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其他不饱和无环烃。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:2.0%。普通关税:30.0%",{"key":331,"value":332},"申报要素","品名, 成分含量, 用途, 用作气体燃料的应报明包装容器容积, 散装货物应报明",{"key":334,"value":335},"Summary","2901299090 unsaturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%",[337,340,342,344,347,350,353,356,359,362,365,368,371,374],{"key":338,"value":339},"符号","GHS08",{"key":341,"value":256},"信号词",{"key":343,"value":258},"危害声明",{"key":345,"value":346},"警示性声明","P301 + P310-P331",{"key":348,"value":349},"个人防护装备","Eyeshields;Gloves",{"key":351,"value":352},"危害码 (欧洲)","F",{"key":354,"value":355},"风险声明 (欧洲)","R36\u002F37\u002F38",{"key":357,"value":358},"安全声明 (欧洲)","S24\u002F25",{"key":360,"value":361},"危险品运输编码","NONH for all modes of transport",{"key":363,"value":364},"WGK德国","2",{"key":366,"value":367},"RTECS号","XB6010000",{"key":369,"value":370},"包装等级","II; III",{"key":372,"value":373},"危险类别","4.1",{"key":325,"value":375},"29012980","\u003Ctd>\n\n\u003Cp>\u003Cstrong>角鲨烯毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1、 急性毒性：小鼠经口LD5O：5gm\u002Fkg\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>角鲨烯生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp> 该物质对水体有稍微的危害。 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F111-02-4_165516.html#duXinDiv\">角鲨烯毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>方法一、以鲨鱼肝油为原料\u003Cbr \u002F>将鲨鱼肝油减压蒸馏，得3.5%的含姥鲨烷初馏分，除去，残留油(96.5%)于533.28-666.61Pa(4-5mmHg)蒸馏，至242℃几无馏出物。此馏出物1450g先用氢氧化钠处理除去游离酸，于金属钠上在666.61Pa(5mmHg)压力下蒸馏，制得角鲨烯成品。此馏出物1383g分4次于1.333kPa(10mmHg)压力下分馏，第I馏分至油浴282℃始馏出。\u003Cbr \u002F>鲨鱼肝油[脱酸，减压蒸馏]→[减压蒸馏]→[钠]角鲨烯成品\u003Cbr \u002F>方法二、以鲨鱼肝为原料\u003Cbr \u002F>浓缩液的制备 取鲨鱼肝，水洗切碎，用双层锅以100℃的蒸气蒸4h再提取，得提取液，浓缩，得浓缩液。\u003Cbr \u002F>鲨鱼肝（碎）[100℃蒸汽, 4h]→提取液[浓缩]→浓缩液\u003Cbr \u002F>角鲨烯成品的制备 将浓缩液放置一昼夜，自然冷却，再提取上清液，加酸性黏土搅拌，放置一昼夜，除去沉淀，得上清液，上清液精制1次，用2号滤纸过滤，得角鲨烯成品。\u003Cbr \u002F>浓缩液→上清液[酸性黏土]→上清液[精制]→鱼鲨烯成品\u003Cbr \u002F>方法三、以鲨肝为原料\u003Cbr \u002F>粗制油的制备 取900g新鲜的冰冻鲸鲨肝脏，去血水，剪碎，分3次 (每次300g)置于高速捣碎机中，每份组织加入250ml蒸馏水，匀浆2min，倾入 2000ml烧杯中，于80℃左右水温中加热，并用1mol\u002FL氢氧化钠溶液调节肝匀浆Ph至9左右，不断搅拌，加热约1h左右，趁热离心(3000r\u002Fmin，20min)，吸取上层黄色油状物，用饱和氯化钠溶液洗涤2-3次，再用蒸馏水洗至Ph呈中性，约得300ml粗制油。\u003Cbr \u002F>鲨鱼肝[捣碎]→匀浆[皂化，分离]→[NaOH, 80℃]黄色油状物[NaCl, H2O]→粗制油\u003Cbr \u002F>角鲨烯的精制 取1份170ml粗制品，置于真空蒸馏烧瓶中，以硅油浴加热，进行减压蒸馏，当内温为85-140℃；真空度为6-1.2Pa时，开始出现第I馏分，为黄色油状物，约40ml。当内温升至190-206℃，真空度为0.8-0.4Pa，收集第II馏分，为淡黄色油状物，约78ml。\u003Cbr \u002F>将第II馏分的油状物置于装有分馏塔的真空蒸馏烧瓶中，再次进行减压蒸馏。当内温为190℃，真空度为0.53Pa开始出现淡黄色油状物，约20ml。当内温升至195-200℃真空度为0.4-0.13Pa，收集无色透明的油状物，约35ml，即为精制的鲨烯产品。\u003Cbr \u002F>粗制油[硅油浴]→[190-206℃， 0.8-0.4Pa]淡黄色油状物[减压浓缩]→[195-200℃, 0.4-0.13Pa]精制鱼鲨烯。\u003C\u002Fp>\u003Cp>方法四：\u003C\u002Fp>\u003Cp>烟草：OR，57。\u003C\u002Fp>\u003Cp>方法五：\u003C\u002Fp>\u003Cp>从烟气中得到的角鲨烯中有痕量异构体。\u003C\u002Fp>","\u003Ctd>\n\r\n                                        \r\n                                        角鲨烯\n\u003Cb>修改号码：6\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F> 产品名称：\n\u003Cb>Squalene\u003C\u002Fb>\n\u003Cbr \u002F> 修改号码：\n\u003Cb>6\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害未分类\n\u003Cbr \u002F> 　健康危害\n\u003Cbr \u002F> 急性毒性（经口）\n\u003Cb>第5级\u003C\u002Fb>\n\u003Cbr \u002F> 　环境危害未分类\n\u003Cbr \u002F>\n\u003Cb>GHS标签元素\u003C\u002Fb>\n\u003Cbr \u002F> 　图标或危害标志无\n\u003Cbr \u002F> 　信号词警告\n\u003Cbr \u002F> 　危险描述吞咽可能有害。\n\u003Cbr \u002F> 　防范说明\n\u003Cbr \u002F>\n\u003Cb>[急救措施]\u003C\u002Fb>\n\u003Cb>若感不适：呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>角鲨烯\n\u003Cbr \u002F> 百分比：\n\u003Cb>>98.0%(GC)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>111-02-4\u003C\u002Fb>\n\u003Cbr \u002F> 俗名：\n\u003Cb>2,6,10,15,19,23-Hexamethyl-2,6,10,14,18,22-tetracosahexaene\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cb>C30H50\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。若感不适立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>若皮肤刺激或发生皮疹：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续清洗。\n\u003Cbr \u002F>\n\u003Cb>如果眼睛刺激：求医\u002F就诊。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>若感不适，呼叫解毒中心\u002F医生。漱口。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F> 角鲨烯\n\u003Cb>修改号码：6\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，泡沫，二氧化碳\n\u003Cbr \u002F> 不适用的灭火剂：水（有可能扩大灾情。）\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F> 周围一旦着火：如果安全，移去可移动容器。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用个人防护用品。远离溢出物\u002F泄露处并处在上风处。确保足够通风。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F> 控制和清洗的方法和材料：用合适的吸收剂（如：旧布，干砂，土，锯屑）吸收泄漏物。一旦大量泄漏，筑堤控\n\u003Cbr \u002F> 制。附着物或收集物应该立即根据合适的法律法规废弃处置。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：在通风良好处进行处理。穿戴合适的防护用具。防止烟雾产生。处理后彻底清洗双手\n\u003Cbr \u002F> 和脸。\n\u003Cbr \u002F> 注意事项：如果蒸气或浮质产生，使用通风、局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免接触皮肤、眼睛和衣物。\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于凉爽、阴暗处。\n\u003Cbr \u002F> 存放于惰性气体环境中。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F>\n\u003Cb>光敏, 气敏\u003C\u002Fb>\n\u003Cbr \u002F> 包装材料：依据法律。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统，操作人员切勿直接接触。同时安装淋浴器和洗\n\u003Cbr \u002F> 眼器。\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：防毒面具。依据当地和政府法规。\n\u003Cbr \u002F> 　手部防护：防护手套。\n\u003Cbr \u002F> 　眼睛防护：安全防护镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>液体\n\u003Cbr \u002F> 外观：透明\n\u003Cbr \u002F> 颜色：\n\u003Cb>无色-浅黄色\u003C\u002Fb>\n\u003Cbr \u002F> 气味：无资料\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：\n\u003Cbr \u002F>\n\u003Cb>-5°C\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>\n\u003Cb>252 °C\u002F0.7kPa\u003C\u002Fb>\n\u003Cbr \u002F> 闪点：\n\u003Cb>220°C\u003C\u002Fb>\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 密度：\n\u003Cb>0.86\u003C\u002Fb>\n\u003Cbr \u002F> 角鲨烯\n\u003Cb>修改号码：6\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>不溶于\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>\n\u003Cbr \u002F> 混和：\n\u003Cb>醚, 丙酮, 石油醚\u003C\u002Fb>\n\u003Cbr \u002F> 微溶于：酒精\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：未报道特殊反应性。\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>ivn-mus LD50:1800 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>orl-rat LD50:5 g\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：无资料\n\u003Cbr \u002F> 对眼睛严重损害或刺激：无资料\n\u003Cbr \u002F> 生殖细胞变异原性：无资料\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>KB6010000\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：无资料\n\u003Cbr \u002F> 甲壳类：无资料\n\u003Cbr \u002F> 藻类：无资料\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>无资料\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律无资料\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在装有后燃和洗涤装置的化学焚烧炉中焚烧。废弃处置时请遵守\n\u003Cbr \u002F> 国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：与联合国分类标准不一致\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>未列明\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F> 角鲨烯\n\u003Cb>修改号码：6\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\u003Cbr \u002F>\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[382,386,392,398,404,410,416,422,428,434,440,446],{"slug":383,"cid":384,"name":173,"nameZh":174,"cas":385},"785884143794786304","J-22932-3","7683-64-9",{"slug":387,"cid":388,"name":389,"nameZh":390,"cas":391},"785872069496672256","J-993888-9","Triethoxy(1H,1H,2H,2H-nonafluorohexyl)silane","三乙氧基(1H,1H,2H,2H-九氟己基)硅烷","102390-98-7",{"slug":393,"cid":394,"name":395,"nameZh":396,"cas":397},"785895549642477568","J-42066-6","Nonacosane","正二十九烷","630-03-5",{"slug":399,"cid":400,"name":401,"nameZh":402,"cas":403},"785875859981471744","J-1110639-1","Didecyldimethylammonium bromide","双十烷基二甲基溴化铵","2390-68-3",{"slug":405,"cid":406,"name":407,"nameZh":408,"cas":409},"785889635443150848","J-1112170-3","Behentrimonium Chloride","二十二烷基三甲基氯化铵","17301-53-0",{"slug":411,"cid":412,"name":413,"nameZh":414,"cas":415},"785892329742405632","J-1112144-1","Benzyldimethyltetradecylammonium chloride dihydrate","苄基二甲基十四烷基氯化铵二水合物","147228-81-7",{"slug":417,"cid":418,"name":419,"nameZh":420,"cas":421},"785872200484786176","J-1991411-5","Didodecyldimethylammonium chloride","双十二烷基二甲基氯化铵","3401-74-9",{"slug":423,"cid":424,"name":425,"nameZh":426,"cas":427},"785883740080443392","J-1173206-2","1-bromoperfluorohexane","1-溴全氟己烷","335-56-8",{"slug":429,"cid":430,"name":431,"nameZh":432,"cas":433},"785891162828312576","J-29105-4","Squalane","角鲨烷","111-01-3",{"slug":435,"cid":436,"name":437,"nameZh":438,"cas":439},"785895426485129216","J-40622-4","triacontane","三十烷","638-68-6",{"slug":441,"cid":442,"name":443,"nameZh":444,"cas":445},"785891446883356672","J-29751-8","Benzyldimethyloctadecylammonium chloride","十八烷基二甲基苄基氯化铵","122-19-0",{"slug":447,"cid":448,"name":449,"nameZh":450,"cas":451},"785889319729500160","J-27286-6","n-Octacosane","二十八烷","630-02-4",1794263601412,"zh-CN",[]]