003Cb>穿戴防护手套\u002F护目镜\u002F防护面具。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>氯甲酸-2-氯乙酯\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>[急救措施]\u003C\u002Fb>\n\u003Cb>吸入：将受害者移到新鲜空气处，在呼吸舒适的地方保持休息。立即呼叫解毒中心\u002F医\u003C\u002Fb>\n\u003Cbr \u002F> 生。\n\u003Cbr \u002F> 食入：漱口。切勿催吐。\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续冲洗。\n\u003Cbr \u002F>\n\u003Cb>皮肤接触：立即去除\u002F脱掉所有被污染的衣物。用水清洗皮肤\u002F淋浴。\u003C\u002Fb>\n\u003Cbr \u002F> 被污染的衣物清洗后方可重新使用。\n\u003Cbr \u002F>\n\u003Cb>立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>[储存]\u003C\u002Fb>存放于通风良好处。保持容器密闭。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F>\n\u003Cb>[废弃处置]\u003C\u002Fb>\n\u003Cb>根据当地政府规定把物品\u002F容器交与工业废弃处理机构。\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>\n\u003Cb>氯甲酸-2-氯乙酯\u003C\u002Fb>\n\u003Cbr \u002F> 百分比：\n\u003Cb>>98.0%(T)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>627-11-2\u003C\u002Fb>\n\u003Cbr \u002F> 俗名：\n\u003Cb>Chloroformic Acid 2-Chloroethyl Ester\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cb>C3H4Cl2O2\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续清洗。\n\u003Cbr \u002F>\n\u003Cb>立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>立即呼叫解毒中心\u002F医生。漱口。切勿引吐。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，二氧化碳\n\u003Cbr \u002F> 不适用的灭火剂：水\n\u003Cbr \u002F> 特殊危险性：小心，燃烧或高温下可能分解产生毒烟。\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F>\n\u003Cb>周围一旦着火：喷水,保持容器冷却，注意切勿直接接触水。如果安全，消除一切火源\u003C\u002Fb>\n\u003Cbr \u002F> 。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用特殊的个人防护用品（自携式呼吸器）。远离溢出物\u002F泄露处并处在上风处。确保\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：足够通风。\n\u003Cbr \u002F> 泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F> 控制和清洗的方法和材料：回收到密闭容器前用干砂或惰性吸收剂吸收泄漏物。一旦大量泄漏，筑堤控制。附着\n\u003Cbr \u002F> 物或收集物应该根据相关法律法规废弃处置。\n\u003Cbr \u002F> 副危险性的防护措施切勿与水接触。移除所有火源。一旦发生火灾应该准备灭火器。使用防火花工具和防\n\u003Cbr \u002F> 爆设备。\n\u003Cbr \u002F>\n\u003Cb>氯甲酸-2-氯乙酯\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：\n\u003Cb>在通风良好处进行处理。穿戴合适的防护用具。防止烟雾产生。远离热源\u002F火花\u002F明火\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>\u002F热表面。禁烟。采取措施防止静电积累。使用防爆设备。处理后彻底清洗双手和脸。\u003C\u002Fb>\n\u003Cbr \u002F> 注意事项：如果可能，使用封闭系统。如果蒸气或浮质产生，使用通风、局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免接触皮肤、眼睛和衣物。\n\u003Cbr \u002F> 可能产生高压。小心打开。\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于冷藏防爆冰箱。\n\u003Cbr \u002F> 存放于惰性气体环境中。\n\u003Cbr \u002F> 防湿。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F>\n\u003Cb>热敏, 潮敏\u003C\u002Fb>\n\u003Cbr \u002F> 包装材料：依据法律。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统。同时安装淋浴器和洗眼器。\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：\n\u003Cb>半面罩或全面罩呼吸器，自携式呼吸器（SCBA），供气呼吸器等。依据当地和政府法\u003C\u002Fb>\n\u003Cbr \u002F> 规，使用通过政府标准的呼吸器。\n\u003Cbr \u002F> 　手部防护：防渗手套。\n\u003Cbr \u002F> 　眼睛防护：护目镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防渗防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>液体\n\u003Cbr \u002F> 外观：透明\n\u003Cbr \u002F> 颜色：\n\u003Cb>无色-极淡的黄色\u003C\u002Fb>\n\u003Cbr \u002F> 气味：无资料\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：无资料\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>\n\u003Cb>154 °C\u003C\u002Fb>\n\u003Cbr \u002F> 闪点：\n\u003Cb>60°C\u003C\u002Fb>\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 蒸气压：\n\u003Cbr \u002F>\n\u003Cb>1.73kPa\u002F48°C\u003C\u002Fb>\n\u003Cbr \u002F> 密度：\n\u003Cb>1.38\u003C\u002Fb>\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>\n\u003Cbr \u002F> 溶于：\n\u003Cb>醚, 苯, 丙酮\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：与水接触分解并产生有毒气体。\n\u003Cbr \u002F> 避免接触的条件：\n\u003Cb>火花, 明火, 静电, 湿气\u003C\u002Fb>\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳, 氯化氢\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>氯甲酸-2-氯乙酯\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>ihl-mus LCLo:200 mg\u002Fm3\u002F10M\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：无资料\n\u003Cbr \u002F> 对眼睛严重损害或刺激：无资料\n\u003Cbr \u002F> 生殖细胞变异原性：无资料\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>LQ5950000\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：无资料\n\u003Cbr \u002F> 甲壳类：无资料\n\u003Cbr \u002F> 藻类：无资料\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>无资料\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律无资料\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在装有后燃和洗涤装置的化学焚烧炉中焚烧。废弃处置时请遵守\n\u003Cbr \u002F> 国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：\n\u003Cb>第1项 毒害品。\u003C\u002Fb>\n\u003Cbr \u002F> 副危险性：\n\u003Cb>第3类：易燃液体 \u002F 第8类：腐蚀品\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>\n\u003Cb>2742\u003C\u002Fb>\n\u003Cbr \u002F> 正式运输名称：\n\u003Cb>氯甲酸盐, 有毒的, 腐蚀的, 易燃的, 不另作详细说明\u003C\u002Fb>\n\u003Cbr \u002F> 包装等级：\n\u003Cb>II\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F>\n\u003Cb>氯甲酸-2-氯乙酯\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\u003Cbr \u002F>\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[395,401,407,413,419,425],{"slug":396,"cid":397,"name":398,"nameZh":399,"cas":400},"785881870582681600","J-21323-1","3,3-Difluoropyrrolidine hydrochloride","3,3-二氟吡咯烷盐酸","163457-23-6",{"slug":402,"cid":403,"name":404,"nameZh":405,"cas":406},"785876795172851712","J-961232-3","N-Methylaniline hydrochloride","N-甲基苯胺盐酸盐","2739-12-0",{"slug":408,"cid":409,"name":410,"nameZh":411,"cas":412},"785880626237542400","J-16519-2","4-Methylaniline hydrochloride","4-甲基苯胺盐酸盐","540-23-8",{"slug":414,"cid":415,"name":416,"nameZh":417,"cas":418},"785898670607306752","J-1187807-2","Potassium (R)-3-hydroxybutyrate","(R)-3-羟基丁酸钾","110972-51-5",{"slug":420,"cid":421,"name":422,"nameZh":423,"cas":424},"785892161827639296","J-1483365-0","Lithium difluoro(oxalato)borate(1-)","二氟草酸硼酸锂","409071-16-5",{"slug":426,"cid":427,"name":428,"nameZh":429,"cas":430},"785884699149996032","J-1330439-3","Calcium malonate","丙二酸钙","19455-76-6",1792658310425,"zh-CN",[]]