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General tariff:30.0%",[367,370,372,375,378,381,384,387,390,393,396,399,402,405,408],{"key":368,"value":369},"符号","GHS02, GHS05, GHS06, GHS09",{"key":371,"value":257},"信号词",{"key":373,"value":374},"危害声明","H225-H300 + H330-H311-H314-H410",{"key":376,"value":377},"补充危害声明","Corrosive to the respiratory tract.",{"key":379,"value":380},"警示性声明","P260-P280-P301 + P310 + P330-P304 + P340 + P310-P305 + P351 + P338-P370 + P378",{"key":382,"value":383},"个人防护装备","Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)",{"key":385,"value":386},"危害码 (欧洲)","F:Flammable",{"key":388,"value":389},"风险声明 (欧洲)","R11;R24\u002F25;R26;R34;R50",{"key":391,"value":392},"安全声明 (欧洲)","S23-S26-S28-S36\u002F37\u002F39-S45-S61",{"key":394,"value":395},"危险品运输编码","UN 1092 6.1\u002FPG 1",{"key":397,"value":398},"WGK德国","3",{"key":400,"value":401},"RTECS号","AS1050000",{"key":403,"value":404},"包装等级","I",{"key":406,"value":407},"危险类别","6.1",{"key":355,"value":409},"2912190030","\u003Ctd>\n\n\u003Cp>\u003Cstrong>丙烯醛毒理学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1.急性毒性\u003C\u002Fp>\n\u003Cp>LD50：26mg\u002Fkg（大鼠经口）；14mg\u002Fkg（小鼠经口）；7mg\u002Fkg（兔经口）；200mg\u002Fkg（兔经皮）\u003C\u002Fp>\n\u003Cp>LC50：18mg\u002Fm\u003Csup>3\u003C\u002Fsup>（大鼠吸入，4h）\u003C\u002Fp>\n\u003Cp>2.刺激性\u003C\u002Fp>\n\u003Cp>家兔经皮：5mg，重度刺激。\u003C\u002Fp>\n\u003Cp>家兔经眼：1mg，重度刺激。\u003C\u002Fp>\n\u003Cp>3.亚急性与慢性毒性 大鼠持续接触本品浓度4.8mg\u002Fm\u003Csup>3\u003C\u002Fsup>,40h后，其肝脏的碱性磷酸酶活性升高。\u003C\u002Fp>\n\u003Cp>4.致突变性 人细胞DNA损伤：30μmol\u002FL。人淋巴细胞姐妹染色体交换：5μmol\u002FL。\u003C\u002Fp>\n\u003Cp>5.致畸性 如果直接在羊膜上给药，丙烯醛可致畸和产生胚胎毒性。\u003C\u002Fp>\n\u003Cp>6.致癌性 IARC致癌性评论：G3，对人及动物致癌性证据不足。\u003C\u002Fp>\n\u003Cp>7.其他 大鼠静脉最低中毒剂量（TDLo）：6mg\u002Fkg（孕后用药9d），胚泡植入后死亡率升高。\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Cstrong>丙烯醛生态学数据:\u003C\u002Fstrong>\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\u003Cp>1.生态毒性\u003C\u002Fp>\n\u003Cp>LC50：0.046mg\u002FL（24h）（褐鳟）；0.079mg\u002FL（24h）（金鱼）；0.0173~0.022mg\u002FL（96h）（黑头呆鱼）；0.23mg\u002FL（24h），0.083mg\u002FL（48h）（水蚤）\u003C\u002Fp>\n\u003Cp>LD50：＜0.08mg\u002FL（24h）（金鱼，改良ASTMD1345）\u003C\u002Fp>\n\u003Cp>EC50：0.034mg\u002FL（48h）（水蚤）\u003C\u002Fp>\n\u003Cp>2.生物降解性\u003C\u002Fp>\n\u003Cp>好氧生物降解（h）：168~672\u003C\u002Fp>\n\u003Cp>厌氧生物降解（h）：672~2880\u003C\u002Fp>\n\u003Cp>3.非生物降解性 空气中光氧化半衰期（h）：3.4~33.7\u003C\u002Fp>\n\u003Cp>\u003C\u002Fp>\n\u003Cp>\u003Ca href=\"\u002Fen\u002Fcas\u002F107-02-8_79266.html#duXinDiv\">丙烯醛毒性英文版\u003C\u002Fa>\u003C\u002Fp>\n\n\u003C\u002Ftd>","\u003Cp>1.实验室制法 将甘油与硫酸氢钾或硫酸镁，硼酸，三氧化铝在215～235 ℃共热，将反应生成的丙烯醛气体蒸出并经冷凝收集，得粗品。将粗品加10%磷酸氢钠溶液调pH值至6，进行分馏，收集50～75 ℃馏分，即得丙烯醛精品。\u003Cbr \u002F>投料比（mol）：甘油：硫酸氢钾：硫酸钾＝1：0.5：0.026。\u003C\u002Fp>\u003Cp>\u003Cbr \u002F>2.工业制法 目前工业上主要采用丙烯催化空气氧化法。\u003Cbr \u002F>将丙烯、空气和水蒸气按一定比例混合后与催化剂一起送入固定床反应器，在0.1~0.2 MPa、350～450 ℃下进行反应，接触时间0.8 s，反应释放的热量回收用以蒸汽的生产。反应生成的气体混合物用水急冷，从急冷塔出来的尾气放空前经过洗涤。从急冷塔塔底出来的有机液进汽提塔，汽提出丙烯醛和其他轻组分，然后用蒸馏法从粗丙烯醛中除去水和乙醛。反应式：\u003Cbr \u002F>投料比（mol）丙烯：空气：水蒸气＝1：10：2。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>\u003Cp>3.乙醛和甲醛在催化剂作用下，经气相催化缩合制得丙烯醛。或者在催化剂的作用下，将丙烯用空气氧化制丙烯醛，副产物为乙酸、乙醛、丙烯酸和二氧化碳。\u003C\u002Fp>\u003Cp>\u003C\u002Fp>","\u003Ctd>\n\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 国标编号: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 31024 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> ＣＡＳ: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 107-02-8 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 中文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 丙烯醛 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 英文名称: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> acrolein；allylaldehyde \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 别 名: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 烯丙醛 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 分子式: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> C\u003Csub>3\u003C\u002Fsub>H\u003Csub>4\u003C\u002Fsub>O；CH\u003Csub>2\u003C\u002Fsub>CHCHO \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 分子量: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 56.06 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 熔 点: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> -87.7℃ 沸点：52.5℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 密 度: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 相对密度(水=1)0.84； \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 蒸汽压: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> -26℃ \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 溶解性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 溶于水，易溶于醇、丙酮等多数有机溶剂 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 稳定性: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 不稳定 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 外观与性状: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 无色或淡黄色液体，有恶臭 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 危险标记: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 7(低闪点易燃液体) \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>\u003Cstrong> 用 途: \u003C\u002Fstrong>\u003C\u002Ftd>\n\u003Ctd> 为合成树脂工业的重要原料之一，也大量用于有机合成与药物合成 \u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\u003Cbr \u002F>\n\u003Cb> 2.对环境的影响: \u003C\u002Fb>\n\u003Cbr \u002F> 一、健康危害 \n\u003Cbr \u002F> 侵入途径：吸入、食入、经皮吸收。\n\u003Cbr \u002F>健康危害：本品有强烈刺激性。吸入蒸气损害呼吸道，出现咽喉炎、胸部压迫感、支气管炎；大量吸入可致肺炎、肺水肿，尚可出现休克、肾炎及心力衰竭。可致死。液体及蒸气损害眼睛；皮肤接触可致灼伤。口服引起口腔及胃刺激或灼伤。 \n\u003Cbr \u002F> 二、毒理学资料及环境行为 \n\u003Cbr \u002F>毒性：属高毒类。\n\u003Cbr \u002F>急性毒性：LD\n\u003Csub>50\u003C\u002Fsub>46mg\u002Fkg(大鼠经口)；562mg\u002Fkg(兔经皮)；LC\n\u003Csub>50\u003C\u002Fsub>300mg\u002Fm\n\u003Csup>3\u003C\u002Fsup>，1\u002F2小时(大鼠吸入)人吸入2.3mg\u002Fm\n\u003Csup>3\u003C\u002Fsup>×5分钟，不能忍受；人吸入153ppm×10分钟，最小致死浓度；人经口5mg\u002Fkg最小致死剂量。\n\u003Cbr \u002F>刺激性：家兔经眼：1mg，重度刺激。家兔经皮：5mg，重度刺激。\n\u003Cbr \u002F>亚急性和慢性毒性：大鼠持续接触本品浓度低至4.8mg\u002Fm\n\u003Csup>3\u003C\u002Fsup>，40小时后，其肝脏的碱性磷酸酶活性升高。\n\u003Cbr \u002F>致突变性：微生物致突变性：鼠伤寒沙门氏菌20nL\u002F皿。微粒体致突变：鼠伤寒沙门氏菌50µl\u002F皿。\n\u003Cbr \u002F>生殖毒性：大鼠静脉最低中毒剂量(TDL\n\u003Csub>0\u003C\u002Fsub>)：6mg\u002Fkg(孕后用药9天)，胚泡植入后死亡率升高。\n\u003Cbr \u002F>致癌性：IARC致癌性评论：动物为不肯定性反应。 \n\u003Cbr \u002F> 危险特性：其蒸气与空气可形成爆炸性混合物，遇明火、高热极易燃烧爆炸。受热分解释出高毒蒸气。在空气中久置后能生成具有爆炸性的过氧化物。与酸类、碱类、氨、胺类、二氧化硫、硫脲、金属盐类、氧化剂等猛烈反应。在火场高温下能发生聚合放热，使容器破裂。\n\u003Cbr \u002F>燃烧(分解)产物：一氧化碳、二氧化碳。 \n\u003Cbr \u002F>\n\n\u003Cb> 3.现场应急监测方法: \u003C\u002Fb>\n\u003Cbr \u002F> 检气管法《化工企业空气中有害物质测定方法》，化学工业出版社 \n\u003Cbr \u002F>\n\n\u003Cb> 4.实验室监测方法: \u003C\u002Fb>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>监测方法\u003C\u002Ftd>\n\u003Ctd>来源\u003C\u002Ftd>\n\u003Ctd>类别\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>气相色谱法\u003C\u002Ftd>\n\u003Ctd>HJ\u002FT39-1999\u003C\u002Ftd>\n\u003Ctd>固定污染源排气\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>气相色谱法\u003C\u002Ftd>\n\u003Ctd>《水质分析大全》张宏陶等主编\u003C\u002Ftd>\n\u003Ctd>水质\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>气相色谱法\u003C\u002Ftd>\n\u003Ctd>《固体废弃物试验与分析评价手册》中国环境监测总站等译\u003C\u002Ftd>\n\u003Ctd>固体废弃物\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>4-已基间苯二酚分光光度法\u003C\u002Ftd>\n\u003Ctd>《空气和废气监测分析方法》国家环保局编\u003C\u002Ftd>\n\u003Ctd>空气和废气\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\n\u003Cb>5.环境标准:\u003C\u002Fb>\n\u003Ctable>\n\u003Ctbody>\n\u003Ctr>\n\u003Ctd>中国(TJ36-79)\u003C\u002Ftd>\n\u003Ctd>车间空气中有害物质的最高容许浓度\u003C\u002Ftd>\n\u003Ctd>0.3mg\u002Fm\u003Csup>3\u003C\u002Fsup>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(TJ36-79)\u003C\u002Ftd>\n\u003Ctd>居住区大气中有害物质的最高容许浓度\u003C\u002Ftd>\n\u003Ctd>0.10mg\u002Fm\u003Csup>3\u003C\u002Fsup>(一次值)\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(GB16297-1996)\u003C\u002Ftd>\n\u003Ctd>大气污染物综合排放标准 \u003C\u002Ftd>\n\u003Ctd>①最高允许排放浓度(mg\u002Fm\u003Csup>3\u003C\u002Fsup>)：\u003Cbr \u002F>16(表2)；20(表1)\u003Cbr \u002F>②最高允许排放速率(kg\u002Fh)：\u003Cbr \u002F>二级0.52～11(表2)；0.61～13(表1)\u003Cbr \u002F>三级0.78～17(表2)；0.92～20(表1)\u003Cbr \u002F>③无组织排放监控浓度限值(mg\u002Fm\u003Csup>3\u003C\u002Fsup>)：\u003Cbr \u002F>0.40(表2)；0.50(表1)\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(GB11607-89)\u003C\u002Ftd>\n\u003Ctd>渔业水质标准\u003C\u002Ftd>\n\u003Ctd>0.02mg\u002FL\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(GB5048-92)\u003C\u002Ftd>\n\u003Ctd>农田灌溉水质标准\u003C\u002Ftd>\n\u003Ctd>0.5mg\u002FL(水作、旱作、蔬菜)\u003Cbr \u002F>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>中国(待颁布)\u003C\u002Ftd>\n\u003Ctd>饮用水源中有害物质的最高容许浓度\u003C\u002Ftd>\n\u003Ctd>0.1mg\u002FL\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003Ctr>\n\u003Ctd>　\u003C\u002Ftd>\n\u003Ctd>嗅觉阈浓度\u003C\u002Ftd>\n\u003Ctd>0.48～4.1mg\u002Fm\u003Csup>3\u003C\u002Fsup>\u003C\u002Ftd>\n\u003C\u002Ftr>\n\u003C\u002Ftbody>\n\u003C\u002Ftable>\n\n\u003Cb>6.应急处理处置方法:\u003C\u002Fb>\n\u003Cbr \u002F> 一、泄漏应急处理  \n\u003Cbr \u002F>迅速撤离泄漏污染区人员至安全区，并立即进行隔离，小泄漏时隔离150米，大泄漏时隔离300米，严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿防毒服。不要直接接触泄漏物。尽可能切断泄漏源。防止进入下水道、排洪沟等限制性空间。小量泄漏：用活性面料或其它惰性材料吸收。也可以用大量水冲洗，洗水稀释后放入废水系统。大量泄漏：构筑围堤或挖坑收容；用泡沫覆盖，降低蒸气灾害。用防爆泵转移至槽车或专用收集器内，回收或运至废物处理场所处置。 \n\u003Cbr \u002F> 二、防护措施 \n\u003Cbr \u002F> 呼吸系统防护：可能接触其蒸气时，必须佩戴自吸过滤式防毒面具(全面罩)。\n\u003Cbr \u002F>眼睛防护：呼吸系统防护中已作防护。\n\u003Cbr \u002F>身体防护：穿防静电工作服。\n\u003Cbr \u002F>手防护：戴橡胶手套。\n\u003Cbr \u002F>其它：工作现场禁止吸烟、进食和饮水。工作毕，淋浴更衣。保持良好的卫生习惯。 \n\u003Cbr \u002F> 三、急救措施 \n\u003Cbr \u002F> 皮肤接触：立即脱去被污染的衣着，用大量流动清水冲洗，至少15分钟。\n\u003Cbr \u002F>眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15分钟。就医。\n\u003Cbr \u002F>吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。\n\u003Cbr \u002F>食入：误服者用水漱口，给饮牛奶或蛋清。就医。 \n\u003Cbr \u002F> 灭火方法：消防人员须戴好防毒面具，在安全距离以外，在上风向灭火。灭火剂：在抗溶性泡沫、干粉、二氧化碳、砂土。用水灭火无效。\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\u003Cbr \u002F>\n\n\u003C\u002Ftd>","2026-08-21T07:03:52.190431Z",false,[416,422,428,434,440,446,452,458,464,470,476,482],{"slug":417,"cid":418,"name":419,"nameZh":420,"cas":421},"785889783778906112","J-28696-4","Polyvinylidene fluoride","聚偏氟乙烯","24937-79-9",{"slug":423,"cid":424,"name":425,"nameZh":426,"cas":427},"785896576466817024","J-44491-7","Polyvinyl chloride","聚氯乙烯","9002-86-2",{"slug":429,"cid":430,"name":431,"nameZh":432,"cas":433},"785883357849325568","J-7986-7","Polydimethylsiloxane","聚二甲基硅氧烷","9016-00-6",{"slug":435,"cid":436,"name":437,"nameZh":438,"cas":439},"785898567767166976","J-51647-2","Graphite Fluoride","氟化石墨烯","51311-17-2",{"slug":441,"cid":442,"name":443,"nameZh":444,"cas":445},"785894875575881728","J-39466-1","1,3-difluoropropane","1,3-二氟丙烷","462-39-5",{"slug":447,"cid":448,"name":449,"nameZh":450,"cas":451},"785888712742408192","J-922352-3","2-Methylpyrrolidine","2-甲基吡咯烷","765-38-8",{"slug":453,"cid":454,"name":455,"nameZh":456,"cas":457},"785883885836701696","J-41075-3","3-Aminopentane","3-氨基戊烷","616-24-0",{"slug":459,"cid":460,"name":461,"nameZh":462,"cas":463},"785882042352013312","J-21977-2","Cycloheptane","环庚烷","291-64-5",{"slug":465,"cid":466,"name":467,"nameZh":468,"cas":469},"785883203456995328","J-1154283-9","3,3-Dimethylpyrrolidine","3,3-二甲基吡咯烷","3437-30-7",{"slug":471,"cid":472,"name":473,"nameZh":474,"cas":475},"785872993652838400","J-1993580-9","Oxepane","氧杂环庚烷","592-90-5",{"slug":477,"cid":478,"name":479,"nameZh":480,"cas":481},"785892634022383616","J-33208-1","Allylthiourea","烯丙基硫脲","109-57-9",{"slug":483,"cid":484,"name":485,"nameZh":486,"cas":487},"785884697602297856","J-23915-6","Chlorotrifluoroethylene","三氟氯乙烯","79-38-9",1794255187992,"zh-CN",[]]