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href=\"\u002Fen\u002Fcas\u002F431-03-8_946619.html#duXinDiv\">2,3-丁二酮毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>1.在自然界，丁二酮广泛存在于多种植物的香精油中，如鸢尾油、当归油、月桂油等，是黄油和其他一些天然产物香味的主要成分。工业上生产丁二酮是将甲基乙基酮用亚硝酸处理，生成丁酮肟，再用稀硫酸分解而得。或用乙烯基乙炔或甲基乙烯基酮经水合再氧化的方法。实验室可用二氧化硒氧化丁酮制取，也有用二酮二肟与亚硝酸钠反应的方法。\u003C\u002Fp>\u003Cp>2.可从含量高的精油中用游离法制得：精油1份加2份磷酸，使生成结晶性加成物C4H6O2·2H3PO4，加水后即释出丁二酮，如磷酸加入过量则加成物为液体。\u003Cbr \u002F>由葡萄糖经特殊发酵获得。\u003Cbr \u002F>用甲乙酮为起始原料合成。\u003Cbr \u002F>将丁酮在盐酸存在下用亚硝酸钠氧化后，用硫酸水解后蒸馏而得。\u003C\u002Fp>\u003Cp>3. 烟草：OR，18；FC，40。\u003C\u002Fp>\u003Cp>4.制法： \u003C\u002Fp>\u003Cp>于装有搅拌器、温度计、回流冷凝器、滴液漏斗（下端伸入液面以下）的反应瓶中，加入2-丁酮（2）40g（0.56mol），浓盐酸52mL，剧烈搅拌下于50～60℃滴加亚硝酸钠40g（0.58mol）溶于136mL水的溶液，约2h加完。注意有一氧化氮逸出。加完后将反应物转移至5L反应瓶中，加入亚硝酸钠141g溶于240mL水的溶液，装上空气冷凝，从冷凝器上口滴加120mL浓硫酸和340mL水的溶液，于10min加完。将混合物放置2天，直至亚硝酸消失（可以用碘化钾-淀粉试纸检验）。加入硫酸钠200g，蒸馏。待镏出液试样与20%的氢氧化钠溶液混合后不变浑浊时停止蒸馏。镏出液用无水硫酸钠干燥，重新蒸馏，收集86～88℃的馏分。这样得到的粗品再以无水硫酸钠干燥，蒸馏，收集86～88℃的馏分，得2，3-丁二酮（1）16～18g，收率33.3%～37.5%。\u003C\u002Fp>","\u003Ctd>\n\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第一部分：化学品名称\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>化学品中文名称：\u003C\u002Ftd>\n\u003Ctd>2，3-丁二酮；二乙酰\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>化学品英文名称：\u003C\u002Ftd>\n\u003Ctd>2，3-Butanedione；Diacetyl\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中文俗名或商品名：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>Synonyms：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>CAS No.：\u003C\u002Ftd>\n\u003Ctd>431-03-8\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子式：\u003C\u002Ftd>\n\u003Ctd>C\u003Csub>4\u003C\u002Fsub>H\u003Csub>6\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子量：\u003C\u002Ftd>\n\u003Ctd>86.09\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第二部分：成分\u002F组成信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd> 纯化学品混合物\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd> 化学品名称：2，3-丁二酮；二乙酰\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>有害物成分\u003C\u002Ftd>\n\u003Ctd>含量\u003C\u002Ftd>\n\u003Ctd>CAS No.\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>2，3-丁二酮\u003C\u002Ftd>\n\u003Ctd>100\u003C\u002Ftd>\n\u003Ctd>431-03-8\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第三部分：危险性概述\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>危险性类别：\u003C\u002Ftd>\n\u003Ctd>第3．2类 中闪点易燃液体\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>侵入途径：\u003C\u002Ftd>\n\u003Ctd>吸入 食入 经皮吸收\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>健康危害：\u003C\u002Ftd>\n\u003Ctd>具有刺激性。接触后可引起恶心、头痛和呕吐。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>环境危害：\u003C\u002Ftd>\n\u003Ctd>对环境有危害，对大气可造成污染。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>燃爆危险：\u003C\u002Ftd>\n\u003Ctd>本品易燃，有毒，具刺激性。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第四部分：急救措施\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>皮肤接触：\u003C\u002Ftd>\n\u003Ctd>脱去污染的衣着，用流动清水冲洗。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>眼睛接触：\u003C\u002Ftd>\n\u003Ctd>立即提起眼睑，用流动清水冲洗。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>吸入：\u003C\u002Ftd>\n\u003Ctd>迅速脱离现场至空气新鲜处。保持呼吸道通畅。必要时进行人工呼吸。就医。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>食入：\u003C\u002Ftd>\n\u003Ctd>误服者给饮大量温水，催吐，就医。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第五部分：消防措施\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>危险特性：\u003C\u002Ftd>\n\u003Ctd>其蒸气与空气形成爆炸性混合物，遇明火、高热能引起燃烧爆炸。与氧化剂能发生强烈反应。其蒸气比空气重，能在较低处扩散到相当远的地方，遇火源引着回燃。若遇高热，容器内压增大，有开裂和爆炸的危险。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>有害燃烧产物：\u003C\u002Ftd>\n\u003Ctd>一氧化碳、二氧化碳。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>灭火方法及灭火剂：\u003C\u002Ftd>\n\u003Ctd>泡沫、二氧化碳、干粉、砂土。用水灭火无效。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>消防员的个体防护：\u003C\u002Ftd>\n\u003Ctd>消防人员须佩戴防毒面具、穿全身消防服\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>禁止使用的灭火剂：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>闪点(℃)：\u003C\u002Ftd>\n\u003Ctd>6\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>自燃温度(℃)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸下限[%(V\u002FV)]：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸上限[%(V\u002FV)]：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>最小点火能(mJ)：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆燃点：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆速：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>最大燃爆压力(MPa)：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>建规火险分级：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第六部分：泄漏应急处理\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>应急处理：\u003C\u002Ftd>\n\u003Ctd>疏散泄漏污染区人员至安全区，禁止无关人员进入污染区，切断火源。建议应急处理人员戴自给式呼吸器，穿一般消防防护服。在确保安全情况下堵漏。喷水雾会减少蒸发但不能降低泄漏物在受限制空间内的易燃性。用活性炭或其它惰性材料吸收，收集运至废物处理场所处置。也可以用大量水冲洗，经稀释的洗水放入废水系统。如大量泄漏，利用围堤收容，然后收集、转移、回收或无害处理后废弃。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第七部分：操作处置与储存\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>操作注意事项：\u003C\u002Ftd>\n\u003Ctd>密闭操作，注意通风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防毒面具（半面罩），戴化学安全防护眼镜，穿防静电工作服，戴橡胶耐油手套。远离火种、热源，工作场所严禁吸烟。使用防爆型的通风系统和设备。防止蒸气泄漏到工作场所空气中。避免与氧化剂、还原剂、碱类接触。灌装时应控制流速，且有接地装置，防止静电积聚。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>储存注意事项：\u003C\u002Ftd>\n\u003Ctd>储存于阴凉、通风的库房。远离火种、热源。库温不宜超过30℃。应与氧化剂、还原剂、碱类、食用化学品分开存放，切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第八部分：接触控制\u002F个体防护\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>最高容许浓度：\u003C\u002Ftd>\n\u003Ctd>中国MAC：未制定标准苏联MAC：未制定标准美国TWA：未制定标准 TLVWN： 未制定标准\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>监测方法：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>工程控制：\u003C\u002Ftd>\n\u003Ctd>密闭操作，注意通风。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>呼吸系统防护：\u003C\u002Ftd>\n\u003Ctd>高浓度环境中，佩带防毒面具。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>眼睛防护：\u003C\u002Ftd>\n\u003Ctd>必要时戴化学安全防护眼镜。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>身体防护：\u003C\u002Ftd>\n\u003Ctd>穿相应的防护服。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>手防护：\u003C\u002Ftd>\n\u003Ctd>戴防护手套。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>其他防护：\u003C\u002Ftd>\n\u003Ctd>工作现场禁止吸烟、进食和饮水。工作后，淋浴更衣。避免长期反复接触。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第九部分：理化特性\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>外观与性状：\u003C\u002Ftd>\n\u003Ctd>微绿黄色液体，有强烈的气味。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>pH：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>熔点(℃)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>沸点(℃)：\u003C\u002Ftd>\n\u003Ctd>88\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>相对密度(水=1)：\u003C\u002Ftd>\n\u003Ctd>0．99\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>相对蒸气密度(空气=1)：\u003C\u002Ftd>\n\u003Ctd>3．00\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>饱和蒸气压(kPa)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>燃烧热(kJ\u002Fmol)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>临界温度(℃)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>临界压力(MPa)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>辛醇\u002F水分配系数的对数值：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>闪点(℃)：\u003C\u002Ftd>\n\u003Ctd>6\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>引燃温度(℃)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸上限%(V\u002FV)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>爆炸下限%(V\u002FV)：\u003C\u002Ftd>\n\u003Ctd>无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子式：\u003C\u002Ftd>\n\u003Ctd>C\u003Csub>4\u003C\u002Fsub>H\u003Csub>6\u003C\u002Fsub>O\u003Csub>2\u003C\u002Fsub>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分子量：\u003C\u002Ftd>\n\u003Ctd>86.09\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>蒸发速率：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>粘性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>溶解性：\u003C\u002Ftd>\n\u003Ctd>溶于水、乙醇、乙醚。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>主要用途：\u003C\u002Ftd>\n\u003Ctd>用作食品香料载体。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十部分：稳定性和反应活性\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>稳定性：\u003C\u002Ftd>\n\u003Ctd>在常温常压下 稳定\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>禁配物：\u003C\u002Ftd>\n\u003Ctd>强氧化剂、强还原剂、强碱。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>避免接触的条件：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>聚合危害：\u003C\u002Ftd>\n\u003Ctd>不能出现\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>分解产物：\u003C\u002Ftd>\n\u003Ctd>一氧化碳、二氧化碳。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十一部分：毒理学资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>急性毒性：\u003C\u002Ftd>\n\u003Ctd>LD50：1580mg／kg(大鼠经口) LC50：无资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>急性中毒：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>慢性中毒：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>亚急性和慢性毒性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>刺激性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致敏性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致突变性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致畸性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>致癌性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十二部分：生态学资料\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>生态毒理毒性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>生物降解性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>非生物降解性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>生物富集或生物积累性：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十三部分：废弃处置\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>废弃物性质：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>废弃处置方法：\u003C\u002Ftd>\n\u003Ctd>处置前应参阅国家和地方有关法规。建议用焚烧法处置。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>废弃注意事项：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十四部分：运输信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003C\u002Ftd>\n\u003Ctd>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable> \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>危险货物编号：\u003C\u002Ftd>\n\u003Ctd>32081\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>UN编号：\u003C\u002Ftd>\n\u003Ctd>2346\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>包装标志：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>包装类别：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>包装方法：\u003C\u002Ftd>\n\u003Ctd>安瓿瓶外普通木箱；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱；螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶（罐）外满底板花格箱、纤维板箱或胶合板箱。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>运输注意事项：\u003C\u002Ftd>\n\u003Ctd>运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。夏季最好早晚运输。运输时所用的槽（罐）车应有接地链，槽内可设孔隔板以减少震荡产生静电。严禁与氧化剂、还原剂、碱类、食用化学品等混装混运。运输途中应防曝晒、雨淋，防高温。中途停留时应远离火种、热源、高温区。装运该物品的车辆排气管必须配备阻火装置，禁止使用易产生火花的机械设备和工具装卸。公路运输时要按规定路线行驶，勿在居民区和人口稠密区停留。铁路运输时要禁止溜放。严禁用木船、水泥船散装运输。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>RETCS号：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>IMDG规则页码：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十五部分：法规信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>国内化学品安全管理法规：\u003C\u002Ftd>\n\u003Ctd>化学危险物品安全管理条例 (1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则 (化劳发[1992] 677号)，工作场所安全使用化学品规定 ([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志 (GB 13690-92)将该物质划为第3.2 类中闪点易燃液体。\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>国际化学品安全管理法规：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>第十六部分：其他信息\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>参考文献：\u003C\u002Ftd>\n\u003Ctd>1.周国泰，化学危险品安全技术全书，化学工业出版社，1997 2.国家环保局有毒化学品管理办公室、北京化工研究院合编，化学品毒性法规环境数据手册，中国环境科学出版社.1992 3.Canadian Centre for Occupational Health and Safety,CHEMINFO Database.1998 4.Canadian Centre for Occupational Health and Safety, RTECS Database, 1989\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>填表时间：\u003C\u002Ftd>\n\u003Ctd>年月日\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>填表部门：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>数据审核单位：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>修改说明：\u003C\u002Ftd>\n\u003Ctd>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>其他信息：\u003C\u002Ftd>\n\u003Ctd>1\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>MSDS修改日期：\u003C\u002Ftd>\n\u003Ctd>年月日\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[413,419,425,431,437,443,449,455,461,467,473,476],{"slug":414,"cid":415,"name":416,"nameZh":417,"cas":418},"785876617078509568","J-13764-4","3-Penten-2-one","3-戊烯-2-酮","625-33-2",{"slug":420,"cid":421,"name":422,"nameZh":423,"cas":424},"785876792106815488","J-817307-7","4-Aminopent-3-en-2-one","4-氨基-3-戊烯-2-酮","1118-66-7",{"slug":426,"cid":427,"name":428,"nameZh":429,"cas":430},"785897769855356928","J-1563084-9","3-Hexanone","3-己酮","589-38-8",{"slug":432,"cid":433,"name":434,"nameZh":435,"cas":436},"844160769669992448","J-1974933-8","4-Hydroxy-2-pentanone","4-羟基-2-戊酮","4161-60-8",{"slug":438,"cid":439,"name":440,"nameZh":441,"cas":442},"785873098107785216","J-1324968-8","3-Methyl-2-cyclohexen-1-one","3-甲基-2-环己烯-1-酮","1193-18-6",{"slug":444,"cid":445,"name":446,"nameZh":447,"cas":448},"785882269452603392","J-2772-5","Polyvinylpyrrolidone","聚乙烯吡咯烷酮","9003-39-8",{"slug":450,"cid":451,"name":452,"nameZh":453,"cas":454},"785892635045793792","J-33215-0","N-Vinyl-2-pyrrolidone","N-乙烯基吡咯烷酮","88-12-0",{"slug":456,"cid":457,"name":458,"nameZh":459,"cas":460},"785873027597340672","J-1012208-4","4-Aminocyclohexanone","4-氨基环己酮","87976-86-1",{"slug":462,"cid":463,"name":464,"nameZh":465,"cas":466},"785894032575303680","J-1325616-1","4-Hydroxycyclohexanone","4-羟基环己酮","13482-22-9",{"slug":468,"cid":469,"name":470,"nameZh":471,"cas":472},"785892201388314624","J-32157-3","1,4-Diazepan-5-one","1,4-二氮杂庚烷-5-酮","34376-54-0",{"slug":474,"cid":295,"name":475,"nameZh":296,"cas":297},"785882721892175872","Dimethylglyoxime",{"slug":477,"cid":478,"name":479,"nameZh":480,"cas":481},"785876791142125568","J-14595-9","4-Hydroxy-3-hexanone","4-羟基-3-己酮","4984-85-4",1794255179520,"zh-CN",[]]