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href=\"\u002Fen\u002Fcas\u002F121-03-9_583619.html#duXinDiv\">对硝基甲苯邻磺酸毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>由对硝基甲苯磺化而得。将熔融的对硝基甲苯吸入搪玻璃反应锅内，加入20%发烟硫酸980kg，控制温度不超过90℃。加完后，升温至105-110℃，保温1h。反应完成后冷却至70℃，加水稀释。在100℃以下搅拌30min，冷到25℃，调整酸度后过滤，滤饼即为2-甲基-5-硝基苯磺酸。\u003Cbr \u002F>\u003C\u002Fp>","\u003Ctd>\n\n\u003Cb>4-硝基甲苯-2-磺酸水合物\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块1. 化学品\u003C\u002Fstrong>\n\u003Cbr \u002F> 产品名称：\n\u003Cb>4-Nitrotoluene-2-sulfonic Acid Hydrate\u003C\u002Fb>\n\u003Cbr \u002F> 修改号码：\n\u003Cb>5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>GHS分类\u003C\u002Fb>\n\u003Cbr \u002F> 　物理性危害\n\u003Cbr \u002F> 金属腐蚀性\n\u003Cb>第1级\u003C\u002Fb>\n\u003Cbr \u002F> 　健康危害\n\u003Cbr \u002F> 急性毒性（经口）\n\u003Cb>第5级\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>皮肤腐蚀\u002F刺激\u003C\u002Fb>\n\u003Cb>1C类\u003C\u002Fb>\n\u003Cbr 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\u002F>\n\u003Cb>4-硝基甲苯-2-磺酸水合物\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块2. 危险性概述\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>[废弃处置]\u003C\u002Fb>\n\u003Cb>根据当地政府规定把物品\u002F容器交与工业废弃处理机构。\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块3. 成分\u002F组成信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>单一物质\u002F混和物\u003C\u002Fb>单一物质\n\u003Cbr \u002F>\n\u003Cb>化学名(中文名)：\u003C\u002Fb>\n\u003Cb>4-硝基甲苯-2-磺酸水合物\u003C\u002Fb>\n\u003Cbr \u002F> 百分比：\n\u003Cb>>95.0%(T)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>CAS编码：\u003C\u002Fb>\n\u003Cb>121-03-9\u003C\u002Fb>\n\u003Cbr \u002F> 分子式：\n\u003Cbr \u002F>\n\u003Cb>C7H7NO5S·xH2O\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块4. 急救措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 吸入：\n\u003Cb>将受害者移到新鲜空气处，保持呼吸通畅，休息。立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 皮肤接触：\n\u003Cb>立即去除\u002F脱掉所有被污染的衣物。用大量肥皂和水轻轻洗。\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 眼睛接触：用水小心清洗几分钟。如果方便，易操作，摘除隐形眼镜。继续清洗。\n\u003Cbr \u002F>\n\u003Cb>立即呼叫解毒中心\u002F医生。\u003C\u002Fb>\n\u003Cbr \u002F> 食入：\n\u003Cb>立即呼叫解毒中心\u002F医生。漱口。切勿引吐。\u003C\u002Fb>\n\u003Cbr \u002F> 紧急救助者的防护：救援者需要穿戴个人防护用品，比如橡胶手套和气密性护目镜。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块5. 消防措施\u003C\u002Fstrong>\n\u003Cbr \u002F> 合适的灭火剂：干粉，泡沫，雾状水，二氧化碳\n\u003Cbr \u002F> 特殊危险性：小心，燃烧或高温下可能分解产生毒烟。\n\u003Cbr \u002F> 特定方法：从上风处灭火，根据周围环境选择合适的灭火方法。\n\u003Cbr \u002F> 非相关人员应该撤离至安全地方。\n\u003Cbr \u002F> 周围一旦着火：如果安全，移去可移动容器。\n\u003Cbr \u002F> 消防员的特殊防护用具：灭火时，一定要穿戴个人防护用品。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块6. 泄漏应急处理\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护措施，防护用具，\n\u003Cb>使用特殊的个人防护用品（针对有毒颗粒的P3过滤式空气呼吸器）。远离溢出物\u002F泄露\u003C\u002Fb>\n\u003Cbr \u002F> 紧急措施：处并处在上风处。\n\u003Cbr \u002F> 泄露区应该用安全带等圈起来，控制非相关人员进入。\n\u003Cbr \u002F> 环保措施：防止进入下水道。\n\u003Cbr \u002F> 控制和清洗的方法和材料：清扫收集粉尘，封入密闭容器。注意切勿分散。附着物或收集物应该立即根据合适的\n\u003Cbr \u002F> 法律法规处置。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块7. 操作处置与储存\u003C\u002Fstrong>\n\u003Cbr \u002F> 处理\n\u003Cbr \u002F> 技术措施：在通风良好处进行处理。穿戴合适的防护用具。防止粉尘扩散。处理后彻底清洗双手\n\u003Cbr \u002F> 和脸。\n\u003Cbr \u002F> 注意事项：如果可能，使用封闭系统。如果粉尘或浮质产生，使用局部排气。\n\u003Cbr \u002F> 操作处置注意事项：避免接触皮肤、眼睛和衣物。\n\u003Cbr \u002F> 使用耐腐蚀设备。\n\u003Cbr \u002F> 贮存\n\u003Cbr \u002F> 储存条件：保持容器密闭。存放于凉爽、阴暗处。\n\u003Cbr \u002F> 存放处须加锁。\n\u003Cbr \u002F> 远离不相容的材料比如氧化剂存放。\n\u003Cbr \u002F> 包装材料：依据法律。只可存放在原用的容器內。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 工程控制：尽可能安装封闭体系或局部排风系统。同时安装淋浴器和洗眼器。\n\u003Cbr \u002F>\n\u003Cb>4-硝基甲苯-2-磺酸水合物\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块8. 接触控制和个体防护\u003C\u002Fstrong>\n\u003Cbr \u002F> 个人防护用品\n\u003Cbr \u002F> 　呼吸系统防护：\n\u003Cb>防尘面具，自携式呼吸器（SCBA），供气呼吸器等。使用通过政府标准的呼吸器。依\u003C\u002Fb>\n\u003Cbr \u002F> 据当地和政府法规。\n\u003Cbr \u002F> 　手部防护：防渗手套。\n\u003Cbr \u002F> 　眼睛防护：护目镜。如果情况需要，佩戴面具。\n\u003Cbr \u002F> 　皮肤和身体防护：防渗防护服。如果情况需要，穿戴防护靴。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块9. 理化特性\u003C\u002Fstrong>\n\u003Cbr \u002F> 固体\n\u003Cbr \u002F>\n\u003Cb>外形（20°C）：\u003C\u002Fb>\n\u003Cbr \u002F> 外观：\n\u003Cb>晶体-粉末\u003C\u002Fb>\n\u003Cbr \u002F> 颜色：\n\u003Cb>白色-深黄红色\u003C\u002Fb>\n\u003Cbr \u002F> 气味：无资料\n\u003Cbr \u002F>\n\u003Cb>pH:\u003C\u002Fb>无数据资料\n\u003Cbr \u002F> 熔点：\n\u003Cbr \u002F>\n\u003Cb>135°C\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>沸点\u002F沸程\u003C\u002Fb>无资料\n\u003Cbr \u002F> 闪点：无资料\n\u003Cbr \u002F> 爆炸特性\n\u003Cbr \u002F> 　爆炸下限：无资料\n\u003Cbr \u002F> 　爆炸上限：无资料\n\u003Cbr \u002F> 蒸气压：\n\u003Cb>0.8Pa\u002F20°C\u003C\u002Fb>\n\u003Cbr \u002F> 密度：无资料\n\u003Cbr \u002F> 溶解度：\n\u003Cbr \u002F>\n\u003Cb>[水]\u003C\u002Fb>溶于\n\u003Cbr \u002F>\n\u003Cb>[其他溶剂]\u003C\u002Fb>\n\u003Cbr \u002F> 溶于：\n\u003Cb>醚, 酒精, 氯仿\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块10. 稳定性和反应性\u003C\u002Fstrong>\n\u003Cbr \u002F> 化学稳定性：一般情况下稳定。\n\u003Cbr \u002F> 危险反应的可能性：未报道特殊反应性。\n\u003Cbr \u002F> 须避免接触的物质氧化剂\n\u003Cbr \u002F>\n\u003Cb>危险的分解产物:\u003C\u002Fb>\n\u003Cb>一氧化碳, 二氧化碳, 氮氧化物 (NOx), 硫氧化物\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块11. 毒理学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 急性毒性：\n\u003Cb>orl-rat LD50:3710 mg\u002Fkg\u003C\u002Fb>\n\u003Cbr \u002F> 对皮肤腐蚀或刺激：\n\u003Cb>skn-rbt 20 mg\u002F24H MOD\u003C\u002Fb>\n\u003Cbr \u002F> 对眼睛严重损害或刺激：\n\u003Cb>eye-rbt 2 mg\u002F24H SEV\u003C\u002Fb>\n\u003Cbr \u002F> 生殖细胞变异原性：无资料\n\u003Cbr \u002F> 致癌性：\n\u003Cbr \u002F>\n\u003Cb>IARC =\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>NTP =\u003C\u002Fb>无资料\n\u003Cbr \u002F> 生殖毒性：无资料\n\u003Cbr \u002F>\n\u003Cb>RTECS 号码:\u003C\u002Fb>\n\u003Cb>DB7175000\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 生态毒性：\n\u003Cbr \u002F> 鱼类：\n\u003Cb>48h LC50:326 mg\u002FL (Oryzias latipes)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>96h LC50:>100 mg\u002FL (Oryzias latipes)\u003C\u002Fb>\n\u003Cbr \u002F> 甲壳类：\n\u003Cb>48h EC50:130 mg\u002FL (Daphnia magna)\u003C\u002Fb>\n\u003Cbr \u002F> 藻类：\n\u003Cb>72h EC50:90 mg\u002FL (Selenastrum capricornutum)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>4-硝基甲苯-2-磺酸水合物\u003C\u002Fb>\n\u003Cb>修改号码：5\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块12. 生态学信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>残留性 \u002F 降解性：\u003C\u002Fb>\n\u003Cb>3 % (by BOD), 0 % (by HPLC), 0 % (by TOC)\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>潜在生物累积 （BCF):\u003C\u002Fb>\n\u003Cb><0.4 (conc. 0.5 mg\u002FL), <4.1 (conc. 0.05 mg\u002FL)\u003C\u002Fb>\n\u003Cbr \u002F> 土壤中移动性\n\u003Cbr \u002F>\n\u003Cb>　log水分配系数：\u003C\u002Fb>无资料\n\u003Cbr \u002F>\n\u003Cb>　土壤吸收系数 （Koc）：\u003C\u002Fb>无资料\n\u003Cbr \u002F> 　亨利定律无资料\n\u003Cbr \u002F>\n\u003Cb>constant(PaM3\u002Fmol):\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块13. 废弃处置\u003C\u002Fstrong>\n\u003Cbr \u002F> 如果可能，回收处理。请咨询当地管理部门。建议在可燃溶剂中溶解混合，在装有后燃和洗涤装置的化学焚烧炉中\n\u003Cbr \u002F> 焚烧。废弃处置时请遵守国家、地区和当地的所有法规。\n\u003Cbr \u002F>\n\n\u003Cstrong>模块14. 运输信息\u003C\u002Fstrong>\n\u003Cbr \u002F> 联合国分类：\n\u003Cb>第8类 腐蚀品\u003C\u002Fb>\n\u003Cbr \u002F>\n\u003Cb>UN编号：\u003C\u002Fb>\n\u003Cb>3261\u003C\u002Fb>\n\u003Cbr \u002F> 正式运输名称：\n\u003Cb>腐蚀性固体, 酸性的, 有机的, 不另作详细说明\u003C\u002Fb>\n\u003Cbr \u002F> 包装等级：\n\u003Cb>III\u003C\u002Fb>\n\u003Cbr \u002F>\n\n\u003Cstrong>模块15. 法规信息\u003C\u002Fstrong>\n\u003Cbr \u002F>\n\u003Cb>《危险化学品安全管理条例》（2002年1月26日国务院发布，2011年2月16日修订）: 针对危险化学品的安全使用、\u003C\u002Fb>\n\u003Cbr \u002F> 生产、储存、运输、装卸等方面均作了相应的规定。\n\u003Cbr \u002F>\n\u003Cbr \u002F>\n\n\u003Cstrong> 模块16 - 其他信息 \u003C\u002Fstrong>\n\u003Cbr \u002F>N\u002FA\n\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\n\u003C\u002Ftd>","2026-08-21T07:51:12.859463Z",false,[349,355,361,367,373,379],{"slug":350,"cid":351,"name":352,"nameZh":353,"cas":354},"785898545608658944","J-51249-1","Lithium (1,2-ethanediolato-O)bis[1,2-ethanediolato(2-)-O,O']silicate","(1,2-乙二醇-O)二[乙二醇(2-)-O,O']硅酸锂","155740-37-7",{"slug":356,"cid":357,"name":358,"nameZh":359,"cas":360},"785892428430184448","J-1492319-9","(Toluene-3,4-dithiolato)zinc(II)","(甲苯-3,4-二巯基)锌(II)","29726-21-4",{"slug":362,"cid":363,"name":364,"nameZh":365,"cas":366},"785888328925843456","J-1332844-5","3-(Dimethylamino)propiophenone hydrochloride","3-(二甲氨基)苯丙酮盐酸盐","879-72-1",{"slug":368,"cid":369,"name":370,"nameZh":371,"cas":372},"785891287193620480","J-1396798-3","2,2,4,4,6,6-Hexamethyl-1,3,5-trithiane","三硫丙酮","828-26-2",{"slug":374,"cid":375,"name":376,"nameZh":377,"cas":378},"785888519284330496","J-1349670-0","1-(9H-fluoren-9-yl)ethanol","(±)-1-(9-芴)乙醇","3023-49-2",{"slug":380,"cid":381,"name":382,"nameZh":383,"cas":384},"785882290201825280","J-1444294-8","2,3,5,6-Tetrafluoro-1,4-benzenedimethanol","2,3,5,6-四氟-1,4-苯二甲醇","92339-07-6",1792634342464,"zh-CN",[]]