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其他不含其他含氧基的无环酮。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%",{"key":336,"value":337},"申报要素","品名, 成分含量, 用途, 丙酮报明包装",{"key":339,"value":340},"Summary","2914190090 other acyclic ketones without other oxygen function。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%",[342,345,347,350,353,356,359,362,365,368,371,374,377,380],{"key":343,"value":344},"符号","GHS02, GHS06",{"key":346,"value":259},"信号词",{"key":348,"value":349},"危害声明","H226-H302-H311-H331",{"key":351,"value":352},"警示性声明","P261-P280-P311",{"key":354,"value":355},"个人防护装备","Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter",{"key":357,"value":358},"危害码 (欧洲)","Xn:Harmful",{"key":360,"value":361},"风险声明 (欧洲)","R10;R22",{"key":363,"value":364},"安全声明 (欧洲)","S21-S23-S24\u002F25",{"key":366,"value":367},"危险品运输编码","UN 2310 3\u002FPG 3",{"key":369,"value":370},"WGK德国","1",{"key":372,"value":373},"RTECS号","SA1925000",{"key":375,"value":376},"包装等级","III",{"key":378,"value":379},"危险类别","3",{"key":330,"value":331},"\u003Ctd>\n\n\u003Cp>\u003Cstrong>乙酰丙酮毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp> 中等毒性，能刺激皮肤、黏膜。人体在150~300mg\u002Fkg下长时间逗留即出现头痛、恶心、呕吐、眩晕和感觉迟钝等症状。 \u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F123-54-6_749441.html#duXinDiv\">乙酰丙酮毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>精制方法：将20%乙酰丙酮粗品溶于80%的苯中，然后与等体积的蒸馏水振荡3小时，易溶于水的乙酸分配到水相中，而乙酰丙酮则溶于苯中。将苯蒸馏除去，精制得到乙酰丙酮。\u003C\u002Fp>\u003Cp>１．丙酮和醋酐缩合法　其反应式如下：\u003Cbr \u002F>\u003Cbr \u002F>　此路线工艺简单、成熟、收率高。但三氟化硼属危险性气体，使用不方便，废液的处理难度大。\u003Cbr \u002F>２．醋酸乙酯丙酮法　其反应式如下：\u003Cbr \u002F>\u003Cbr \u002F>　该法是一种经典合成方法。该工艺需用金属钠，给工业化生产带来一定危险性。\u003Cbr \u002F>３．乙酰乙酸乙酯醋酐法　其反应式如下：\u003Cbr \u002F>\u003Cbr \u002F>　该工艺操作简单、方便，设备投资少，\u003Cbr \u002F>但其技术经济指标不太理想，原料成本相\u003Cbr \u002F>当于进口产品价格。\u003Cbr \u002F>４．乙酰乙酸乙酯乙烯酮法　其反应式如下：\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>此法反应条件温和，收率较高。但工艺流程长，原料价格高，投资大。\u003Cbr \u002F>５．乙烯酮丙酮缩合转化法　其反应式如下：\u003Cbr \u002F>\u003Cbr \u002F>６．丙酮醋酸乙酯法　其反应式如下：\u003C\u002Fp>\u003Cp>\u003Cbr \u002F>\u003C\u002Fp>\u003Cp>7.将过量的精制的乙酸乙酯和干燥的丙酮混合，冷却至0℃以下，边搅拌边缓慢加入粉末状氨基钠，反应开始，并放出大量氨气：\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>冰水冷却下，搅拌反应24H之后，室温下静置过夜。然后加入等量的冰和水，静置分层，取水层，用稀硫酸中和至酸性。再加入适量饱和乙酸铜溶液，使乙酰丙酮，形成螯合物析出，析出充分后，抽滤，用水洗涤两次后，转入乙醚中充分振荡，加入2mol／L的硫酸使螯合物分解，静置后，分出乙醚层，酸层\u003Cbr \u002F>用乙醚萃取一次、乙醚层合并，加入无水氯化钙干燥脱水，过滤、蒸馏、回收可馏分乙醚，收集125～140℃馏分，第二次蒸馏，收集135～140℃馏分，即为成品。\u003C\u002Fp>","\u003Ctd>\n\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第一部分：化学品名称\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>化学品中文名称：\u003C\u002Ftd>\n\u003Ctd>乙酰丙酮；2,4-戊二酮\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>化学品英文名称：\u003C\u002Ftd>\n\u003Ctd>Acetylacetone；2,4-Pentanedione\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中文俗名或商品名：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>Synonyms：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>CAS No.：\u003C\u002Ftd>\n\u003Ctd>123-54-6\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子式：\u003C\u002Ftd>\n\u003Ctd>C\u003Csub>5\u003C\u002Fsub>H\u003Csub>8\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子量：\u003C\u002Ftd>\n\u003Ctd>100.11\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第二部分：成分\u002F组成信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd> 纯化学品混合物\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd> 化学品名称：乙酰丙酮；2,4-戊二酮\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>有害物成分\u003C\u002Ftd>\n\u003Ctd>含量\u003C\u002Ftd>\n\u003Ctd>CAS No.\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第三部分：危险性概述\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>危险性类别：\u003C\u002Ftd>\n\u003Ctd>第3.3类 高闪点易燃液体\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>侵入途径：\u003C\u002Ftd>\n\u003Ctd>吸入 食入 经皮吸收\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>健康危害：\u003C\u002Ftd>\n\u003Ctd>吸入、摄入或经皮肤吸收对身体有害，对眼睛有刺激作用，对皮肤可能有刺激作用。中毒表现有头痛、恶心和呕吐。慢性影响：实验表明有诱变作用。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>环境危害：\u003C\u002Ftd>\n\u003Ctd>对环境有危害，对大气可造成污染。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>燃爆危险：\u003C\u002Ftd>\n\u003Ctd>本品易燃，有毒，具刺激性。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第四部分：急救措施\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>皮肤接触：\u003C\u002Ftd>\n\u003Ctd>脱去污染的衣着，用流动清水冲洗。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>眼睛接触：\u003C\u002Ftd>\n\u003Ctd>立即提起眼睑，用流动清水冲洗。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>吸入：\u003C\u002Ftd>\n\u003Ctd>迅速脱离现场至空气新鲜处。保持呼吸道通畅。必要时进行人工呼吸。就医。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>食入：\u003C\u002Ftd>\n\u003Ctd>误服者给饮大量温水，催吐，就医。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第五部分：消防措施\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>危险特性：\u003C\u002Ftd>\n\u003Ctd>遇明火、高热或与氧化剂接触，有引起燃烧爆炸的危险。若遇高热，容器内压增大，有开裂和爆炸的危险。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>有害燃烧产物：\u003C\u002Ftd>\n\u003Ctd>一氧化碳、二氧化碳。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>灭火方法及灭火剂：\u003C\u002Ftd>\n\u003Ctd>泡沫、二氧化碳、干粉、砂土。用水灭火无效。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>消防员的个体防护：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>禁止使用的灭火剂：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>闪点(℃)：\u003C\u002Ftd>\n\u003Ctd>34\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>自燃温度(℃)：\u003C\u002Ftd>\n\u003Ctd>340\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸下限[%(V\u002FV)]：\u003C\u002Ftd>\n\u003Ctd>1.7\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸上限[%(V\u002FV)]：\u003C\u002Ftd>\n\u003Ctd>11.4\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>最小点火能(mJ)：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆燃点：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆速：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>最大燃爆压力(MPa)：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>建规火险分级：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第六部分：泄漏应急处理\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>应急处理：\u003C\u002Ftd>\n\u003Ctd>疏散泄漏污染区人员至安全区，禁止无关人员进入污染区，切断火源。建议应急处理人员戴好防毒面具，穿一般消防防护服。在确保安全情况下堵漏。喷水雾会减少蒸发，但不能降低泄漏物在受限制空间内的易燃性。用活性炭或其它惰性材料吸收，然后收集运至废物处理场所处置。如大量泄漏，利用围堤收容，然后收集、转移、回收或无害处理后废弃。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第七部分：操作处置与储存\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>操作注意事项：\u003C\u002Ftd>\n\u003Ctd>密闭操作，局部排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防毒面具（半面罩），戴化学安全防护眼镜，穿防静电工作服，戴橡胶耐油手套。远离火种、热源，工作场所严禁吸烟。使用防爆型的通风系统和设备。防止蒸气泄漏到工作场所空气中。避免与氧化剂、还原剂、碱类、卤素接触。充装要控制流速，防止静电积聚。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>储存注意事项：\u003C\u002Ftd>\n\u003Ctd>储存于阴凉、通风的库房。远离火种、热源。应与氧化剂、还原剂、碱类、卤素、食用化学品分开存放，切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第八部分：接触控制\u002F个体防护\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>最高容许浓度：\u003C\u002Ftd>\n\u003Ctd>中国MAC：未制定标准 苏联MAC：未制定标准 美国TWA：未制定标准 TLVWN： 未制定标准\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>监测方法：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>工程控制：\u003C\u002Ftd>\n\u003Ctd>密闭操作，局部排风。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>呼吸系统防护：\u003C\u002Ftd>\n\u003Ctd>可能接触其蒸气时，应该佩带防毒面具。高浓度环境中，佩带自给式呼吸器。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>眼睛防护：\u003C\u002Ftd>\n\u003Ctd>一般不需特殊防护，高浓度接触时可戴化学安全防护眼镜。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>身体防护：\u003C\u002Ftd>\n\u003Ctd>穿相应的防护服。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>手防护：\u003C\u002Ftd>\n\u003Ctd>戴防护手套。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>其他防护：\u003C\u002Ftd>\n\u003Ctd>工作现场禁止吸烟、进食和饮水。工作后，淋浴更衣。避免长期反复接触。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第九部分：理化特性\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>外观与性状：\u003C\u002Ftd>\n\u003Ctd>无色或微黄色液体，有酯的气味。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>pH：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>熔点(℃)：\u003C\u002Ftd>\n\u003Ctd>-23．2\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>沸点(℃)：\u003C\u002Ftd>\n\u003Ctd>140．5\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>相对密度(水=1)：\u003C\u002Ftd>\n\u003Ctd>0．98\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>相对蒸气密度(空气=1)：\u003C\u002Ftd>\n\u003Ctd>3．45\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>饱和蒸气压(kPa)：\u003C\u002Ftd>\n\u003Ctd>0．93／20℃\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>燃烧热(kJ\u002Fmol)：\u003C\u002Ftd>\n\u003Ctd>2574.5\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>临界温度(℃)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>临界压力(MPa)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>辛醇\u002F水分配系数的对数值：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>闪点(℃)：\u003C\u002Ftd>\n\u003Ctd>34\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>引燃温度(℃)：\u003C\u002Ftd>\n\u003Ctd>340\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸上限%(V\u002FV)：\u003C\u002Ftd>\n\u003Ctd>11.4\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸下限%(V\u002FV)：\u003C\u002Ftd>\n\u003Ctd>1.7\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子式：\u003C\u002Ftd>\n\u003Ctd>C\u003Csub>5\u003C\u002Fsub>H\u003Csub>8\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子量：\u003C\u002Ftd>\n\u003Ctd>100.11\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>蒸发速率：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>粘性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>溶解性：\u003C\u002Ftd>\n\u003Ctd>微溶于水，溶于醇、氯仿、醚、苯、丙酮等多数有机溶剂。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>主要用途：\u003C\u002Ftd>\n\u003Ctd>用作醋酸纤维素的溶剂，有机合成中间体，金属络合剂，涂料干燥剂，润滑剂、杀虫剂。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十部分：稳定性和反应活性\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>稳定性：\u003C\u002Ftd>\n\u003Ctd>在常温常压下 稳定\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>禁配物：\u003C\u002Ftd>\n\u003Ctd>强氧化剂、卤素、强还原剂、强碱。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>避免接触的条件：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>聚合危害：\u003C\u002Ftd>\n\u003Ctd>不能出现\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分解产物：\u003C\u002Ftd>\n\u003Ctd>一氧化碳、二氧化碳\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十一部分：毒理学资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>急性毒性：\u003C\u002Ftd>\n\u003Ctd>LD50：590mg\u002Fkg(大鼠经口)；810mg／kg(兔经皮) LC50：无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>急性中毒：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>慢性中毒：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>亚急性和慢性毒性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>刺激性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致敏性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致突变性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致畸性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致癌性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十二部分：生态学资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>生态毒理毒性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>生物降解性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>非生物降解性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>生物富集或生物积累性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十三部分：废弃处置\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>废弃物性质：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>废弃处置方法：\u003C\u002Ftd>\n\u003Ctd>处置前应参阅国家和地方有关法规。建议用焚烧法处置。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>废弃注意事项：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十四部分：运输信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003C\u002Ftd>\n\u003Ctd>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>危险货物编号：\u003C\u002Ftd>\n\u003Ctd>33587\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>UN编号：\u003C\u002Ftd>\n\u003Ctd>2310\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>包装标志：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>包装类别：\u003C\u002Ftd>\n\u003Ctd>Ⅲ\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>包装方法：\u003C\u002Ftd>\n\u003Ctd>小开口钢桶；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱；螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶（罐）外满底板花格箱、纤维板箱或胶合板箱。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>运输注意事项：\u003C\u002Ftd>\n\u003Ctd>运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。夏季最好早晚运输。运输时所用的槽（罐）车应有接地链，槽内可设孔隔板以减少震荡产生静电。严禁与氧化剂、还原剂、碱类、卤素、食用化学品等混装混运。运输途中应防曝晒、雨淋，防高温。中途停留时应远离火种、热源、高温区。装运该物品的车辆排气管必须配备阻火装置，禁止使用易产生火花的机械设备和工具装卸。公路运输时要按规定路线行驶，勿在居民区和人口稠密区停留。铁路运输时要禁止溜放。严禁用木船、水泥船散装运输。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>RETCS号：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>IMDG规则页码：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十五部分：法规信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>国内化学品安全管理法规：\u003C\u002Ftd>\n\u003Ctd>化学危险物品安全管理条例 (1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则 (化劳发[1992] 677号)，工作场所安全使用化学品规定 ([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志 (GB 13690-92)将该物质划为第3.3 类高闪点易燃液体。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>国际化学品安全管理法规：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十六部分：其他信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>参考文献：\u003C\u002Ftd>\n\u003Ctd>1.周国泰，化学危险品安全技术全书，化学工业出版社，1997 2.国家环保局有毒化学品管理办公室、北京化工研究院合编，化学品毒性法规环境数据手册，中国环境科学出版社.1992 3.Canadian Centre for Occupational Health and Safety,CHEMINFO Database.1998 4.Canadian Centre for Occupational Health and Safety, RTECS Database, 1989\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>填表时间：\u003C\u002Ftd>\n\u003Ctd>年月日\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>填表部门：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>数据审核单位：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>修改说明：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>其他信息：\u003C\u002Ftd>\n\u003Ctd>1\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>MSDS修改日期：\u003C\u002Ftd>\n\u003Ctd>年月日\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[387,393,399,405,409,415,421,427,433,439,445,451],{"slug":388,"cid":389,"name":390,"nameZh":391,"cas":392},"785889753466671104","J-1015079-5","Ethanolamine hydrochloride","乙醇胺盐酸盐","2002-24-6",{"slug":394,"cid":395,"name":396,"nameZh":397,"cas":398},"785883181285904384","J-7379-0","1,1-Dimethoxypropane","丙醛缩二甲醇","4744-10-9",{"slug":400,"cid":401,"name":402,"nameZh":403,"cas":404},"785876836004401152","J-14853-8","Lithium acetylacetonate","乙酰丙酮锂","18115-70-3",{"slug":406,"cid":407,"name":402,"nameZh":403,"cas":408},"785898548444008448","J-1314521-6","19185-99-0",{"slug":410,"cid":411,"name":412,"nameZh":413,"cas":414},"785873164981768192","J-1014076-8","lithium pyruvate","丙酮酸锂","2922-61-4",{"slug":416,"cid":417,"name":418,"nameZh":419,"cas":420},"785895899992690688","J-1981464-3","1-Aminopropan-2-one hydrochloride","氨基丙酮盐酸盐","7737-17-9",{"slug":422,"cid":423,"name":424,"nameZh":425,"cas":426},"847790479121584128","J-1134083-3","2-(methylamino)ethanol,hydrochloride","2-甲胺乙醇盐酸盐","62640-03-3",{"slug":428,"cid":429,"name":430,"nameZh":431,"cas":432},"785875684076556288","J-1971914-3","Oxetan-3-ylmethanol","氧杂环丁烷-3-甲醇","6246-06-6",{"slug":434,"cid":435,"name":436,"nameZh":437,"cas":438},"785896071678136320","J-1103247-6","ethyl 2-(methylamino)acetate","2-(甲基氨基)乙酸乙酯","13200-60-7",{"slug":440,"cid":441,"name":442,"nameZh":443,"cas":444},"785880589717737472","J-1009875-6","m-Tolylhydrazine","3-甲苯肼","536-89-0",{"slug":446,"cid":447,"name":448,"nameZh":449,"cas":450},"785897659536773120","J-47589-8","1,3-Propanediol","1,3-丙二醇","504-63-2",{"slug":452,"cid":453,"name":454,"nameZh":455,"cas":456},"785883597948063744","J-1343774-6","2-Aminoethanol copper complex","乙醇胺铜","52906-32-8",1794267246382,"zh-CN",[]]