[{"data":1,"prerenderedAt":-1},["ShallowReactive",2],{"currency-rates":3,"compound-J-1330829-6":8,"$fyk2oeqxpb7bd":287,"verified-suppliers-J-1330829-6":446},{"rates":4,"source":7},{"USD":5,"CNY":6},1,6.691314,"live",{"slug":9,"cid":10,"imgSvg":11,"name":12,"nameZh":12,"cas":13,"formula":14,"iupac":12,"mdl":15,"mw":16,"category":17,"categoryName":18,"categoryEnName":19,"industry":15,"tags":20,"synonyms":21,"properties":27,"ghs":86,"offers":93,"activity":94,"upstream":95,"downstream":132,"customs":193,"safetyRows":197,"toxicity":243,"synthesis":244,"msds":245,"updatedAt":246,"isProhibited":247,"related":248,"__ts":285,"__lang":286,"__slug":10},"785897803724361728","J-1330829-6","\u002Fimages\u002Fchem_structures_svg\u002F116\u002F7719-09-7.svg","氯化亚砜","7719-09-7","Cl2OS","","118.970","inorganic","无机化合物","Inorganic Chemicals",[],[22,23,24,25,26],"亚硫酰氯","二氯亚砜","二氯氧硫","氯化亚硫酰","氧氯化硫",[28,32,36,40,44,48,51,54,57,61,65,69,72,75,79,83],{"label":29,"labelZh":29,"value":30,"prop":31},"Melting Point","-105 °C","meltingPoint",{"label":33,"labelZh":33,"value":34,"prop":35},"Boiling Point","79.0±9.0 °C at 760 mmHg","boilingPoint",{"label":37,"labelZh":37,"value":38,"prop":39},"Density","2.0±0.1 g\u002Fcm3","density",{"label":41,"labelZh":41,"value":42,"prop":43},"Flash Point","105°C","flashPoint",{"label":45,"labelZh":46,"value":47},"Exact Mass","精确质量","117.904694",{"label":49,"labelZh":49,"value":50},"PSA","36.28000",{"label":52,"labelZh":52,"value":53},"LogP","0.68",{"label":55,"labelZh":55,"value":56},"外观性状","透明至黄色液体",{"label":58,"labelZh":59,"value":60},"Vapor Pressure","蒸汽压","100.3±0.1 mmHg at 25°C",{"label":62,"labelZh":63,"value":64},"Refractive Index","折射率","1.593",{"label":66,"labelZh":67,"value":68},"Storage Conditions","储存条件","储存注意事项储存于阴凉、通风的库房。库温不超过30℃，相对湿度不超过75%。保持容器密封。应与碱类等分开存放，切忌混储。储区应备有泄漏应急处理设备和合适的收容材料。",{"label":70,"labelZh":70,"value":71},"稳定性","1.遇水易分解为二氧化硫和氯化氢。溶于苯、氯仿和四氯化碳中。加热至140℃开始分解生成氯气、二氧化硫和一氯化硫。其氯原子取代羟基或巯基能力显著，有时可以取代二氧化硫、氢或氧。氯化亚砜能与有羟基的酚或醇有机化合物反应生成相应的氯化物，与磺酸反应生成磺酰氯，与格利雅试剂反应生成相应的亚砜化合物。折光能力很强，有如SO2一样令人不愉快的气味。二氯亚砜在稍高于沸点的温度下会发生明显的分解，分解产物为S2Cl2,SO2和Cl2。可溶于苯和三氯甲烷，与水反应生成SO2和HCl。\n2.非常活泼，具有强腐蚀性，其蒸气和液体对眼睛、黏膜和皮肤有强烈的刺激作用。操作时应戴防护手套，避免皮肤接触。氯化亚砜须在玻璃瓶内于室温下干燥环境中储存。它与水反应放出有毒气体HCl和SO\n2\n，由于SOCl\n2\n参与的大部分反应都会放出以上两种气体，所以必须在通风橱中进行操作。SOCl\n2\n在高于140\no\nC时会分解生成Cl\n2\n、SO\n2\n和S\n2\nCl\n2\n，铁和\u002F或锌的杂质会催化加剧该分解反应。\n3.稳定性稳定\n4.禁配物 水、碱类\n5.避免接触的条件 受热、潮湿空气\n6.聚合危害 不聚合",{"label":73,"labelZh":73,"value":74},"水溶解性","REACTS",{"label":76,"labelZh":77,"value":78},"Molecular Structure","分子结构","1、摩尔折射率：20.60\n2、摩尔体积（cm\n3\n\u002Fmol）：60.8\n3、等张比容（90.2K）：179.9\n4、表面张力（dyne\u002Fcm）：76.7\n5、极化率（10\n-24\ncm\n3\n）：8.17",{"label":80,"labelZh":81,"value":82},"Computational Chemistry","计算化学","1、疏水参数计算参考值（XlogP）：1.5\n2、氢键供体数量：0\n3、氢键受体数量：1\n4、可旋转化学键数量：0\n5、互变异构体数量：\n6、拓扑分子极性表面积（TPSA）：17.1\n7、重原子数量：4\n8、表面电荷：0\n9、复杂度：29\n10、同位素原子数量：0\n11、确定原子立构中心数量：0\n12、不确定原子立构中心数量：0\n13、确定化学键立构中心数量：0\n14、不确定化学键立构中心数量：0\n15、共价键单元数量：1",{"label":84,"labelZh":84,"value":85},"更多","1.性状：淡黄色至红色、发烟液体，有强烈刺激气味。\n2.熔点（℃）：-105\n3.沸点（℃）：76~79\n4.相对密度（水=1）：1.64\n5.相对蒸气密度（空气=1）：4.1\n6.饱和蒸气压（kPa）：13.3（21.4℃）\n7.临界压力（MPa）：4.43\n8.辛醇\u002F水分配系数：0.92\n9.溶解性：可混溶于苯、氯仿、四氯化碳等。\n10.黏度（mPa·s,0ºC）：0.80\n11.黏度（mPa·s,38ºC）：0.545\n12.蒸发热（KJ\u002Fmol）：31.32\n13.生成热（KJ\u002Fmol）：206.0\n14.电导率（S\u002Fm）：2×10\n-6\n15.蒸气压（kPa,20ºC）：13.3\n16.蒸气压（kPa,50ºC）：42.9\n17.蒸气压（kPa,70ºC）：85.0\n18.蒸气压（kPa,75ºC）：99.5\n19.体膨胀系数（K\n-1\n）：0.0010",{"pictogram":87,"signal":88,"hazards":89},"Corrosion \u002F Acute Toxicity","Danger",[90,91,92],"H302 — Harmful if swallowed \u002F 吞咽有害","H314 — Causes severe skin burns and eye damage \u002F 造成严重皮肤灼伤和眼损伤","H331 — Toxic if inhaled \u002F 吸入会中毒",[],[],[96,102,108,114,120,126],{"slug":97,"cid":98,"name":99,"nameZh":99,"cas":100,"imgSvg":101},"785882281767080000","J-2874-1","四氯化碳","56-23-5","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F445\u002F56-23-5.svg",{"slug":103,"cid":104,"name":105,"nameZh":105,"cas":106,"imgSvg":107},"785889952792580100","J-29069-6","一氧化二氯","7791-21-1","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F448\u002F7791-21-1.svg",{"slug":109,"cid":110,"name":111,"nameZh":111,"cas":112,"imgSvg":113},"785889196911890400","J-26831-0","二氯化硫","10545-99-0","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F493\u002F10545-99-0.svg",{"slug":115,"cid":116,"name":117,"nameZh":117,"cas":118,"imgSvg":119},"785897206660993000","J-46665-7","三氧化硫","7446-11-9","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F102\u002F7446-11-9.svg",{"slug":121,"cid":122,"name":123,"nameZh":123,"cas":124,"imgSvg":125},"785894658197688300","J-1308326-3","铁粉","7439-89-6","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F096\u002F7439-89-6.svg",{"slug":127,"cid":128,"name":129,"nameZh":129,"cas":130,"imgSvg":131},"785884684755144700","J-23865-4","二氧化硫","7446-09-5","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F495\u002F7446-09-5.svg",[133,139,145,151,157,163,169,175,181,187],{"slug":134,"cid":135,"name":136,"nameZh":136,"cas":137,"imgSvg":138},"785882824153501700","J-1144735-5","顺式-1,2-二氯环己烷","10498-35-8","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F138\u002F10498-35-8.svg",{"slug":140,"cid":141,"name":142,"nameZh":142,"cas":143,"imgSvg":144},"785892813924470800","J-33854-3","反式-1,2-二氯环己烷","822-86-6","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F176\u002F822-86-6.svg",{"slug":146,"cid":147,"name":148,"nameZh":148,"cas":149,"imgSvg":150},"785872677482008600","J-1992697-3","6-氯-6-氧代己酸乙酯(硫辛酸杂质)","1071-71-2","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F475\u002F1071-71-2.svg",{"slug":152,"cid":153,"name":154,"nameZh":154,"cas":155,"imgSvg":156},"785881626834899000","J-20290-3","2-苯乙硫醇","4410-99-5","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F258\u002F4410-99-5.svg",{"slug":158,"cid":159,"name":160,"nameZh":160,"cas":161,"imgSvg":162},"785875482909347800","J-10068-5","β-氯代苯乙烷","622-24-2","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F334\u002F622-24-2.svg",{"slug":164,"cid":165,"name":166,"nameZh":166,"cas":167,"imgSvg":168},"785884774504861700","J-1366928-5","环丁基甲酰氯","5006-22-4","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F303\u002F5006-22-4.svg",{"slug":170,"cid":171,"name":172,"nameZh":172,"cas":173,"imgSvg":174},"785872247414853600","J-1991507-2","丙二酸单乙酯酰氯","36239-09-5","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F193\u002F36239-09-5.svg",{"slug":176,"cid":177,"name":178,"nameZh":178,"cas":179,"imgSvg":180},"785894551414902800","J-37969-4","4-氯丁酸乙酯","3153-36-4","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F263\u002F3153-36-4.svg",{"slug":182,"cid":183,"name":184,"nameZh":184,"cas":185,"imgSvg":186},"785892761495670800","J-33596-6","2,4-二氯苯甲酸","50-84-0","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F241\u002F50-84-0.svg",{"slug":188,"cid":189,"name":190,"nameZh":190,"cas":191,"imgSvg":192},"785897992828751900","J-48726-7","4-氯丁酸甲酯","3153-37-5","https:\u002F\u002Fapi.chemical.xiaokangmed.com\u002Fimages\u002Fchem_structures_svg\u002F225\u002F3153-37-5.svg",[194],{"key":195,"value":196},"海关编码","2812101000",[198,201,203,206,209,212,215,218,221,224,227,230,233,236,239,242],{"key":199,"value":200},"符号","GHS05, GHS06",{"key":202,"value":88},"信号词",{"key":204,"value":205},"危害声明","H302-H314-H331",{"key":207,"value":208},"补充危害声明","Contact with water liberates toxic gas., Reacts violently with water.",{"key":210,"value":211},"警示性声明","P261-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P233",{"key":213,"value":214},"靶器官","Blood, Central nervous system, Liver",{"key":216,"value":217},"个人防护装备","Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter",{"key":219,"value":220},"危害码 (欧洲)","C:Corrosive;",{"key":222,"value":223},"风险声明 (欧洲)","R14;R20\u002F22;R29;R35",{"key":225,"value":226},"安全声明 (欧洲)","S26-S36\u002F37\u002F39-S45-S28-S27",{"key":228,"value":229},"危险品运输编码","UN 1836 8\u002FPG 1",{"key":231,"value":232},"WGK德国","1",{"key":234,"value":235},"RTECS号","XM5150000",{"key":237,"value":238},"包装等级","I",{"key":240,"value":241},"危险类别","8",{"key":195,"value":196},"\u003Ctd>\n\n\u003Cp>\u003Cstrong>氧氯化硫毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1、本品有毒，其蒸气刺激眼睛和黏膜，液体触及皮肤能引起烧伤。\u003C\u002Fp>\n\u003Cp>2、毒性比二氧化硫大，蒸气对呼吸道和眼结膜有明显的刺激作用。皮肤接触引起灼伤。工作场所最高容许浓度24.15mg\u002Fm3（空气中）。猫吸入85mg\u002Fm3浓度的亚硫酰（二）氯蒸气，20分钟可引起死亡。\u003C\u002Fp>\n\u003Cp>3.急性毒性 LC50：2435mg\u002Fm\u003Csup>3\u003C\u002Fsup>（大鼠吸入）\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>氧氯化硫生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp> 对水是稍微危害的，若无政府许可，勿将材料排入周围环境。 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F7719-09-7_1186895.html#duXinDiv\">氧氯化硫毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>1.氯磺酸法 先将硫黄粉加入反应器中，通入氯气进行反应生成一氯化硫。再将一定量的氯磺酸和一氯化硫加入反应器内，在50℃以下通入氯气进行反应，反应好的物料经粗馏、冷凝，收集130℃以下的料液送至精馏锅，为了使低沸点的二氯化硫转变成一氯化硫留在锅内，则要加入粗品数量的15%～20%硫黄，然后送去精馏，经回流4h，色泽正常后，收集气相75～80℃的馏分，制得亚硫酰氯成品。其反应方程式如下：\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>2.二氧化硫法 以硫黄、液氯和液体二氧化硫为原料，采用全循环和液相循环法，生产高纯度氯化亚砜矾，纯度99%以上，该方法工艺先进，产品质量稳定，“三废”排放少。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>图XVI-4 制备SOCL2的制备\u003C\u002Fp>\u003Cp>二氯亚砜也叫亚硫酰二氯或氯化亚硫酰。\u003C\u002Fp>\u003Cp>图制备SOCl2的装置\u003C\u002Fp>\u003Cp>1—烧瓶1；2—烧瓶2；3—密封磨口\u003C\u002Fp>\u003Cp>(1).在如图所示的烧瓶1中加入纯净的发烟硫酸，在烧瓶2中加入SCl2。慢慢加热烧瓶1，并用冰水冷却烧瓶2，SO3进入SCl2中即开始发生反应，放出的SO2通过通风柜排出。当反应完成后将1拆除并密封磨口3，在隔绝湿气的条件下慢慢进行蒸馏。然后在中间馏分中加入硫，仔细地分馏数次。获取76～77℃完全无色的馏分为最后产品。\u003C\u002Fp>\u003Cp>(2).用一装有回流冷凝管的250mL双口烧瓶作反应器，反应器经彻底干燥后放入100g PCl5。冷凝管的上端联接一支CaCl2干燥管，在反应器的另一口中插入一根导气管至瓶底。从导气管中通入经仔细干燥过的SO2气体，摇荡反应瓶以加速反应进行。数小时后，PCl5全部溶解，反应即完成。用高效能的分馏柱仔细分馏产物数次，可得SOCl2产品。\u003C\u002Fp>\u003Cp>精制方法：工业品的亚硫酸（二）氯中常含有硫酰氯、一氯化硫和二氯化硫等杂质，一般重蒸一次即可使用，但仍带有黄色。若需高纯度的产品，可将450mL亚硫酰（二）氯与12.5g硫加热回流4.5小时，然后用高效分馏柱分馏两次可得无色纯品。也可在亚磷酸三苯酯存在下进行蒸馏精制。\u003C\u002Fp>\u003Cp>3.在干燥的五氯化磷中通入干燥的二氧化硫气体，在搅拌下边回流边反应，反应放出的热量将五氯化磷熔融：\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>待五氯化磷完全熔融后，加热混合物并搅拌均匀。然后精馏混合物数次，收集77～80℃馏分，即得试剂氯化亚砜。\u003C\u002Fp>","\u003Ctd>\n\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>1.1 产品标识符\u003C\u002Fb>\n\u003Cbr \u002F> : 氯化亚砜\n\u003Cbr \u002F> 产品名称\n\u003Cbr \u002F>\n\u003Cb>1.2 鉴别的其他方法\u003C\u002Fb>\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F>\n\u003Cb>1.3 有关的确定了的物质或混合物的用途和建议不适合的用途\u003C\u002Fb>\n\u003Cbr \u002F> 仅用于研发。不作为药品、家庭或其它用途。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>2.1 GHS-分类\u003C\u002Fb>\n\u003Cbr \u002F> 急性毒性, 经口 (类别 4)\n\u003Cbr \u002F> 急性毒性, 吸入 (类别 3)\n\u003Cbr \u002F> 皮肤腐蚀 (类别 1A)\n\u003Cbr \u002F> 严重眼睛损伤 (类别 1)\n\u003Cbr \u002F>\n\u003Cb>2.2 GHS 标记要素，包括预防性的陈述\u003C\u002Fb>\n\u003Cbr \u002F> 象形图\n\u003Cbr \u002F> 警示词危险\n\u003Cbr \u002F> 危险申明\n\u003Cbr \u002F> H302吞咽有害。\n\u003Cbr \u002F> H314造成严重皮肤灼伤和眼损伤。\n\u003Cbr \u002F> H331吸入会中毒。\n\u003Cbr \u002F> 警告申明\n\u003Cbr \u002F> 预防措施\n\u003Cbr \u002F> P261避免吸入粉尘\u002F烟\u002F气体\u002F烟雾\u002F蒸气\u002F喷雾.\n\u003Cbr \u002F> P264操作后彻底清洁皮肤。\n\u003Cbr \u002F> P270使用本产品时不要进食、饮水或吸烟。\n\u003Cbr \u002F> P271只能在室外或通风良好之处使用。\n\u003Cbr \u002F> P280戴防护手套\u002F穿防护服\u002F戴护目镜\u002F戴面罩.\n\u003Cbr \u002F> 事故响应\n\u003Cbr \u002F> P301 + P330 + P331如果吞咽：漱口，不要催吐。\n\u003Cbr \u002F> P303 + P361 + P353如果皮肤（或头发）接触：立即除去∕脱掉所有沾污的衣物。用水清洗皮肤∕\n\u003Cbr \u002F> 淋浴。\n\u003Cbr \u002F> P304 + P340如果吸入：将受害人移至空气新鲜处并保持呼吸舒适的姿势休息。\n\u003Cbr \u002F> P305 + P351 + P338如与眼睛接触，用水缓慢温和地冲洗几分钟。如戴隐形眼镜并可方便地取\n\u003Cbr \u002F> 出，取出隐形眼镜，然后继续冲洗.\n\u003Cbr \u002F> P310立即呼叫中毒控制中心或医生.\n\u003Cbr \u002F> P321具体处置（见本标签上提供的急救指导）。\n\u003Cbr \u002F> P363沾污的衣服清洗后方可再用。\n\u003Cbr \u002F> 安全储存\n\u003Cbr \u002F> P403 + P233存放于通风良的地方。 保持容器密闭。\n\u003Cbr \u002F> P405存放处须加锁。\n\u003Cbr \u002F> 废弃处置\n\u003Cbr \u002F> P501将内容物\u002F 容器处理到得到批准的废物处理厂。\n\u003Cbr \u002F>\n\u003Cb>2.3 其它危害物\u003C\u002Fb>\n\u003Cbr \u002F> 遇水剧烈反应。, 遇水即释放出毒气。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>3.1 物 质\u003C\u002Fb>\n\u003Cbr \u002F> : Cl2OS\n\u003Cbr \u002F> 分子式\n\u003Cbr \u002F> : 118.97 g\u002Fmol\n\u003Cbr \u002F> 分子量\n\u003Cbr \u002F> 组分浓度或浓度范围\n\u003Cbr \u002F> Thionyl chloride\n\u003Cbr \u002F> <=100%\n\u003Cbr \u002F> 化学文摘登记号(CAS7719-09-7\n\u003Cbr \u002F> No.)231-748-8\n\u003Cbr \u002F> EC-编号016-015-00-0\n\u003Cbr \u002F> 索引编号\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>4.1 必要的急救措施描述\u003C\u002Fb>\n\u003Cbr \u002F> 一般的建议\n\u003Cbr \u002F> 请教医生。 向到现场的医生出示此安全技术说明书。\n\u003Cbr \u002F> 吸入\n\u003Cbr \u002F> 如果吸入,请将患者移到新鲜空气处。 如呼吸停止,进行人工呼吸。 请教医生。\n\u003Cbr \u002F> 皮肤接触\n\u003Cbr \u002F> 立即脱掉被污染的衣服和鞋。 用肥皂和大量的水冲洗。 立即将患者送往医院。 请教医生。\n\u003Cbr \u002F> 眼睛接触\n\u003Cbr \u002F> 用大量水彻底冲洗至少15分钟并请教医生。\n\u003Cbr \u002F> 食入\n\u003Cbr \u002F> 禁止催吐。 切勿给失去知觉者通过口喂任何东西。 用水漱口。 请教医生。\n\u003Cbr \u002F>\n\u003Cb>4.2 主要症状和影响，急性和迟发效应\u003C\u002Fb>\n\u003Cbr \u002F> 该物质对粘膜组织和上呼吸道、眼睛和皮肤破坏巨大。\n\u003Cbr \u002F>\n\u003Cb>4.3 及时的医疗处理和所需的特殊处理的说明和指示\u003C\u002Fb>\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>5.1 灭火介质\u003C\u002Fb>\n\u003Cbr \u002F> 灭火方法及灭火剂\n\u003Cbr \u002F> 干粉\n\u003Cbr \u002F>\n\u003Cb>5.2 源于此物质或混合物的特别的危害\u003C\u002Fb>\n\u003Cbr \u002F> 硫氧化物, 氯化氢气体\n\u003Cbr \u002F>\n\u003Cb>5.3 给消防员的建议\u003C\u002Fb>\n\u003Cbr \u002F> 如必要的话,戴自给式呼吸器去救火。\n\u003Cbr \u002F>\n\u003Cb>5.4 进一步信息\u003C\u002Fb>\n\u003Cbr \u002F> 水解物质释放酸性气体，与金属表面接触能产生可燃和\u002F或爆炸性的氢气。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄露应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>6.1 作业人员防护措施、防护装备和应急处置程序\u003C\u002Fb>\n\u003Cbr \u002F> 戴呼吸罩。 避免吸入蒸气、烟雾或气体。 保证充分的通风。 人员疏散到安全区域。\n\u003Cbr \u002F>\n\u003Cb>6.2 环境保护措施\u003C\u002Fb>\n\u003Cbr \u002F> 如能确保安全，可采取措施防止进一步的泄漏或溢出。 不要让产品进入下水道。\n\u003Cbr \u002F>\n\u003Cb>6.3 泄漏化学品的收容、清除方法及所使用的处置材料\u003C\u002Fb>\n\u003Cbr \u002F> 用惰性吸附材料吸收并当作危险废物处理。 不要用水冲洗。 放入合适的封闭的容器中待处理。\n\u003Cbr \u002F>\n\u003Cb>6.4 参考其他部分\u003C\u002Fb>\n\u003Cbr \u002F> 丢弃处理请参阅第13节。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>7.1 安全操作的注意事项\u003C\u002Fb>\n\u003Cbr \u002F> 避免接触皮肤和眼睛。 避免吸入蒸气和烟雾。\n\u003Cbr \u002F>\n\u003Cb>7.2 安全储存的条件,包括任何不兼容性\u003C\u002Fb>\n\u003Cbr \u002F> 贮存在阴凉处。 使容器保持密闭，储存在干燥通风处。\n\u003Cbr \u002F> 打开了的容器必须仔细重新封口并保持竖放位置以防止泄漏。\n\u003Cbr \u002F> 不要与水接触。贮存期间严禁与水接触。\n\u003Cbr \u002F> 充气操作和储存\n\u003Cbr \u002F>\n\u003Cb>7.3 特定用途\u003C\u002Fb>\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>8.1 容许浓度\u003C\u002Fb>\n\u003Cbr \u002F> 最高容许浓度\n\u003Cbr \u002F>\n\u003Cb>8.2 暴露控制\u003C\u002Fb>\n\u003Cbr \u002F> 适当的技术控制\n\u003Cbr \u002F> 避免与皮肤、眼睛和衣服接触。 休息前和操作本品后立即洗手。\n\u003Cbr \u002F> 个体防护设备\n\u003Cbr \u002F> 眼\u002F面保护\n\u003Cbr \u002F> 紧密装配的防护眼镜请使用经官方标准如NIOSH (美国) 或 EN 166(欧盟)\n\u003Cbr \u002F> 检测与批准的设备防护眼部。\n\u003Cbr \u002F> 皮肤保护\n\u003Cbr \u002F> 戴手套取 手套在使用前必须受检查。\n\u003Cbr \u002F> 请使用合适的方法脱除手套(不要接触手套外部表面),避免任何皮肤部位接触此产品.\n\u003Cbr \u002F> 使用后请将被污染过的手套根据相关法律法规和有效的实验室规章程序谨慎处理. 请清洗并吹干双手\n\u003Cbr \u002F> 所选择的保护手套必须符合EU的89\u002F686\u002FEEC规定和从它衍生出来的EN 376标准。\n\u003Cbr \u002F> 完全接触\n\u003Cbr \u002F> 物料: 氟橡胶\n\u003Cbr \u002F> 最小的层厚度 0.7 mm\n\u003Cbr \u002F> 溶剂渗透时间: 480 min\n\u003Cbr \u002F> 测试过的物质Vitoject® (KCL 890 \u002F Z677698, 规格 M)\n\u003Cbr \u002F> 飞溅保护\n\u003Cbr \u002F> 物料: 丁基橡胶\n\u003Cbr \u002F> 最小的层厚度 0.3 mm\n\u003Cbr \u002F> 溶剂渗透时间: 101 min\n\u003Cbr \u002F> 测试过的物质Butoject® (KCL 897 \u002F Z677647, 规格 M)\n\u003Cbr \u002F> , 测试方法 EN374\n\u003Cbr \u002F> 如果以溶剂形式应用或与其它物质混合应用，或在不同于EN\n\u003Cbr \u002F> 374规定的条件下应用，请与EC批准的手套的供应商联系。\n\u003Cbr \u002F> 这个推荐只是建议性的,并且务必让熟悉我们客户计划使用的特定情况的工业卫生学专家评估确认才可.\n\u003Cbr \u002F> 这不应该解释为在提供对任何特定使用情况方法的批准.\n\u003Cbr \u002F> 身体保护\n\u003Cbr \u002F> 全套防化学试剂工作服, 阻燃防护服,\n\u003Cbr \u002F> 防护设备的类型必须根据特定工作场所中的危险物的浓度和数量来选择。\n\u003Cbr \u002F> 呼吸系统防护\n\u003Cbr \u002F> 如危险性评测显示需要使用空气净化的防毒面具，请使用全面罩式多功能防毒面具（US）或ABEK型\n\u003Cbr \u002F> （EN\n\u003Cbr \u002F> 14387）防毒面具筒作为工程控制的候补。如果防毒面具是保护的唯一方式，则使用全面罩式送风防\n\u003Cbr \u002F> 毒面具。 呼吸器使用经过测试并通过政府标准如NIOSH（US）或CEN（EU）的呼吸器和零件。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>9.1 基本的理化特性的信息\u003C\u002Fb>\n\u003Cbr \u002F> a) 外观与性状\n\u003Cbr \u002F> 形状: 液体, 透明\n\u003Cbr \u002F> b) 气味\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> c) 气味阈值\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> d) pH值\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> e) 熔点\u002F凝固点\n\u003Cbr \u002F> 熔点\u002F凝固点: -105 °C\n\u003Cbr \u002F> f) 沸点、初沸点和沸程\n\u003Cbr \u002F> 79 °C\n\u003Cbr \u002F> g) 闪点\n\u003Cbr \u002F> 不适用\n\u003Cbr \u002F> h) 蒸发速率\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> i) 易燃性(固体,气体)\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> j) 高的\u002F低的燃烧性或爆炸性限度 无数据资料\n\u003Cbr \u002F> k) 蒸气压\n\u003Cbr \u002F> 129 hPa 在 20 °C\n\u003Cbr \u002F> l) 蒸汽密度\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> m) 密度\u002F相对密度\n\u003Cbr \u002F> 1.64 g\u002FmL 在 20 °C1.631 g\u002FmL 在 25 °C\n\u003Cbr \u002F> n) 水溶性\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> o) n-辛醇\u002F水分配系数\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> p) 自燃温度\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> q) 分解温度\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> r) 粘度\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应活性\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>10.1 反应性\u003C\u002Fb>\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F>\n\u003Cb>10.2 稳定性\u003C\u002Fb>\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F>\n\u003Cb>10.3 危险反应\u003C\u002Fb>\n\u003Cbr \u002F> 遇水剧烈反应。\n\u003Cbr \u002F>\n\u003Cb>10.4 应避免的条件\u003C\u002Fb>\n\u003Cbr \u002F> 防治容器进水以免发生剧烈反应。\n\u003Cbr \u002F> 暴露在潮湿中。\n\u003Cbr \u002F>\n\u003Cb>10.5 不相容的物质\u003C\u002Fb>\n\u003Cbr \u002F> 醇类, 胺, 金属, 遇水剧烈反应。\n\u003Cbr \u002F>\n\u003Cb>10.6 危险的分解产物\u003C\u002Fb>\n\u003Cbr \u002F> 其它分解产物 - 无数据资料\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学资料\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>11.1 毒理学影响的信息\u003C\u002Fb>\n\u003Cbr \u002F> 急性毒性\n\u003Cbr \u002F> 半数致死剂量 (LD50) 经口 - 大鼠 - 324 mg\u002Fkg\n\u003Cbr \u002F> 半数致死浓度（LC50） 吸入 - 大鼠 - 4 h - 2.72 mg\u002Fl\n\u003Cbr \u002F> 皮肤刺激或腐蚀\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 眼睛刺激或腐蚀\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 呼吸道或皮肤过敏\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 生殖细胞致突变性\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 致癌性\n\u003Cbr \u002F> IARC:\n\u003Cbr \u002F> 此产品中没有大于或等于 0。1%含量的组分被 IARC鉴别为可能的或肯定的人类致癌物。\n\u003Cbr \u002F> 生殖毒性\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 特异性靶器官系统毒性（一次接触）\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 特异性靶器官系统毒性（反复接触）\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 吸入危险\n\u003Cbr \u002F> 无数据资料\n\u003Cbr \u002F> 潜在的健康影响\n\u003Cbr \u002F> 吸入吸入会中毒。 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